Excitonic surface lattice resonances

Electromagnetic resonances are important in controlling light at the nanoscale. The most studied such resonance is the surface plasmon resonance that is associated with metallic nanostructures. Here we explore an alternative resonance, the surface exciton-polariton resonance, one based on excitonic molecular materials. Our study is based on analytical and numerical modelling. We show that periodic arrays of suitable molecular nanoparticles may support surface lattice resonances that arise as a result of coherent interactions between the particles. Our results demonstrate that excitonic molecular materials are an interesting alternative to metals for nanophotonics; they offer the prospect of both fabrication based on supramolecular chemistry and optical functionality arising from the way the properties of such materials may be controlled with light.

[1]  W. Barnes,et al.  Plasmonic surface lattice resonances on arrays of different lattice symmetry , 2014 .

[2]  Eric C. Le Ru,et al.  Principles of Surface-Enhanced Raman Spectroscopy: And Related Plasmonic Effects , 2008 .

[3]  M. S. Skolnick,et al.  Photon-mediated hybridization of frenkel excitons in organic semiconductor microcavities , 2000, Science.

[4]  Z. Kam,et al.  Absorption and Scattering of Light by Small Particles , 1998 .

[5]  George C Schatz,et al.  Controlling plasmon line shapes through diffractive coupling in linear arrays of cylindrical nanoparticles fabricated by electron beam lithography. , 2005, Nano letters.

[6]  D. Wiersma,et al.  The dynamics of one‐dimensional excitons in liquids , 1995 .

[7]  Vladimir Bulovic,et al.  Layer‐by‐Layer J‐Aggregate Thin Films with a Peak Absorption Constant of 106 cm–1 , 2005 .

[8]  Zhe Yuan,et al.  Plasmonic properties of supported Pt and Pd nanostructures. , 2006, Nano letters.

[9]  M. Käll,et al.  Realizing Strong Light-Matter Interactions between Single-Nanoparticle Plasmons and Molecular Excitons at Ambient Conditions. , 2015, Physical review letters.

[10]  Vadim A. Markel Coupled-dipole Approach to Scattering of Light from a One-dimensional Periodic Dipole Structure , 1993 .

[11]  E. Narimanov,et al.  Quest for organic plasmonics , 2013 .

[12]  Sergey I. Bozhevolnyi,et al.  Nanofocusing of electromagnetic radiation , 2013, Nature Photonics.

[13]  Semion K. Saikin,et al.  Photonics meets excitonics: natural and artificial molecular aggregates , 2013, 1304.0124.

[14]  M. Mishchenko,et al.  Reprint of: T-matrix computations of light scattering by nonspherical particles: a review , 1996 .

[15]  J. D. Swalen,et al.  A New Optical Phenomenon: Exciton Surface Polaritons at Room Temperature , 1979 .

[16]  Wei Zhou,et al.  Tunable subradiant lattice plasmons by out-of-plane dipolar interactions. , 2011, Nature nanotechnology.

[17]  W. Barnes,et al.  Localized exciton–polariton modes in dye-doped nanospheres: a quantum approach , 2015, 1506.01321.

[18]  Lukas Novotny,et al.  Principles of Nano-Optics by Lukas Novotny , 2006 .

[19]  G. Pirruccio,et al.  Coherent control of the optical absorption in a plasmonic lattice coupled to a luminescent layer , 2016, 2016 Conference on Lasers and Electro-Optics (CLEO).

[20]  V. Kravets,et al.  Extremely narrow plasmon resonances based on diffraction coupling of localized plasmons in arrays of metallic nanoparticles. , 2008, Physical review letters.

[21]  W. Barnes,et al.  Collective resonances in gold nanoparticle arrays. , 2008, Physical review letters.

[22]  Experimental demonstration of the optical lattice resonance in arrays of Si nanoresonators , 2016 .

[23]  M. Meier,et al.  Enhanced fields on large metal particles: dynamic depolarization. , 1983, Optics letters.

[24]  Alexander Moroz,et al.  Depolarization field of spheroidal particles , 2009 .

[25]  Michael I. Mishchenko,et al.  Calculation of the T matrix and the scattering matrix for ensembles of spheres , 1996 .

[26]  E. Schonbrun,et al.  Experimental observation of narrow surface plasmon resonances in gold nanoparticle arrays , 2008 .

[27]  W. Barnes,et al.  Optical field-enhancement and subwavelength field-confinement using excitonic nanostructures. , 2014, Nano letters.

[28]  D. DeJarnette,et al.  Polarization angle affects energy of plasmonic features in Fano resonant regular lattices , 2014 .

[29]  A. Berrier,et al.  Collective resonances in plasmonic crystals: Size matters , 2012, 1305.3134.

[30]  F. G. D. Abajo Colloquium: Light scattering by particle and hole arrays , 2007, 0903.1671.

[31]  Shunsuke Murai,et al.  Plasmonics for solid-state lighting: enhanced excitation and directional emission of highly efficient light sources , 2013, Light: Science & Applications.

[32]  William L. Barnes,et al.  Strong coupling between surface plasmon-polaritons and organic molecules in subwavelength hole arrays , 2005 .

[33]  James P. Gordon,et al.  Radiation Damping in Surface-Enhanced Raman Scattering , 1982 .

[34]  George C Schatz,et al.  Silver nanoparticle array structures that produce remarkably narrow plasmon lineshapes. , 2004, The Journal of chemical physics.

[35]  G. Mie Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen , 1908 .

[36]  V. Kravets,et al.  Narrow Collective Plasmon Resonances in Nanostructure Arrays Observed at Normal Light Incidence for Simplified Sensing in Asymmetric Air and Water Environments , 2014 .

[37]  C. Mirkin,et al.  Plasmonic photonic crystals realized through DNA-programmable assembly , 2014, Proceedings of the National Academy of Sciences.