Fertiliser drawn forward osmosis desalination: the concept, performance and limitations for fertigation

With the world’s population growing rapidly, pressure is increasing on the limited fresh water resources. Membrane technology could play a vital role in solving the water scarcity issues through alternative sources such as saline water sources and wastewater reclamation. The current generation of membrane technologies, particularly reverse osmosis (RO), has significantly improved in performance. However, RO desalination is still energy intensive and any effort to improve energy efficiency increases total cost of the product water. Since energy, environment and climate change issues are all inter-related, desalination for large-scale irrigation requires new novel technologies that address the energy issues. Forward osmosis (FO) is an emerging membrane technology. However, FO desalination for potable water is still a challenge because, recovery and regeneration of draw solutes require additional processes and energy. This article focuses on the application of FO desalination for non-potable irrigation where maximum water is required. In this concept of fertiliser drawn FO (FDFO) desalination, fertilisers are used as draw solutions (DS). The diluted draw solution after desalination can be directly applied for fertigation without the need for recovery and regeneration of DS. FDFO desalination can make irrigation water available at comparatively lower energy than the current desalination technologies. As a low energy technology, FDFO can be easily powered by renewable energy sources and therefore suitable for inland and remote applications. This article outlines the concept of FDFO desalination and critically evaluates the scope and limitations of this technology for fertigation, including suggestions on options to overcome some of these limitations.

[1]  Rong Wang,et al.  Synthesis and characterization of flat-sheet thin film composite forward osmosis membranes , 2011 .

[2]  Meng Wang,et al.  Carbon nanotube: Possible candidate for forward osmosis , 2010 .

[3]  Jeffrey R. McCutcheon,et al.  Dewatering press liquor derived from orange production by forward osmosis , 2011 .

[4]  Rong Wang,et al.  Modeling salt accumulation in osmotic membrane bioreactors: Implications for FO membrane selection a , 2011 .

[5]  J. Šimůnek,et al.  Evaluation of urea-ammonium-nitrate fertigation with drip irrigation using numerical modeling , 2006 .

[6]  Mark Conyers,et al.  Predicting the response of wheat (Triticum aestivum L.) to liquid and granular phosphorus fertilisers in Australian soils , 2007 .

[7]  Manuel Pulido-Velazquez,et al.  Water conservation in irrigation can increase water use , 2008, Proceedings of the National Academy of Sciences.

[8]  Robert L McGinnis,et al.  Desalination by ammonia–carbon dioxide forward osmosis: Influence of draw and feed solution concentrations on process performance , 2006 .

[9]  Chuyang Y. Tang,et al.  Synthesis and characterization of novel forward osmosis membranes based on layer-by-layer assembly. , 2011, Environmental science & technology.

[10]  M. Elimelech,et al.  The Future of Seawater Desalination: Energy, Technology, and the Environment , 2011, Science.

[11]  R. Hails,et al.  Assessing the risks associated with new agricultural practices , 2002, Nature.

[12]  J. Georgiadis,et al.  Science and technology for water purification in the coming decades , 2008, Nature.

[13]  W. Jury,et al.  The role of science in solving the world's emerging water problems. , 2005, Proceedings of the National Academy of Sciences of the United States of America.

[14]  Chuyang Y. Tang,et al.  Characterization of novel forward osmosis hollow fiber membranes , 2010 .

[15]  Charles Donald Moody Forward osmosis extractors : theory, feasibility and design optimization , 1977 .

[16]  Menachem Elimelech,et al.  Reverse draw solute permeation in forward osmosis: modeling and experiments. , 2010, Environmental science & technology.

[17]  J. McCutcheon,et al.  Internal concentration polarization in forward osmosis: role of membrane orientation , 2006 .

[18]  Sherub Phuntsho,et al.  A novel low energy fertilizer driven forward osmosis desalination for direct fertigation: Evaluating , 2011 .

[19]  Tzahi Y Cath,et al.  Solute coupled diffusion in osmotically driven membrane processes. , 2009, Environmental science & technology.

[20]  Tzahi Y Cath,et al.  Forward osmosis for concentration of anaerobic digester centrate. , 2007, Water research.

[21]  S. A. Barber,et al.  An Evaluation of the Mechanisms Governing the Supply of Ca, Mg, K, and Na to Soybean Roots (Glycine max) 1 , 1966 .

[22]  C Vandecasteele,et al.  Modelling of the retention of uncharged molecules with nanofiltration. , 2002, Water research.

[23]  Sherub Phuntsho,et al.  Membrane autopsy of a 10 year old hollow fibre membrane from Sydney Olympic Park water reclamation plant , 2011 .

[24]  Chen Xiao NANOFILTRATION TECHNOLOGY AND ITS APPLICATIONS IN FOOD AND FERMENTATION INDUSTRIES , 2000 .

[25]  Shahbaz Khan,et al.  Managing climate risks in Australia: options for water policy and irrigation management , 2008 .

[26]  C. D. Lundin,et al.  A multi-barrier osmotic dilution process for simultaneous desalination and purification of impaired water , 2010 .

[27]  How Yong Ng,et al.  Modified models to predict flux behavior in forward osmosis in consideration of external and internal concentration polarizations , 2008 .

