Long-term monitoring of atmospheric corrosion at weathering steel bridges by an electrochemical impedance method

Abstract Weathering steel corrosion was monitored for one to two years under natural atmosphere by an electrochemical impedance technique. Two identical comb-shape weathering steel sheets embedded in epoxy resin were used as monitoring probe electrodes at two different bridges in Japan. Impedances at 10 kHz ( Z 10kHz ) and 10 mHz ( Z 10mHz ) were automatically measured every hour. Coupons (50 × 50 × 2 mm 3 ) prepared from the same steel sheets were exposed together to measure the corrosion mass loss. The average ( Z 10mHz ) −1 value for half to one year exposure correlated well with the average corrosion rate determined from the corrosion mass loss.

[1]  Shotaro Morimoto,et al.  Mössbauer Spectroscopic Study of Rust Formed on a Weathering Steel and a Mild Steel Exposed for a Long Term in an Industrial Environment , 2002 .

[2]  Masato Yamashita,et al.  Composition and protective ability of rust layer formed on weathering steel exposed to various environments , 2006 .

[3]  H. Townsend,et al.  Atmospheric corrosion of different steels in marine, rural and industrial environments , 1999 .

[4]  A. Nishikata,et al.  AC impedance study on corrosion of 55%Al-Zn alloy-coated steel under thin electrolyte layers , 2000 .

[5]  T. Shinohara,et al.  Evaluation of Corrosivity in Atmospheric Environment by ACM (Atmospheric Corrosion Monitor) Type Corrosion Sensor , 2005 .

[6]  Atsushi Nishikata,et al.  Corrosion monitoring of nickel-containing steels in marine atmospheric environment , 2005 .

[7]  Stuart Lyon,et al.  A mechanistic study of initial atmospheric corrosion kinetics using electrical resistance sensors , 2005 .

[8]  A. Nishikata,et al.  Influence of Electrolyte Layer Thickness and pH on the Initial Stage of the Atmospheric Corrosion of Iron , 1997 .

[9]  Robert G. Kelly,et al.  The Evolution of the Adsorbed Solution Layer during Atmospheric Corrosion and Its Effects on the Corrosion Rate of Copper , 1993 .

[10]  Atsushi Nishikata,et al.  Electrochemical impedance study on galvanized steel corrosion under cyclic wet–dry conditions––influence of time of wetness , 2004 .

[11]  Hidesato Mabuchi,et al.  An electrochemical impedance study on atmospheric corrosion of steels in a cyclic wet-dry condition , 1995 .

[12]  M. Stratmann The Investigation of the Corrosion Properties of Metals, Covered with Adsorbed Electrolyte Layers - A New Experimental Technique , 1987 .

[13]  Y. Tsutsumi,et al.  Initial Stage of Pitting Corrosion of Type 304 Stainless Steel under Thin Electrolyte Layers Containing Chloride Ions , 2005 .

[14]  Atsushi Nishikata,et al.  An application of electrochemical impedance spectroscopy to atmospheric corrosion study , 1995 .

[15]  Atsushi Nishikata,et al.  AC impedance monitoring of pitting corrosion of stainless steel under a wet-dry cyclic condition in chloride-containing environment , 1996 .

[16]  Florian Mansfeld,et al.  Electrochemical monitoring of atmospheric corrosion phenomena , 1976 .

[17]  A. Nishikata,et al.  Monitoring of water uptake in organic coatings under cyclic wet–dry condition , 2003 .

[18]  Florian Mansfeld,et al.  Laboratory studies of atmospheric corrosion—I. Weight loss and electrochemical measurements , 1980 .

[19]  A. Nishikata,et al.  Degradation mechanism of galvanized steel in wet–dry cyclic environment containing chloride ions , 2004 .

[20]  A. Nishikata,et al.  Electrochemical impedance spectroscopy of metals covered with a thin electrolyte layer , 1996 .

[21]  Atsushi Nishikata,et al.  Electrochemical corrosion monitoring of galvanized steel under cyclic wet–dry conditions , 2000 .

[22]  Desmond C. Cook,et al.  Spectroscopic identification of protective and non-protective corrosion coatings on steel structures in marine environments , 2005 .

[23]  M. Moriyama,et al.  Effect of annealing atmosphere on void formation in copper interconnects : Special issue on materials-related issues for Cu interconnects used in ultra high speed large scaled integrated Si devices , 2002 .

[24]  Atsushi Nishikata,et al.  Pitting corrosion mechanism of stainless steels under wet-dry exposure in chloride-containing environments , 1998 .

[25]  A. Nishikata,et al.  Investigation of atmospheric corrosion of Zn using ac impedance and differential pressure meter , 2004 .

[26]  Masato Yamashita,et al.  The long term growth of the protective rust layer formed on weathering steel by atmospheric corrosion during a quarter of a century , 1994 .

[27]  M. Stern,et al.  Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves , 1957 .