Synthesis, crystal structure and spectroscopic study of trans-diazidobis(2,4,6-trimethylpyridine)copper(II) and azidotetrakis(3-ethyl-4-methylpyridine)copper(II) nitrate; [Cu(s-collidine)2(N3)2] and [Cu(β-collidine)4(N3)](NO3)

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