On the Nature of Foam. IV. Phase Inversion and Foaming of Emulsion Consisting of Acetic Acid, Ethyl Ether, and Water

(1) It has been discovered, that there is certain heterogeneous system consisting of acetic acid, ethyl ether and water, which behaves both foamy and non foamy, according to the different modes of shaking. This behaviour in foam formation is due to the difference in the type of emulsions produced. (2) Three modes of shaking were noted and their influences upon the type of emulsion have been discussed. (3) The heterogeneous region of this system is divided into three parts, according to the type of emulsion produced by shaking, namely, oil-in-water region, water-in-oil region and phase inversion zone. In phase inversion zone, both types of emulsions are possible to be produced by different modes of shaking. Observations and discussions were made upon these emulsions.

[1]  Tunetaka Sasaki On the Nature of Foam. II. The Foam Formation of Ternary System, Acetic Acid–Ethyl Ether–Water , 1938 .

[2]  P. Rehbinder,et al.  Stabilisierende Wirkung von Adsorptionsschichten grenzflächenaktiver Stoffe auf disperse Systeme. II. Stabilität von Blasen und Tropfen an Trennungsflächen , 1930 .

[3]  C. Foulk A Theory of Liquid Film Formation , 1929 .

[4]  R. Woodman The Preparation and Conditions of Formation of the Two Possible Types of Emulsion in the System Cresylic Acid—Gelatine—Water , 1925 .

[5]  J. Hildebrand,et al.  THE THEORY OF EMULSIFICATION1 , 1923 .

[6]  O. Wilson,et al.  Some Factors Affecting the Stability and Inversion of Oil-Water Emulsions. , 1921 .

[7]  S. Bhatnagar CXCIX.—Studies in emulsions. Part III. Further investigations on the reversal of type by electrolytes , 1921 .

[8]  S. Bhatnagar LVII.—Studies in emulsions. Part I. A new method of determining the inversion of phases , 1920 .

[9]  Irving Langmuir,et al.  THE CONSTITUTION AND FUNDAMENTAL PROPERTIES OF SOLIDS AND LIQUIDS. II. LIQUIDS.1 , 1917 .

[10]  W. D. Harkins,et al.  THE ORIENTATION OF MOLECULES IN THE SURFACES OF LIQUIDS, THE ENERGY RELATIONS AT SURFACES, SOLUBILITY, ADSORPTION, EMULSIFICATION, MOLECULAR ASSOCIATION, AND THE EFFECT OF ACIDS AND BASES ON INTERFACIAL TENSION.1 (SURFACE ENERGY VI.) , 1917 .

[11]  W. D. Harkins,et al.  THE STRUCTURE OF THE SURFACES OF LIQUIDS, AND SOLUBILITY AS RELATED TO THE WORK DONE BY THE ATTRACTION OF TWO LIQUID SURFACES AS THEY APPROACH EACH OTHER. [SURFACE TENSION. V.] , 1917 .

[12]  T. B. Robertson Notiz über einige Faktoren, welche die Bestandteile von Oel-Wasseremulsionen bestimmen , 1910 .