A Luminescent Silver(I) Metal‐Organic Framework with New (4,6)‐Connected Topology Based on Mixed Tetrachlorotereph­thalate and 2,2′‐Bipyridine Ligands

A silver(I) coordination polymer with mixed 2,3,5,6-tetrachloro-1,4-benzenedicarboxylate (BDC-Cl4) and 2,2′-bipyridine (2,2′-bpy) ligands, [Ag2(BDC-Cl4)(2,2′-bpy)]n (1), was synthesized and structurally characterized. Compound 1 features a robust three-dimensional (3D) network, exhibiting a new (4,6)-connected net with the Schlafli symbol of (32·42·5·6)2(32·42·52·87·9·10). The photoluminescence properties of 1 were investigated in the solid state at room temperature.

[1]  A. Salifoglou,et al.  Coordination polymeric materials in binary and ternary Cu(II)–tetracarboxylato–bipy systems: Structure–reactivity correlation in Cu(II)–(O,N) 1D–3D lattice assemblies , 2012 .

[2]  Di Sun,et al.  A novel photoluminescent silver(I) wire supported by 4-tert-butylbenzoate and ligand-unsupported Ag⋯Ag interactions , 2012 .

[3]  Yang Zhao,et al.  Syntheses, structures and photoluminescent properties of a series of Ag(I) coordination architectures based on 2,4-diamino-6-methyl-1,3,5-triazine and dicarboxylates: from a 0D discrete molecule to a 3D infinite network , 2011 .

[4]  M. Du,et al.  Alkali-Metal-Templated Assemblies of New 3D Lead(II) Tetrachloroterephthalate Coordination Frameworks , 2011 .

[5]  Z. Su,et al.  An exceptional 54-fold interpenetrated coordination polymer with 10(3)-srs network topology. , 2011, Journal of the American Chemical Society.

[6]  Di Sun,et al.  Effect of Different Carboxylates on a Series of Ag(I) Coordination Compounds with Benzoguanamine Ligand , 2011 .

[7]  Di Sun,et al.  pH-Dependent Ag(I) coordination architectures constructed from 4-cyanopyridine and phthalic acid: from discrete structure to 2D sheet , 2011 .

[8]  A. Kirillov,et al.  Design of Silver(I)−PTA Coordination Polymers through Controlled N,P-Coordination of 1,3,5-Triaza-7-phosphaadamantane (PTA) with Arylcarboxylates , 2010 .

[9]  Yangzhong Liu,et al.  Silver Coordination Polymers Based on Neutral Trinitrile Ligand: Topology and the Role of Anion , 2010 .

[10]  M. Zeller,et al.  Reactions of H2S with AgCl within a porous coordination network. , 2010, Inorganic chemistry.

[11]  Wei‐Yin Sun,et al.  Synthesis, Structures, and Properties of Zinc(II) and Cadmium(II) Complexes with 1,2,4,5-Tetrakis(imidazol-1-ylmethyl)benzene and Multicarboxylate Ligands , 2010 .

[12]  A. Wojtczak,et al.  X-Ray structural and gas phase studies of silver(i) perfluorinated carboxylate complexes with 2,2'-bipyridyl as potential precursors for chemical vapour deposition (CVD). , 2010, Dalton transactions.

[13]  Jin Yang,et al.  Series of 2D and 3D coordination polymers based on 1,2,3,4-benzenetetracarboxylate and N-donor ligands: synthesis, topological structures, and photoluminescent properties. , 2010, Inorganic chemistry.

[14]  Sheng-ping Guo,et al.  A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light. , 2009, Journal of the American Chemical Society.

[15]  Yan Liu,et al.  Anion-driven conformational polymorphism in homochiral helical coordination polymers. , 2009, Journal of the American Chemical Society.

[16]  Qun Chen,et al.  Four copper(II) coordination polymers with a tetrachlorinated benzenedicarboxylate ligand: Solvent effect on diversiform supramolecular arrays , 2009 .

[17]  M. Allendorf,et al.  Luminescent metal-organic frameworks. , 2009, Chemical Society reviews.

[18]  Cheng‐Peng Li,et al.  Cobalt(II), silver(I), and lead(II) tetrabromoterephthalates exhibiting the 1-D linear chain, 2-D CdCl2-type layer, and 3-D penta-nodal mixed-connecting coordination frameworks , 2009 .

[19]  X. Bu,et al.  A photoluminescent 3D silver(I) coordination polymer with mixed ligands anthracene-9,10-dicarboxylate and hexamethylenetetramine, showing binodal 4-connected (43·63)2(42·62·82)3 topology , 2008 .

[20]  Qi Liu,et al.  Solvent-Controlled Assembly of Manganese(II) Tetrachloroterephthalates with 1D Chain, 2D Layer, and 3D Coordination Architectures , 2008 .

[21]  Elisabeta I. Szerb,et al.  Structural Variations in Bipyridine Silver(I) Complexes: Role of the Substituents and Counterions , 2008 .

[22]  N. Armaroli,et al.  Luminescent complexes beyond the platinum group: the d10 avenue. , 2008, Chemical communications.

[23]  P. Steel,et al.  Metallosupramolecular silver(I) assemblies based on pyrazine and related ligands , 2008 .

[24]  C. Su,et al.  Recent Advances in Supramolecular Design and Assembly of Silver(i) Coordination Polymers , 2006 .

[25]  J. Clyburne,et al.  Structure of organic and metal-organic networks based on a bifunctional m-terphenyl carboxylic acid. , 2006, Inorganic chemistry.

[26]  Omar M Yaghi,et al.  Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal-organic frameworks. , 2006, Journal of the American Chemical Society.

[27]  S. Batten,et al.  Direction of topological isomers of silver(I) coordination polymers induced by solvent, and selective anion-exchange of a class of PtS-type host frameworks. , 2005, Chemical communications.

[28]  Guanghua Li,et al.  Water-insoluble Ag-U-organic assemblies with photocatalytic activity. , 2005, Chemistry.

[29]  Michael O'Keeffe,et al.  Reticular chemistry: occurrence and taxonomy of nets and grammar for the design of frameworks. , 2005, Accounts of chemical research.

[30]  Xiao‐Ming Chen,et al.  Silver(I)–hexamethylenetetramine molecular architectures: from self-assembly to designed assembly , 2003 .

[31]  L. Cronin,et al.  Controlling dimensionality of silver(I) coordination networks with rigid aliphatic amino ligands: from a 2D to a 3D network of unprecedented topology comprising helical channels. , 2003, Chemical communications.

[32]  Anthony L. Spek,et al.  Journal of , 1993 .

[33]  Chi-Ming Che,et al.  Spectroscopic evidence for argentophilicity in structurally characterized luminescent binuclear silver(I) complexes , 2000 .

[34]  Chen,et al.  Self-Assembled Three-Dimensional Coordination Polymers with Unusual Ligand-Unsupported Ag-Ag Bonds: Syntheses, Structures, and Luminescent Properties. , 1999, Angewandte Chemie.

[35]  Vivian Wing-Wah Yam,et al.  Design of luminescent polynuclear copper(I) and silver(I) complexes with chalcogenides and acetylides as the bridging ligands , 1998 .

[36]  H. Patterson,et al.  Temperature-Dependent Photoluminescence Properties of Tl[Ag(CN)2]: Formation of Luminescent Metal—Metal-Bonded Inorganic Exciplexes in the Solid State. , 1998 .

[37]  M. Jansen.  Homoatomic d10–d10 Interactions: Their Effects on Structure and Chemical and Physical Properties , 1987 .