Working group (WG) discussions on proficiency testing and external quality assessment held at the Eurachem workshop, Portorož, Slovenia 26–27 Sept 2005 are summarised. The discussions focused on performance criteria (WG 1), different aspects of accreditation (WGs 2–3), the revised international harmonised protocol (WG 4), pre- and post-analytical schemes (WG 5), Internet applications (WG 6), experience from the CoEPT project (WG 7), and future aspects (WG 8). Current status, problems and future directions were identified. The WG contained a mix of participants with different expertise. This was done to promote cross-fertilisation of ideas between sectors. The WG issues reflected the content of the keynote lectures and some issues were covered from different perspectives by more than one WG.