Ultrasonic enhancement of the supercritical extraction from ginger.

This work examines the concurrent use of power ultrasound during the extraction of pungent compounds from a typical herb (ginger) with supercritical CO(2). A power ultrasonic transducer with an operating frequency of 20 kHz is connected to an extraction vessel and the extraction of gingerols from freeze-dried ginger particles (4-8 mm) is monitored. In the presence of ultrasound, we find that both the extraction rate and the yield increase. The higher extraction rate is attributed to disruption of the cell structures and an increase in the accessibility of the solvent to the internal particle structure, which enhances the intra-particle diffusivity. While cavitation would readily account for such enhancement in ambient processes, the absence of phase boundaries should exclude such phenomena above the critical point. Possible alternate mechanisms for the cell structure damage are discussed.

[1]  Din-Chung Liou,et al.  Fluid—solid mass transfer in a supercritical fluid extractor , 1988 .

[2]  J A Gallego,et al.  Mass transfer enhancement in supercritical fluids extraction by means of power ultrasound. , 2004, Ultrasonics sonochemistry.

[3]  G. Price,et al.  Ultrasonically initiated polymerization of methyl methacrylate , 1991 .

[4]  C. Marrone,et al.  Almond oil extraction by supercritical CO2: experiments and modelling , 1998 .

[5]  H. M. Cheung,et al.  Ultrasound Assisted Polymerization of Mma and Styrene in near Critical Co2 , 2005 .

[6]  C. Wai,et al.  Ultrasound enhancement of dissolution kinetics of uranium oxides in supercritical carbon dioxide , 2001 .

[7]  C. P. Hicks,et al.  Gas-liquid critical properties of binary mixtures , 1975 .

[8]  H. Sovová,et al.  Rate of the vegetable oil extraction with supercritical CO2—I. Modelling of extraction curves , 1994 .

[9]  M. Palma,et al.  Ultrasound-assisted extraction of soy isoflavones. , 2003, Journal of chromatography. A.

[10]  Christophe Gourdon,et al.  Investigation in solid-liquid extraction: influence of ultrasound , 2002 .

[11]  M. Spiro,et al.  Extraction of ginger rhizome: kinetic studies with supercritical carbon dioxide , 2007 .

[12]  A. Adamson A textbook of physical chemistry , 1973 .

[13]  J. Keurentjes,et al.  Cavitation-Induced Reactions in High-Pressure Carbon Dioxide , 2002, Science.

[14]  F. Marken,et al.  High-pressure sonoelectrochemistry in aqueous solution: Soft cavitation under CO2 , 1998 .

[15]  H. Johnstone,et al.  Heat and mass transfer in packed beds , 1955 .

[16]  L. H. Thompson,et al.  Sonochemistry: Science and Engineering , 1999 .

[17]  Chien M. Wai,et al.  Ultrasound-enhanced dissolution of UO2 in supercritical CO2 containing a CO2-Philic complexant of tri-n-butylphosphate and nitric acid , 2002 .

[18]  D. Mcqueen Ultrasonically enhanced chemical dissociation from solid surfaces with application to cleaning electronic circuit boards , 1990 .

[19]  R. Sadus High Pressure Phase Behaviour of Multicomponent Fluid Mixtures , 1992 .