Direct synthesis of gasoline and diesel range branched alkanes with acetone from lignocellulose

For the first time, gasoline and diesel range C6–C15 branched alkanes were directly synthesized in a high carbon yield (∼80%) by the self-condensation of acetone and subsequent hydrodeoxygenation over a dual-bed catalyst system.

[1]  Xue-qing Gong,et al.  Direct hydrodeoxygenation of raw woody biomass into liquid alkanes , 2016, Nature Communications.

[2]  Jie Xu,et al.  Production of Diethyl Terephthalate from Biomass-Derived Muconic Acid. , 2016, Angewandte Chemie.

[3]  R. Chen,et al.  Enhancing acetone biosynthesis and acetone-butanol-ethanol fermentation performance by co-culturing Clostridium acetobutylicum/Saccharomyces cerevisiae integrated with exogenous acetate addition. , 2016, Bioresource technology.

[4]  David Linke,et al.  ZrO2 -Based Alternatives to Conventional Propane Dehydrogenation Catalysts: Active Sites, Design, and Performance. , 2015, Angewandte Chemie.

[5]  Qinghong Zhang,et al.  Oxidative conversion of lignin and lignin model compounds catalyzed by CeO2-supported Pd nanoparticles , 2015 .

[6]  Arne Thomas,et al.  Controlling hydrogenation selectivity with Pd catalysts on carbon nitrides functionalized silica , 2015 .

[7]  Eric R. Sacia,et al.  Highly selective condensation of biomass-derived methyl ketones as a source of aviation fuel. , 2015, ChemSusChem.

[8]  Eric R. Sacia,et al.  Synthesis of biomass-derived methylcyclopentane as a gasoline additive via aldol condensation/hydrodeoxygenation of 2,5-hexanedione , 2015 .

[9]  Xue-Qing Gong,et al.  Pd/NbOPO₄ multifunctional catalyst for the direct production of liquid alkanes from aldol adducts of furans. , 2014, Angewandte Chemie.

[10]  Fei Liu,et al.  Combination of Pd/C and Amberlyst-15 in a single reactor for the acid/hydrogenating catalytic conversion of carbohydrates to 5-hydroxy-2,5-hexanedione , 2014 .

[11]  Fei Liu,et al.  Palladium/Carbon dioxide cooperative catalysis for the production of diketone derivatives from carbohydrates. , 2014, ChemSusChem.

[12]  Yuriy Román‐Leshkov,et al.  Insights into the catalytic activity and surface modification of MoO3 during the hydrodeoxygenation of lignin-derived model compounds into aromatic hydrocarbons under low hydrogen pressures , 2014 .

[13]  Jianji Wang,et al.  Formation of C–C bonds for the production of bio-alkanes under mild conditions , 2014 .

[14]  P. Ford,et al.  Catalytic conversion of nonfood woody biomass solids to organic liquids. , 2014, Accounts of chemical research.

[15]  D. Resasco,et al.  Kinetics and Mechanism of Ketonization of Acetic Acid on Ru/TiO2 Catalyst , 2014, Topics in catalysis.

[16]  Catherine Pinel,et al.  Conversion of biomass into chemicals over metal catalysts. , 2014, Chemical reviews.

[17]  Inaki Gandarias,et al.  Hydrodeoxygenation of the angelica lactone dimer, a cellulose-based feedstock: simple, high-yield synthesis of branched C7 -C10 gasoline-like hydrocarbons. , 2014, Angewandte Chemie.

[18]  Avelino Corma,et al.  Conversion of biomass platform molecules into fuel additives and liquid hydrocarbon fuels , 2014 .

[19]  R. Rinaldi,et al.  A route for lignin and bio-oil conversion: dehydroxylation of phenols into arenes by catalytic tandem reactions. , 2013, Angewandte Chemie.

[20]  Yuriy Román-Leshkov,et al.  Domino reaction catalyzed by zeolites with Brønsted and Lewis acid sites for the production of γ-valerolactone from furfural. , 2013, Angewandte Chemie.

[21]  Z. Cao,et al.  Chemical synthesis of lactic acid from cellulose catalysed by lead(II) ions in water , 2013, Nature Communications.

[22]  Suresh Mutyala,et al.  Selective hydrogenation of the CC bond of α,β-unsaturated carbonyl compounds over PdNPs–SBA-15 in a water medium , 2013 .

[23]  Q. Guo,et al.  Linked strategy for the production of fuels via formose reaction , 2013, Scientific Reports.

[24]  F. Dean Toste,et al.  Integration of chemical catalysis with extractive fermentation to produce fuels , 2012, Nature.

[25]  D. Resasco,et al.  Aqueous-phase ketonization of acetic acid over Ru/TiO2/carbon catalysts , 2012 .

[26]  R. Rinaldi,et al.  Exploiting H-transfer reactions with RANEY® Ni for upgrade of phenolic and aromatic biorefinery feeds under unusual, low-severity conditions , 2012 .

[27]  Chen Zhao,et al.  Selective catalytic hydroalkylation and deoxygenation of substituted phenols to bicycloalkanes , 2012 .

[28]  P. Ford,et al.  One-pot catalytic conversion of cellulose and of woody biomass solids to liquid fuels. , 2011, Journal of the American Chemical Society.

[29]  G. Huber,et al.  Production of furfural and carboxylic acids from waste aqueous hemicellulose solutions from the pulp and paper and cellulosic ethanol industries , 2011 .

[30]  A. Corma,et al.  Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts , 2011 .

[31]  Avelino Corma,et al.  Production of high-quality diesel from biomass waste products. , 2011, Angewandte Chemie.

[32]  D. M. Alonso,et al.  Catalytic conversion of biomass to biofuels , 2010 .

[33]  Xiaolai Wang,et al.  Cr, Zr-incorporated hydrotalcites and their application in the synthesis of isophorone , 2010 .

[34]  Benjamin G. Harvey,et al.  Synthesis of renewable jet and diesel fuels from 2-ethyl-1-hexene , 2010 .

[35]  Dong Wang,et al.  Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels , 2010, Science.

[36]  J. Dumesic,et al.  Vapour-phase C–C coupling reactions of biomass-derived oxygenates over Pd/CeZrOx catalysts , 2009 .

[37]  A. Corma,et al.  Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. , 2006, Chemical reviews.

[38]  G. Huber,et al.  Production of Liquid Alkanes by Aqueous-Phase Processing of Biomass-Derived Carbohydrates , 2005, Science.

[39]  J. I. D. Cosimo,et al.  Synthesis of α,β-unsaturated ketones over thermally activated Mg–Al hydrotalcites , 1998 .

[40]  Philippe Sautet,et al.  Competitive C=C and C=O adsorption of α-β unsaturated aldehydes on Pt and Pd surfaces in relation with the selectivity of hydrogenation reactions : a theoretical approach , 1995 .

[41]  A. Corma,et al.  Synthesis of high quality alkyl naphthenic kerosene by reacting an oil refinery with a biomass refinery stream , 2015 .

[42]  Benjamin G. Harvey,et al.  The role of butanol in the development of sustainable fuel technologies , 2011 .

[43]  T. Eggeman,et al.  Recovery of organic acids from fermentation broths , 2005, Applied Biochemistry and Biotechnology.