Probing cation antisite disorder in Gd 2 Ti 2 O 7 pyrochlore by site-specific near-edge x-ray-absorption fine structure and x-ray photoelectron spectroscopy

Disorder in ${\mathrm{Gd}}_{2}{\mathrm{Ti}}_{2}{\mathrm{O}}_{7}$ is investigated by near-edge x-ray-absorption fine structure (NEXAFS) and x-ray photoelectron spectroscopy (XPS). NEXAFS shows ${\mathrm{Ti}}^{4+}$ ions occupy octahedral sites with a tetragonal distortion induced by vacant oxygen sites. $\mathrm{O}\phantom{\rule{0.3em}{0ex}}1s$ XPS spectra obtained with a charge neutralization system from ${\mathrm{Gd}}_{2}{\mathrm{Ti}}_{2}{\mathrm{O}}_{7}(100)$ and the ${\mathrm{Gd}}_{2}{\mathrm{Ti}}_{2}{\mathrm{O}}_{7}$ pyrochlore used by Chen et al. [Phys. Rev. Lett. 88, 105901 (2002)], both yielded a single peak, unlike the previous result on the latter that found two peaks. The current results give no evidence for an anisotropic distribution of Ti and O. The extra features reported in the aforementioned communication resulted from charging effects and incomplete surface cleaning. Thus, a result confirming the direct observation of simultaneous cation-anion antisite disordering and lending credence to the split vacancy model has been clarified.