Membrane Reactors for in Situ Water Removal: A Review of Applications

This paper reviews the investigated applications of membrane reactors for in situ water removal during catalytic reactions in the food, pharmaceutical, cosmetics, and petrochemical sectors. The glo...

[1]  Frank Lipnizki,et al.  Pervaporation-based hybrid process: a review of process design, applications and economics , 1999 .

[2]  I. Ortiz,et al.  Pervaporation Technology for the Dehydration of Solvents and Raw Materials in the Process Industry , 2007 .

[3]  M. Menéndez,et al.  Preparation and characterization of two-layered mordenite-ZSM-5 bi-functional membranes , 2006 .

[4]  J. Llorens,et al.  Technical and economical feasibility of zeolite NaA membrane-based reactors in liquid-phase etherification reactions , 2009 .

[5]  T. Tsotsis,et al.  Models and experiments with pervaporation membrane reactors integrated with an adsorbent system , 2004 .

[6]  B. Mattiasson,et al.  Water activity control in enzymatic esterification processes , 1997 .

[7]  Leland M. Vane,et al.  High permeability membranes for the dehydration of low water content ethanol by pervaporation , 2007 .

[8]  T. Nakane,et al.  Application of FAU-type zeolite membranes to vapor/gas separation under high pressure and high temperature up to 5 MPa and 180 °C , 2007 .

[9]  Sun Bok Lee,et al.  Enzymatic esterification reaction in organic media with continuous water stripping: effect of water content on reactor performance and enzyme agglomeration , 1997 .

[10]  F. Kapteijn,et al.  Fischer–Tropsch synthesis with in situ H2O removal – Directions of membrane development , 2008 .

[11]  E. Drioli,et al.  HIGH TEMPERATURE MEMBRANE REACTORS AND INTEGRATED MEMBRANE OPERATIONS , 2002 .

[12]  Shih-Perng Tsai,et al.  Pervaporation-assisted esterification of lactic and succinic acids with downstream ester recovery , 2006 .

[13]  M. Rahimpour,et al.  Simultaneous utilization of two different membranes for intensification of ultrapure hydrogen produc , 2011 .

[14]  I. Agirre,et al.  A techno‐economic comparison of various process options for the production of 1,1‐diethoxy butane , 2012 .

[15]  King Lun Yeung,et al.  Experiments and modeling of membrane microreactors , 2005 .

[16]  I. Ortiz,et al.  Pervaporative dehydration of organic mixtures using a commercial silica membrane: Determination of kinetic parameters , 2005 .

[17]  Enrico Drioli,et al.  Membrane materials for addressing energy and environmental challenges. , 2012, Annual review of chemical and biomolecular engineering.

[18]  M. David,et al.  Ion-exchange membranes made of semi-interpenetrating polymer networks, used for pervaporation-assisted esterification and ion transport , 2003 .

[19]  Nándor Nemestóthy,et al.  Influence of pervaporation process parameters on enzymatic catalyst deactivation , 2004 .

[20]  K. Bélafi-Bakó,et al.  Large-scale enzymatic production of natural flavour esters in organic solvent with continuous water removal. , 2000, Journal of biotechnology.

[21]  Matthias Wessling,et al.  In situ product recovery: Submerged membranes vs. external loop membranes , 2012 .

[22]  Marc A. Dubé,et al.  Biodiesel Production Using Ultralow Catalyst Concentrations , 2008 .

[23]  M. Menéndez,et al.  Use of membranes in fischer-tropsch reactors , 2000 .

[24]  T. Melin,et al.  Performance efficiency of tubular inorganic membrane modules for pervaporation , 2005 .

[25]  Faïçal Larachi,et al.  Sorption-enhanced dimethyl ether synthesis—Multiscale reactor modeling , 2011 .

[26]  J. Armor Membrane catalysis: Where is it now, what needs to be done? , 1995 .

[27]  V. Salim,et al.  Brazilian Journal of Chemical Engineering ETHYL OLEATE PRODUCTION BY MEANS OF PERVAPORATION-ASSISTED ESTERIFICATION USING HETEROGENEOUS CATALYSIS , 2010 .

[28]  M. Ortiz,et al.  Mathematical modelling of styrene drying by adsorption onto activated alumina , 2002 .

[29]  W. Kiatkittipong,et al.  Simulation of pervaporation membrane reactors for liquid phase synthesis of ethyl tert-butyl ether from tert-butyl alcohol and ethanol , 2003 .

[30]  Jürgen Gmehling,et al.  Esterification of acetic acid with isopropanol coupled with pervaporation: Part II. Study of a pervaporation reactor , 2006 .

[31]  R. Borup,et al.  Dimethyl ether (DME) as an alternative fuel , 2006 .

