Natural radionuclide content of disposed phosphogypsum as TENORM produced from phosphorus fertilizer industry in Turkey

Abstract This study aims to determine radiological characterization of disposed phosphogypsum (PG) as technologically enhanced naturally occurring radioactive material produced from phosphorus fertilizer plants (PFPs) in Turkey and evaluate radiological impacts of outdoor storage and transport and the usage of PG as additive and filling materials in building sector and road construction. The mean activity concentrations of 226 Ra, 232 Th and 40 K measured for the PG samples from PFP A and PFP B are 125.0, 15.1 and 7.5 Bq kg −1 and 436.0, 9.4 and 13.0 Bq kg −1 , respectively. The mean activity concentrations of 226 Ra, 232 Th and 40 K are also compared with available reported data from other countries in the literature. The mean value of radium equivalent activity (Ra eq ) index calculated for the PFP A PG samples is 146.7 Bq kg −1 which is lower than the limit of 370 Bq kg −1 set for building materials and for the PFP B PG samples is 449.6 Bq kg −1 which is within the recommended safety limits for usability of PG as aggregate in making roads, streets, pavements and railroad ballast. Generic exposure scenarios given in the Radiation Protection 122 were used for radiological evaluation for members of the public and workers. The mean annual effective doses evaluated for members of the public and workers are lower than the annual limit of 1 mSv y −1 .

[1]  Mohammad Al-Oudat,et al.  Radiological impacts of phosphogypsum. , 2011, Journal of environmental management.

[2]  S. Stoulos,et al.  The application of phosphogypsum in agriculture and the radiological impact. , 2006, Journal of environmental radioactivity.

[3]  S. Black,et al.  Naturally occurring radioactive material (NORM) from a former phosphoric acid processing plant. , 2006, Journal of environmental radioactivity.

[4]  M. Alam,et al.  Radioactivity in chemical fertilizers used in Bangladesh , 1997 .

[5]  V. Shukla,et al.  Radiological impact of utilization of phosphogypsum and fly ash in building construction in India , 2005 .

[6]  Nurhayat Degirmenci,et al.  Application of phosphogypsum in soil stabilization , 2007 .

[7]  Ş. Turhan,et al.  Estimation of possible radiological hazards from natural radioactivity in commercially-utilized ornamental and countertops granite tiles , 2012 .

[8]  I. Altun,et al.  UTILIZATION OF WEATHERED PHOSPHOGYPSUM AS SET RETARDER IN PORTLAND CEMENT , 2004 .

[9]  A. C. Wätjen,et al.  Activity measurements of technically enhanced naturally occurring radionuclides (TENORM) in phosphogypsum. , 2009, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[10]  D. Kim,et al.  Overall natural radioactivity of a phosphate fertilizer industry in Korea , 2011 .

[11]  Barbara Paci Mazzilli,et al.  Radiochemical characterization of Brazilian phosphogypsum , 2000 .

[12]  T. Elnimr,et al.  Radioactivity and fluoride contamination derived from a phosphate fertilizer plant in Egypt. , 2009, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[13]  B. Mazzilli,et al.  Assessment of external gamma exposure and radon levels in a dwelling constructed with phosphogypsum plates. , 2011, Journal of hazardous materials.

[14]  M Maghrabi,et al.  Investigations on the activity concentrations of 238U, 226RA, 228RA, 210PB and 40K in Jordan phosphogypsum and fertilizers. , 2008, Radiation protection dosimetry.

[15]  N. Değirmenci Utilization of phosphogypsum as raw and calcined material in manufacturing of building products , 2008 .

[16]  Ş. Turhan Radioactivity levels of limestone and gypsum used as building raw materials in Turkey and estimation of exposure doses. , 2010, Radiation protection dosimetry.

[17]  Aurora López-Delgado,et al.  Environmental impact and management of phosphogypsum. , 2009, Journal of environmental management.

[18]  H. Oguz,et al.  The formation of alite phase by using phosphogypsum and oil shale , 2000 .

[19]  Ş. Turhan Radiological impacts of the usability of clay and kaolin as raw material in manufacturing of structural building materials in Turkey. , 2009, Journal of radiological protection : official journal of the Society for Radiological Protection.

[20]  Konstantin Kovler,et al.  Natural radionuclides in building materials available in Israel , 2002 .

[21]  C. Dueñas,et al.  Radiological impacts of natural radioactivity from phosphogypsum piles in Huelva (Spain) , 2010 .

[22]  Şeref Turhan,et al.  Assessment of the radiological impacts of utilizing coal combustion fly ash as main constituent in the production of cement , 2011, Environmental monitoring and assessment.

[23]  M. Benmansour,et al.  Natural radioactivity in phosphates, phosphogypsum and natural waters in Morocco. , 2001, Journal of environmental radioactivity.