Quantitative and qualitative investigation of the fuel utilization and introducing a novel calculation idea based on transfer phenomena in a polymer electrolyte membrane (PEM) fuel cell

Abstract In this study, fuel utilization (U F ) of a PEMFC have been investigated within transfer phenomenon approach. Description of the U F and fuel consumption measurement is the main factor to obtain the U F . The differences between the experimental study and theoretical calculations results in the previous research articles reveal the available theoretical equations should be studied more based on the fundamental affairs of the U F . Hence, there is a substantial issue that the U F description satisfies the principles, and then it can be validated by the experimental results. The results of this study indicate that the U F and power grew by 1.1% and 1%, respectively, based on one degree increased temperature. In addition, for every 1 kPa pressure increment, U F improved considerably by 0.25% and 0.173% in the 40 °C and 80 °C, respectively. Furthermore, in the constant temperature, the power improved by 22% based on one atmospheric growth of the pressure. Results of this research show that the U F has a differential nature, therefore differential equations will be employed to do an accurate theoretical calculation. Accordingly, it seems that the main defect of the theoretical calculation depends on Nernst equation that can be modified by a differential nature coefficient.

[1]  Claire H. Woo,et al.  PEM fuel cell current regulation by fuel feed control , 2007 .

[2]  Li Zhang,et al.  A Numerical Study on Microfluidic Fuel Cell: Improving Fuel Utilization and Fuel Operation Concentration , 2014 .

[3]  Jenn-Jiang Hwang Effect of hydrogen delivery schemes on fuel cell efficiency , 2013 .

[4]  B. Zitouni,et al.  Numerical simulation of exchange membrane fuel cells in different operating conditions , 2012 .

[5]  Yong Hao,et al.  Efficiency and fuel utilization of methane-powered single-chamber solid oxide fuel cells , 2008 .

[6]  G. Whitesides,et al.  Membraneless vanadium redox fuel cell using laminar flow. , 2002, Journal of the American Chemical Society.

[7]  H. A. Ozgoli,et al.  Modeling SOFC and GT Integrated-Cycle Power System with Energy Consumption Minimizing Target to Improve Comprehensive cycle Performance (Applied in pulp and paper; case studied) , 2011 .

[8]  P. Rodatz,et al.  Operational aspects of a large PEFC stack under practical conditions , 2004 .

[9]  Sarit K. Das,et al.  Experimental investigation of dry feed operation in a polymer electrolyte membrane fuel cell , 2014 .

[10]  Hossein Ghadamian,et al.  Alternative Biomass Fuels Consideration Exergy and Power Analysis for Hybrid System Includes PSOFC and GT Integration , 2015 .

[11]  José C. Páscoa,et al.  Analysis of PEM (Polymer Electrolyte Membrane) fuel cell cathode two-dimensional modeling , 2014 .

[12]  W. Mohamed,et al.  Hydrogen preheating through waste heat recovery of an open-cathode PEM fuel cell leading to power output improvement , 2016 .

[13]  Suthida Authayanun,et al.  Theoretical analysis of a biogas-fed PEMFC system with different hydrogen purifications: conventional and membrane-based water gas shift processes. , 2014 .

[14]  Hossein Ghadamian,et al.  Thermo-economic analysis of absorption air cooling system for pressurized solid oxide fuel cell/gas turbine cycle , 2012 .

[15]  In-Su Han,et al.  PEM fuel-cell stack design for improved fuel utilization , 2013 .

[16]  Hossein Ghadamian,et al.  Quantitative analysis of irreversibilities causes voltage drop in fuel cell (simulation & modeling) , 2004 .

[17]  K. Kang,et al.  Numerical modeling and analysis of micro-porous layer effects in polymer electrolyte fuel cells , 2009 .

[18]  Larry J. Markoski,et al.  Microfluidic fuel cell based on laminar flow , 2004 .

[19]  Tommi Keränen,et al.  Optimization study of purge cycle in proton exchange membrane fuel cell system , 2013 .

[20]  Jyoti Phirani,et al.  Analyses of fuel utilization in microfluidic fuel cell , 2008 .

[21]  P. Kulesza,et al.  Oxygen permeation through Nafion 117 membrane and its impact on efficiency of polymer membrane ethan , 2011 .

[22]  Frano Barbir,et al.  PEM Fuel Cells: Theory and Practice , 2012 .

[23]  Hossein Ghadamian,et al.  An algorithm for optimum design and macro-model development in PEMFC with exergy and cost considerations , 2006 .

[24]  A. Sasmito,et al.  Investigation of the purging effect on a dead-end anode PEM fuel cell-powered vehicle during segments of a European driving cycle , 2015 .

[25]  R. Datta,et al.  PEM fuel cell as a membrane reactor , 2001 .

[26]  Farzaneh Hooman,et al.  Energy Efficiency Improvement Analysis Considering Environmental Aspects in Regard to Biomass Gasification PSOFC/GT Power Generation System , 2013 .

[27]  Xianguo Li,et al.  Effective transport properties for polymer electrolyte membrane fuel cells – With a focus on the gas diffusion layer , 2013 .

[28]  Hengbing Zhao,et al.  Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles , 2008 .

[29]  Suman Basu,et al.  Modeling two-phase flow in PEM fuel cell channels , 2008 .

[30]  Mario Paolone,et al.  Experimental analysis of a PEM fuel cell performance at variable load with anodic exhaust management optimization , 2013 .

[31]  David Sinton,et al.  Improved fuel utilization in microfluidic fuel cells: A computational study , 2005 .

[32]  Z. Farhat,et al.  Modeling of catalyst layer microstructural refinement and catalyst utilization in a PEM fuel cell , 2004 .

[33]  Fortunato Migliardini,et al.  Hydrogen purge and reactant feeding strategies in self-humidified PEM fuel cell systems , 2017 .

[34]  Hisao Nishikawa,et al.  High fuel utilization operation of pure hydrogen fuel cells , 2008 .