In Situ Generated Hydrated Diorganotin Cations as Synthons for Hydrogen-Bonded and Coordination-Driven 1D-, 2D-, and 3D-Assemblies

The reaction of di-n-butyltin oxide with 1,5-naphthalenedisulfonic acid tetrahydrate in a 2:1 ratio afforded [{n-Bu2Sn(μ-OH)}2{μ-1,5-C10H6(SO3)2}]n (1). The latter is a three-dimensional coordinati...