Shock initiation and hot spots in plastic-bonded 1,3,5-triamino-2,4,6-trinitrobenzene (TATB)

TATB (1,3,5-triamino-2,4,6-trinitrobenzene) is a powerful explosive whose dynamical behavior is difficult to study because TATB is so insensitive to initiation by shock waves. We used a tabletop microscope equipped with 0–4.5 km/s laser-launched flyer plates to study shock initiation of TATB, which was fabricated in the form of an array of hundreds of plastic-bonded explosive minicharges (X-TATB = 80% TATB + 20% Sylgard 182 polymer). The 4 ns shocks from the flyer plates were not effective in initiating TATB, but we also developed a two-layer array where flyers first initiated a plastic-bonded PETN (pentaerythritol tetranitrate) charge (X-PETN = 80% PETN + 20% Sylgard), which drove an initiating 25 ns shock into the X-TATB. Thermal emission from shocked X-TATB was used to measure time-dependent temperature profiles with a resolution of 2 ns and to produce high-speed (5 ns) videos. In X-TATB, flyer plates produced 2500–3500 K hot spots and combustion at 2500 K. With X-PETN initiators, X-TATB had 3500–4000 K hot spots and a powerful volume explosion lasting a few nanoseconds. Prospects for producing TATB detonations on a tabletop are discussed.TATB (1,3,5-triamino-2,4,6-trinitrobenzene) is a powerful explosive whose dynamical behavior is difficult to study because TATB is so insensitive to initiation by shock waves. We used a tabletop microscope equipped with 0–4.5 km/s laser-launched flyer plates to study shock initiation of TATB, which was fabricated in the form of an array of hundreds of plastic-bonded explosive minicharges (X-TATB = 80% TATB + 20% Sylgard 182 polymer). The 4 ns shocks from the flyer plates were not effective in initiating TATB, but we also developed a two-layer array where flyers first initiated a plastic-bonded PETN (pentaerythritol tetranitrate) charge (X-PETN = 80% PETN + 20% Sylgard), which drove an initiating 25 ns shock into the X-TATB. Thermal emission from shocked X-TATB was used to measure time-dependent temperature profiles with a resolution of 2 ns and to produce high-speed (5 ns) videos. In X-TATB, flyer plates produced 2500–3500 K hot spots and combustion at 2500 K. With X-PETN initiators, X-TATB had 3500–4000 ...

[1]  L. Salvati,et al.  Shock Initiation Microscopy with High Time and Space Resolution , 2020 .

[2]  D. Dlott,et al.  Hot Spot Chemistry in Several Polymer‐Bound Explosives under Nanosecond Shock Conditions , 2019 .

[3]  L. Salvati,et al.  Hot-spot generation and growth in shocked plastic-bonded explosives studied by optical pyrometry , 2019, Journal of Applied Physics.

[4]  D. Dlott,et al.  Dynamic absorption in optical pyrometry of hot spots in plastic-bonded triaminotrinitrobenzene , 2019, Applied Physics Letters.

[5]  K. Suslick,et al.  Shock Wave Energy Absorption in Metal-Organic Framework. , 2019, Journal of the American Chemical Society.

[6]  L. Salvati,et al.  Optical windows as materials for high-speed shock wave detectors , 2018, AIP Advances.

[7]  A. S. Tappan,et al.  Ultrafast Shock-Induced Reactions in Pentaerythritol Tetranitrate Thin Films. , 2018, The journal of physical chemistry. A.

[8]  D. Dlott,et al.  Detonation on a tabletop: Nitromethane with high time and space resolution , 2018, Journal of Applied Physics.

[9]  K. Suslick,et al.  Shock wave dissipation by metal organic framework , 2018 .

[10]  杨镇,et al.  梯恩梯(TNT)爆轰初期形成富碳团簇分子及类石墨结构的分子动力学模拟 , 2018 .

[11]  T. Aslam,et al.  Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman , 2018 .

[12]  Qikai Li,et al.  Carbon-rich Clusters and Graphite-like Structure Formation during Early Detonation of 2,4,6-Trinitrotoluene (TNT) via Molecular Dynamics Simulation , 2018 .

[13]  A. Nakano,et al.  Multiple Reaction Pathways in Shocked 2,4,6-Triamino-1,3,5-trinitrobenzene Crystal , 2017 .

[14]  D. Dlott,et al.  32-channel pyrometer with high dynamic range for studies of shocked nanothermites , 2017 .

[15]  D. Dlott,et al.  Multichannel emission spectrometer for high dynamic range optical pyrometry of shock-driven materials. , 2016, The Review of scientific instruments.

[16]  D. Dlott,et al.  High dynamic range emission measurements of shocked energetic materials: Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) , 2016 .

[17]  A. Banishev,et al.  High-Speed Laser-Launched Flyer Impacts Studied with Ultrafast Photography and Velocimetry , 2016, Journal of Dynamic Behavior of Materials.

[18]  D. Dlott Shock compression dynamics under a microscope , 2015 .

[19]  K. Suslick,et al.  Mechanochemistry for Shock Wave Energy Dissipation , 2015 .

[20]  Michel Doucet,et al.  In-situ Raman spectroscopy and high-speed photography of a shocked triaminotrinitrobenzene based explosive , 2015 .

[21]  Min Zhou,et al.  Computational analysis of temperature rises in microstructures of HMX-Estane PBXs , 2013 .

[22]  Seokpum Kim,et al.  Ignition criterion for heterogeneous energetic materials based on hotspot size-temperature threshold , 2013 .

[23]  T. Ghosh,et al.  2,4,6-triamino-1,3,5-trinitrobenzene (TATB) and TATB-based formulations--a review. , 2010, Journal of hazardous materials.

[24]  D. M. Hoffman,et al.  The Microstructure of TATB‐Based Explosive Formulations During Temperature Cycling Using Ultra‐Small‐Angle X‐Ray Scattering , 2009 .

[25]  E. Reed,et al.  Nitrogen-rich heterocycles as reactivity retardants in shocked insensitive explosives. , 2009, Journal of the American Chemical Society.

[26]  Craig M. Tarver,et al.  Critical conditions for impact- and shock-induced hot spots in solid explosives , 1996 .

[27]  N. Hetherington,et al.  Aging effects on the detonation velocity of XTX-8003☆ , 1980 .

[28]  Jerry Wackerle,et al.  Shock Initiation of XTX‐8003 and Pressed PETN , 1970 .