[32]  P. Kreis,et al.  Scale‐up und detaillierte Prozessanalyse eines Membranreaktors am Beispiel einer heterogen katalysierten Veresterung , 2011 .

[33]  Ken-ichi Okamoto,et al.  Application of zeolite T membrane to vapor-permeation-aided esterification of lactic acid with ethanol , 2002 .

[34]  Mohammad Reza Rahimpour,et al.  Differential evolution (DE) strategy for optimization of hydrogen production and utilization in a th , 2011 .

[35]  F. Mizukami,et al.  Application of a CHA-type zeolite membrane to the esterification of adipic acid with isopropyl alcohol using sulfuric acid catalyst , 2012 .

[36]  Rafiqul Gani,et al.  Computer aided design, analysis and experimental investigation of membrane assisted batch reaction-separation systems , 2009, Comput. Chem. Eng..

[37]  Ken-ichi Okamoto,et al.  Application of Zeolite Membranes to Esterification Reactions , 2001 .

[38]  Zhen-Jia Zhang,et al.  Synthesis of long-term acid-stable zeolite membranes and their potential application to esterification reactions , 2009 .

[39]  Mohammad Reza Rahimpour,et al.  Simultaneous hydrogen production and utilization via coupling of Fischer–Tropsch synthesis and decalin dehydrogenation reactions in GTL technology , 2011 .

[40]  C. P. Borges,et al.  Synthesis of Ethyl Acetate by Coupling a Heterogeneous Catalytic System with a Pervaporation Unit , 2005 .

[41]  A. Basile,et al.  A theoretical analysis of methanol synthesis from CO2 and H2 in a ceramic membrane reactor , 2007 .

[42]  F. Kapteijn,et al.  Water vapour separation from permanent gases by a zeolite-4A membrane , 2005 .

[43]  B. List Emil Knoevenagel and the roots of aminocatalysis. , 2010, Angewandte Chemie.

[44]  Yi-Ming Sun,et al.  A catalytic membrane reactor: its performance in comparison with other types of reactors , 1990 .

[45]  M. Rohde,et al.  Improving carbon utilization in biomass conversion to synthetic Studies in Surface Science and Catalysishydrocarbons via Fischer-Tropsch synthesis , 2004 .

[46]  V. Salim,et al.  Synthesis and characterization of a catalytic membrane for pervaporation-assisted esterification reactors , 2008 .

[47]  I. Fonseca,et al.  Esterification of acetic acid by isoamylic alcohol over catalytic membranes of poly(vinyl alcohol) containing sulfonic acid groups , 2006 .

[48]  Y. S. Lin,et al.  Effects of water vapor on gas permeation and separation properties of MFI zeolite membranes at high temperatures , 2012 .

[49]  M. Sahimi,et al.  Design issues of pervaporation membrane reactors for esterification , 2002 .

[50]  Eduardo S. Pérez-Cisneros,et al.  Synthesis of n-propyl propionate in a pilot-plant reactive distillation column: Experimental study and simulation , 2012, Comput. Chem. Eng..

[51]  Tahereh Kaghazchi,et al.  Application of membrane separation processes in petrochemical industry: a review , 2009 .

[52]  M. Menéndez,et al.  Synthesis, characterization and separation properties of a composite mordenite/ZSM-5/chabazite hydrophilic membrane , 1998 .

[53]  F. Hai,et al.  Introduction - A review of membrane reactors , 2011 .

[54]  T. Tsuru Development of Metal-doped Silica Membranes for Increased Hydrothermal Stability and Their Applications to Membrane Reactors for Steam Reforming of Methane , 2011 .

[55]  King Lun Yeung,et al.  Zeolites in Microsystems for Chemical Synthesis and Energy Generation , 2009 .

[56]  Satish J. Parulekar Analysis of Pervaporation-Aided Esterification of Organic Acids , 2007 .

[57]  L Giorno,et al.  Biocatalytic membrane reactors: applications and perspectives. , 2000, Trends in biotechnology.

[58]  King Lun Yeung,et al.  Knoevenagel condensation reaction between benzaldehyde and ethyl acetoacetate in microreactor and membrane microreactor , 2008 .

[59]  T. Qiu,et al.  Novel Procedure for Coproduction of Ethyl Acetate and n-Butyl Acetate by Reactive Distillation , 2012 .

[60]  F. Larachi,et al.  Dimethyl Ether Synthesis with in situ H2O Removal in Fixed-Bed Membrane Reactor: Model and Simulations† , 2010 .

[61]  K. Wasewar,et al.  Esterification of lactic acid with ethanol in a pervaporation reactor: modeling and performance study , 2009 .