[28]  Menachem Elimelech,et al.  Comparison of fouling behavior in forward osmosis (FO) and reverse osmosis (RO) , 2010 .

[29]  Menachem Elimelech,et al.  High performance thin-film composite forward osmosis membrane. , 2010, Environmental science & technology.

[30]  C. D. Moody,et al.  Forward osmosis extractors , 1976 .

[31]  Klaus-Viktor Peinemann,et al.  Membranes for Power Generation by Pressure Retarded Osmosis , 2008 .

[32]  Menachem Elimelech,et al.  Modeling water flux in forward osmosis: Implications for improved membrane design , 2007 .

[33]  I. Papadopoulos,et al.  A fertigation system for experimental purposes , 1987, Plant and Soil.

[34]  Luís F. Melo,et al.  BIOFOULING IN WATER SYSTEMS , 1997 .

[35]  Menachem Elimelech,et al.  Energy requirements of ammonia-carbon dioxide forward osmosis desalination , 2007 .

[36]  J. Cheeseman,et al.  Mechanisms of salinity tolerance in plants. , 1988, Plant physiology.

[37]  Herve Plusquellec,et al.  Is the daunting challenge of irrigation achievable? , 2002 .

[38]  George W. Gokel,et al.  Dean's handbook of organic chemistry , 2003 .

[39]  Amy E. Childress,et al.  Forward osmosis: Principles, applications, and recent developments , 2006 .

[40]  Benny D. Freeman,et al.  Reverse osmosis desalination: water sources, technology, and today's challenges. , 2009, Water research.

[41]  Avi Ostfeld,et al.  Biofouling formation and modeling in nanofiltration membranes applied to wastewater treatment , 2010 .

[42]  Menachem Elimelech,et al.  A novel approach for modeling concentration polarization in crossflow membrane filtration based on the equivalence of osmotic pressure model and filtration theory , 1998 .

[43]  How Yong Ng,et al.  A novel hybrid forward osmosis - nanofiltration (FO-NF) process for seawater desalination: Draw solution selection and system configuration , 2010 .

[44]  Menachem Elimelech,et al.  A novel ammonia-carbon dioxide forward (direct) osmosis desalination process , 2005 .

[45]  M. Elimelech,et al.  Organic fouling of forward osmosis membranes: Fouling reversibility and cleaning without chemical reagents , 2010 .

[46]  Rong Wang,et al.  Fabrication of novel poly(amide–imide) forward osmosis hollow fiber membranes with a positively charged nanofiltration-like selective layer , 2011 .

[47]  Tzahi Y. Cath,et al.  High recovery of concentrated RO brines using forward osmosis and membrane distillation , 2009 .

[48]  C. Revenga,et al.  Urban growth, climate change, and freshwater availability , 2011, Proceedings of the National Academy of Sciences.

[49]  Ata M. Hassan,et al.  A new approach to membrane and thermal seawater desalination processes using nanofiltration membranes (Part 1) , 1998 .

[50]  Linda Zou,et al.  Brackish water desalination by a hybrid forward osmosis-nanofiltration system using divalent draw solute , 2012 .

[51]  R. Service,et al.  Desalination Freshens Up , 2006, Science.

[52]  Tzahi Y. Cath,et al.  Selection of inorganic-based draw solutions for forward osmosis applications , 2010 .

[53]  David M. Fox,et al.  The School of Renewable Natural Resources , 2006 .

[54]  Raphael Semiat,et al.  Energy issues in desalination processes. , 2008, Environmental science & technology.

[55]  Mohammad Badruzzaman,et al.  Energy minimization strategies and renewable energy utilization for desalination: a review. , 2011, Water research.

[56]  H. Flemming,et al.  Biofouling in water systems – cases, causes and countermeasures , 2002, Applied Microbiology and Biotechnology.

[57]  Gary L. Amy,et al.  Hydrophilic Superparamagnetic Nanoparticles: Synthesis, Characterization, and Performance in Forward Osmosis Processes , 2011 .

[58]  Dana Karl Anderson Concentration of Dilute Industrial Wastes by Direct Osmosis , 1977 .

[59]  Kevin F. Goss,et al.  Environmental flows, river salinity and biodiversity conservation: managing trade-offs in the Murray-Darling basin , 2003 .

[60]  Kai Yu Wang,et al.  Double-Skinned Forward Osmosis Membranes for Reducing Internal Concentration Polarization within the Porous Sublayer , 2010 .

[61]  Anthony G Fane,et al.  Fouling propensity of forward osmosis: investigation of the slower flux decline phenomenon. , 2010, Water science and technology : a journal of the International Association on Water Pollution Research.

[62]  Andreas Phocaides,et al.  Handbook on pressurized irrigation techniques , 2001 .

[63]  Amy E. Childress,et al.  The forward osmosis membrane bioreactor: A low fouling alternative to MBR processes , 2009 .

[64]  Richard E. Kravath,et al.  Desalination of sea water by direct osmosis , 1975 .

[65]  Menachem Elimelech,et al.  Performance evaluation of sucrose concentration using forward osmosis , 2009 .

[66]  Menachem Elimelech,et al.  Relating performance of thin-film composite forward osmosis membranes to support layer formation and , 2011 .

[67]  Xiaofeng Lu,et al.  Preparation and characterization of NF composite membrane , 2002 .