High-resolution ac-pulse modulated electrohydrodynamic jet printing on highly insulating substrates

This paper presents a new high-resolution ac-pulse modulated electrohydrodynamic (EHD)-jet printing technology on highly insulating substrates for drop-on-demand fabrication of electrical features and interconnects using silver nanoink. In traditional EHD-jet printing, the remained charge of the printed droplets changes the electrostatic field distribution and interrupts the follow-on printing behavior, especially for highly insulating substrates which have slow charge decay rates. The residue charge makes the control of EHD-jet printing very challenging for high-resolution continuous features. In this paper, by using modulated ac-pulsed voltage, the EHD-jet printing process switches the charge polarity of the consequent droplets to neutralize the charge on the substrate. The effect of the residue charge is minimized, which enables high-resolution printing of continuous patterns. Moreover, by modulating the pulse frequency, voltage, and duration, the EHD-jet printing behavior can be controlled with respect to printing speed/frequency and droplet size. Printing frequency is directly controlled by the pulse frequency, and the droplet dimension is controlled by the voltage and the duration of the pulse. We demonstrated that ac-pulse modulated EHD-jet printing can overcome the long-predicated charge accumulation problem on highly insulating substrates, and potentially be applied to many flexible electronics applications.

[1]  A. Gañán-Calvo,et al.  The supercritical nature of electrohydrodynamically driven capillary microjets emitted in the EHD spraying of liquids , 1996 .

[2]  Alfonso M. Gañán-Calvo,et al.  Current and droplet size in the electrospraying of liquids. Scaling laws , 1997 .

[3]  A. Gañán-Calvo On the general scaling theory for electrospraying , 2004, Journal of Fluid Mechanics.

[4]  Leslie Y Yeo,et al.  A new ac electrospray mechanism by Maxwell-Wagner polarization and capillary resonance. , 2004, Physical review letters.

[5]  H W Li,et al.  Dewetting of conducting polymer inkjet droplets on patterned surfaces , 2004, Nature materials.

[6]  Ilhan A. Aksay,et al.  Electrohydrodynamic “drop-and-place” particle deployment , 2006 .

[7]  John A Rogers,et al.  High-resolution electrohydrodynamic jet printing. , 2007, Nature materials.

[8]  Dae-Young Lee,et al.  Electrohydrodynamic printing of silver nanoparticles by using a focused nanocolloid jet , 2007 .

[9]  U. Schubert,et al.  Inkjet Printing of Narrow Conductive Tracks on Untreated Polymeric Substrates , 2008 .

[10]  Takao Someya,et al.  Organic transistors manufactured using inkjet technology with subfemtoliter accuracy , 2008, Proceedings of the National Academy of Sciences.

[11]  Yong-Young Noh,et al.  Polarity Effects of Polymer Gate Electrets on Non‐Volatile Organic Field‐Effect Transistor Memory , 2008 .

[12]  R. Collins,et al.  Electrohydrodynamic tip streaming and emission of charged drops from liquid cones , 2008 .

[13]  G. Lim,et al.  Electrohydrodynamic repulsion of droplets falling on an insulating substrate in an electric field , 2009 .

[14]  J. F. Dijksman,et al.  Relaxation times in single event electrospraying controlled by nozzle front surface modification. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[15]  Doyoung Byun,et al.  Mechanism of electrohydrodynamic printing based on ac voltage without a nozzle electrode , 2009 .

[16]  John A Rogers,et al.  Nanoscale, electrified liquid jets for high-resolution printing of charge. , 2010, Nano letters.

[17]  Ke Wang,et al.  Direct fabrication of electrically functional microstructures by fully voltage-controlled electrohydrodynamic jet printing of silver nano-ink , 2010 .

[18]  M Paturzo,et al.  Dispensing nano-pico droplets and liquid patterning by pyroelectrodynamic shooting. , 2010, Nature nanotechnology.

[19]  P. M. Ferreira,et al.  High-speed and drop-on-demand printing with a pulsed electrohydrodynamic jet , 2010 .

[20]  Henning Sirringhaus,et al.  High yield, single droplet electrode arrays for nanoscale printed electronics. , 2010, ACS nano.

[21]  M. Tiwari,et al.  On the Principles of Printing Sub‐micrometer 3D Structures from Dielectric‐Liquid‐Based Colloids , 2011 .

[22]  H. Matsui,et al.  Inkjet printing of single-crystal films , 2011, Nature.

[23]  Jeonghyun Kim,et al.  Patterned oxide semiconductor by electrohydrodynamic jet printing for transparent thin film transistors , 2012 .

[24]  S. Chua,et al.  Jettable fluid space and jetting characteristics of a microprint head , 2012, Journal of Fluid Mechanics.

[25]  Kyung Hyun Choi,et al.  Fine resolution drop-on-demand electrohydrodynamic patterning of conductive silver tracks on glass substrate , 2013 .

[26]  Sam S. Yoon,et al.  Effects of pulsing frequency on characteristics of electrohydrodynamic inkjet using micro-Al and nano-Ag particles , 2013 .

[27]  Fei Huang,et al.  All-solution processed polymer light-emitting diode displays , 2013, Nature Communications.

[28]  D. Poulikakos,et al.  Open-atmosphere sustenance of highly volatile attoliter-size droplets on surfaces , 2013, Proceedings of the National Academy of Sciences.

[29]  Ronn Andriessen,et al.  Inkjet Printing of Back Electrodes for Inverted Polymer Solar Cells , 2013 .

[30]  Doyoung Byun,et al.  Invisible metal-grid transparent electrode prepared by electrohydrodynamic (EHD) jet printing , 2013 .

[31]  Yong-Young Noh,et al.  Large-scale organic nanowire lithography and electronics , 2013, Nature Communications.

[32]  Yong-Young Noh,et al.  Toward Printed Integrated Circuits based on Unipolar or Ambipolar Polymer Semiconductors , 2013, Advanced materials.