[62]  Design Directions for Composite Catalytic Hollow Fibre Membranes for Condensation Reactions , 2004 .

[63]  A. Moheb,et al.  Vapor-permeation-aided esterification of isopropanol/propionic acid using NaA and PERVAP® 2201 membranes , 2010 .

[64]  J. Bilbao,et al.  Deactivation and regeneration of hybrid catalysts in the single-step synthesis of dimethyl ether from syngas and CO2 , 2005 .

[65]  Q. Liu,et al.  Modeling of esterification of acetic acid with n-butanol in the presence of Zr(SO4)2·4H2O coupled pervaporation , 2002 .

[66]  F. Kapteijn,et al.  Application of a sodalite membrane reactor in esterification—Coupling reaction and separation , 2010 .

[67]  S. Dinçer,et al.  Esterification of Acetic Acid and Isobutanol in a Pervaporation Membrane Reactor Using Different Membranes , 2011 .

[68]  Jürgen Gmehling,et al.  Esterification of acetic acid with isopropanol coupled with pervaporation: Part I: Kinetics and pervaporation studies , 2006 .

[69]  M. Iliuta,et al.  Integrated aqueous-phase glycerol reforming to dimethyl ether synthesis—A novel allothermal dual bed membrane reactor concept , 2012 .

[70]  P. Pfromm,et al.  Real time measurement and control of thermodynamic water activities for enzymatic catalysis in hexane. , 2005, Journal of biotechnology.

[71]  Costin Sorin Bildea,et al.  A review of biodiesel production by integrated reactive separation technologies , 2012 .

[72]  M. Menéndez,et al.  Mordenite and ZSM-5 hydrophilic tubular membranes for the separation of gas phase mixtures , 2000 .

[73]  Y. Hidaka,et al.  High-temperature pyrolysis of dimethyl ether in shock waves , 2000 .

[74]  B. Sea,et al.  Preparation of hydrophilic ceramic membranes for a dehydration membrane reactor , 2006 .

[75]  F. Kapteijn,et al.  Practical Approach to Zeolitic Membranes and Coatings: State of the Art, Opportunities, Barriers, and Future Perspectives , 2012 .

[76]  Thomas A. Litzinger,et al.  Effects of oxygenated additives on aromatic species in fuel-rich, premixed ethane combustion: a modeling study , 2003 .

[77]  T. Miyata,et al.  Membrane reactor for acceleration of esterification using a special ionic liquid with reaction and separation and microwave heating , 2012 .

[78]  R. Gemert,et al.  Performing Esterification Reactions by Combining Heterogeneous Catalysis and Pervaporation in a Batch Process , 2005 .

[79]  G. Olah,et al.  Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons. , 2009, The Journal of organic chemistry.

[80]  U. Bornscheuer,et al.  Efficient water removal in lipase-catalyzed esterifications using a low-boiling-point azeotrope. , 2002, Biotechnology and bioengineering.

[81]  M. Menéndez,et al.  Continuous zeolite membrane reactor for esterification of ethanol and acetic acid , 2007 .

[82]  Ivo F J Vankelecom,et al.  Polymeric membranes in catalytic reactors. , 2002, Chemical reviews.

[83]  H. Kita,et al.  Vapor-permeation-aided esterification of oleic acid , 1994 .

[84]  U. Bornscheuer,et al.  Lipase-catalyzed glucose fatty acid ester synthesis in ionic liquids. , 2005, Organic letters.

[85]  H. Kita,et al.  PERVAPORATION-AIDED ESTERIFICATION OF OLEIC ACID , 1993 .

[86]  Fujio Mizukami,et al.  Stoichiometric Ester Condensation Reaction Processes by Pervaporative Water Removal via Acid-Tolerant Zeolite Membranes , 2007 .

[87]  C. Téllez,et al.  Zeolite Membrane Reactors , 2011 .

[88]  I. Agirre,et al.  The Conceptual Design of a Continuous Pervaporation Membrane Reactor for the Production of 1,1-Diethoxy Butane , 2012 .

[89]  I Agirre,et al.  Catalytic reactive distillation process development for 1,1 diethoxy butane production from renewable sources. , 2011, Bioresource technology.

[90]  Kamalesh K. Sirkar,et al.  MEMBRANE SEPARATION TECHNOLOGIES: CURRENT DEVELOPMENTS , 1997 .

[91]  Qiang Xu,et al.  Biodiesel production from esterification of oleic acid over aminophosphonic acid resin D418 , 2012 .

[92]  Sau Man Lai,et al.  Knoevenagel condensation reaction in zeolite membrane microreactor , 2003 .

[93]  Enrico Drioli,et al.  Membrane engineering in process intensificationAn overview , 2011 .

