Structural Design for Efficient Perovskite Solar Modules

The fabrication of large area perovskite solar modules (PSMs) is attracting increasing attention. Traditionally, thin film solar modules are prepared by laser‐engraving several isolated lines to create a series of subcells. This process inevitably leads to an increase in series resistance when combining the subcells. Herein, a facile structure combining series and parallel cell connections is designed and developed for constructing PSMs. A champion power conversion efficiency (PCE) of 18.82% is achieved for perovskite composite modules with a designated area of 21.06 cm2. Furthermore, the PSMs can continue to operate even when parts of the device are shaded or broken. Because of the repeated structural arrangement, these modules may be suitable for fabrication on a broader scale for commercial applications.

[1]  A. Palma Laser‐Processed Perovskite Solar Cells and Modules , 2020 .

[2]  N. Park,et al.  Scalable fabrication and coating methods for perovskite solar cells and solar modules , 2020, Nature Reviews Materials.

[3]  Wen-Hau Zhang,et al.  Superior Textured Film and Process Tolerance Enabled by Intermediate‐State Engineering for High‐Efficiency Perovskite Solar Cells , 2020, Advanced science.

[4]  Zhihui Zhang,et al.  Standardizing Perovskite Solar Modules beyond Cells , 2019, Joule.

[5]  Sisi He,et al.  Scalable Fabrication of Metal Halide Perovskite Solar Cells and Modules , 2019, ACS Energy Letters.

[6]  M. Nazeeruddin,et al.  Retarding Thermal Degradation in Hybrid Perovskites by Ionic Liquid Additives , 2019, Advanced Functional Materials.

[7]  Junsheng Yu,et al.  Highly efficient prismatic perovskite solar cells , 2019, Energy & Environmental Science.

[8]  Fei Huang,et al.  From scalable solution fabrication of perovskite films towards commercialization of solar cells , 2019, Energy & Environmental Science.

[9]  Jinsong Huang,et al.  Scalable Fabrication of Efficient Perovskite Solar Modules on Flexible Glass Substrates , 2019, Advanced Energy Materials.

[10]  Wen-Hau Zhang,et al.  Design of an Inorganic Mesoporous Hole‐Transporting Layer for Highly Efficient and Stable Inverted Perovskite Solar Cells , 2018, Advanced materials.

[11]  Zhen Li,et al.  Outlook and Challenges of Perovskite Solar Cells toward Terawatt-Scale Photovoltaic Module Technology , 2018, Joule.

[12]  Ruixin Ma,et al.  High‐Performance Perovskite Solar Cells with Large Grain‐Size obtained by using the Lewis Acid‐Base Adduct of Thiourea , 2018 .

[13]  Kai Zhu,et al.  Scalable fabrication of perovskite solar cells , 2018 .

[14]  Kai Zhu,et al.  Highly Efficient Perovskite Solar Modules by Scalable Fabrication and Interconnection Optimization , 2018 .

[15]  Xudong Yang,et al.  A solvent- and vacuum-free route to large-area perovskite films for efficient solar modules , 2017, Nature.

[16]  Kai Zhu,et al.  Perovskite Solar Cells—Towards Commercialization , 2017 .

[17]  T. Noda,et al.  Thermally Stable MAPbI3 Perovskite Solar Cells with Efficiency of 19.19% and Area over 1 cm2 achieved by Additive Engineering , 2017, Advanced materials.

[18]  Kai Zhu,et al.  Perovskite ink with wide processing window for scalable high-efficiency solar cells , 2017, Nature Energy.

[19]  Yue Hu,et al.  Stable Large‐Area (10 × 10 cm2) Printable Mesoscopic Perovskite Module Exceeding 10% Efficiency , 2017 .

[20]  Henry J. Snaith,et al.  A low viscosity, low boiling point, clean solvent system for the rapid crystallisation of highly specular perovskite films , 2017 .

[21]  Liyuan Han,et al.  Soft-cover deposition of scaling-up uniform perovskite thin films for high cost-performance solar cells , 2016 .

[22]  Christophe Ballif,et al.  Laser-Scribing Patterning for the Production of Organometallic Halide Perovskite Solar Modules , 2015, IEEE Journal of Photovoltaics.

[23]  Aldo Di Carlo,et al.  Perovskite solar cells and large area modules (100 cm2) based on an air flow-assisted PbI2 blade coating deposition process , 2015 .

[24]  Sandeep Kumar Pathak,et al.  Ultrasmooth organic–inorganic perovskite thin-film formation and crystallization for efficient planar heterojunction solar cells , 2015, Nature Communications.

[25]  M. Green,et al.  The emergence of perovskite solar cells , 2014, Nature Photonics.

[26]  Tsutomu Miyasaka,et al.  Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. , 2009, Journal of the American Chemical Society.