[94]  M. Menéndez,et al.  Synthesis of MTBE in zeolite membrane reactors , 2000 .

[95]  I. Ortiz,et al.  Pervaporative dehydration of industrial solvents using a zeolite NaA commercial membrane , 2003 .

[96]  I. Ortiz,et al.  Pervaporative recovery of acetic acid from an acetylation industrial effluent using commercial membranes , 2005 .

[97]  B. Swamy,et al.  Preparation and characterization of 4A zeolite‐filled mixed matrix membranes for pervaporation dehydration of isopropyl alcohol , 2011 .

[98]  M. Sanz,et al.  Ethyl lactate production via esterification of lactic acid with ethanol combined with pervaporation , 2010 .

[99]  Ana M. Eliceche,et al.  Comparative behaviour of hydrophilic membranes in the pervaporative dehydration of cyclohexane , 2006 .

[100]  Shih-Perng Tsai,et al.  Esterification of Lactic Acid and Ethanol with/without Pervaporation , 2003 .

[101]  Kamalesh K. Sirkar,et al.  Membrane in a reactor: A functional perspective , 1999 .

[102]  M. F. Malone,et al.  Semibatch Reactive Distillation for Isopropyl Acetate Synthesis , 2011 .

[103]  H. Neomagus,et al.  A Predictive Model for Permeation Flux in a Membrane Reactor: Aspects of Esterification , 2005 .

[104]  Y. Sekine,et al.  Selective permeation and separation of steam from water–methanol–hydrogen gas mixtures through mordenite membrane , 2008 .

[105]  K. Yeung,et al.  An investigation of Knoevenagel condensation reaction in microreactors using a new zeolite catalyst , 2004 .

[106]  R. Hughes,et al.  Enhancement of esterification reaction yield using zeolite A vapour permeation membrane , 2002 .

[107]  P. Halling,et al.  Use of salt hydrates to buffer optimal water level during lipase catalysed in synthesis in organic media: a practical procedure for organic chemists , 1992 .

[108]  Manh Hoang,et al.  A review of water recovery by vapour permeation through membranes. , 2012, Water research.

[109]  A. Urtiaga,et al.  Dehydration of Industrial Ketonic Effluents by Pervaporation. Comparative Behavior of Ceramic and Polymeric Membranes , 2003 .

[110]  Ana M. Eliceche,et al.  Optimisation of azeotropic distillation columns combined with pervaporation membranes , 2002 .

[111]  Jtf Jos Keurentjes,et al.  Preparation of zeolite-coated pervaporation membranes for the integration of reaction and separation , 2005 .

[112]  J. N. Armor,et al.  Applications of catalytic inorganic membrane reactors to refinery products , 1998 .

[113]  S. Sridhar,et al.  Preparation of fatty acid methyl ester through temperature gradient driven pervaporation process , 2010 .

[114]  Robert Y. M. Huang,et al.  Studies of a membrane reactor: Esterification facilitated by pervaporation , 1996 .

[115]  A. Gavriilidis,et al.  Design and fabrication of zeolite-based microreactors and membrane microseparators , 2001 .

[116]  U. Ehrenstein,et al.  Manufacture of an environmental-safe biolubricant from fusel oil by enzymatic esterification in solvent-free system , 2004 .

[117]  Alessia Arteconi,et al.  Emissions from Ethers and Organic Carbonate Fuel Additives: A Review , 2011 .

[118]  M. Rohde,et al.  Membrane application in Fischer–Tropsch synthesis reactors—Overview of concepts , 2005 .

[119]  A. Basile,et al.  An experimental study of CO2 hydrogenation into methanol involving a zeolite membrane reactor , 2004 .

[120]  Mohammad Reza Rahimpour,et al.  A novel water perm-selective membrane dual-type reactor concept for Fischer–Tropsch synthesis of GTL (gas to liquid) technology , 2011 .

[121]  A. Trusek-Holownia,et al.  An integrated process: ester synthesis in an enzymatic membrane reactor and water sorption. , 2007, Journal of biotechnology.

[122]  E. Drioli,et al.  Methanol as an Energy Source and/or Energy Carrier in Membrane Processes , 2007 .

[123]  M. Menéndez,et al.  Coupling of reaction and separation at the microscopic level: esterification processes in a H-ZSM-5 membrane reactor , 2002 .

[124]  I. Ortiz,et al.  Pervaporation of azeotropic mixtures ethanol/ethyl tert-butyl ether: influence of membrane conditioning and operation variables on pervaporation flux☆ , 2002 .

[125]  J. Caro,et al.  Zeolite Membranes: From the Laboratory Scale to Technical Applications , 2005 .