Current Status of Nanoclay Phytotoxicity

The use of nanotechnology in several fields has created a great interest and its rapid development with application in material science, nanomedicine, medical diagnosis, computer chips, catalysis, and so on.

[1]  C. Geri,et al.  The effects of nano-TiO2 on seed germination, development and mitosis of root tip cells of Vicia narbonensis L. and Zea mays L , 2011 .

[2]  T. Xia,et al.  Toxic Potential of Materials at the Nanolevel , 2006, Science.

[3]  Mingxian Liu,et al.  Recent advance in research on halloysite nanotubes-polymer nanocomposite , 2014 .

[4]  Selective desorption characteristics of halloysite nanotubes for anionic azo dyes , 2014 .

[5]  Yingqing Zhan,et al.  Novel polyvinylidene fluoride nanofiltration membrane blended with functionalized halloysite nanotubes for dye and heavy metal ions removal. , 2016, Journal of hazardous materials.

[6]  G. Schroeder,et al.  High decrease in soil metal bioavailability by metal immobilization with halloysite clay , 2015, Environmental Chemistry Letters.

[7]  P. M. Neumann,et al.  Colloidal suspensions of clay or titanium dioxide nanoparticles can inhibit leaf growth and transpiration via physical effects on root water transport. , 2009, Plant, cell & environment.

[8]  Pengwei Huo,et al.  Effect of metal ion (Zn2+, Bi3+, Cr3+, and Ni2+)-doped CdS/halloysite nanotubes (HNTs) photocatalyst for the degradation of tetracycline under visible light , 2015 .

[9]  Xiazhang Li,et al.  Hierarchical La0.7Ce0.3FeO3/halloysite nanocomposite for photocatalytic degradation of antibiotics , 2016 .

[10]  Giuseppe Lazzara,et al.  Ecocompatible Halloysite/Cucurbit[8]uril Hybrid as Efficient Nanosponge for Pollutants Removal , 2016 .

[11]  Jianfeng Chen,et al.  Assembled alginate/chitosan micro-shells for removal of organic pollutants , 2009 .

[12]  Y. Lvov,et al.  Self-healing coatings based on halloysite clay polymer composites for protection of copper alloys. , 2013, ACS applied materials & interfaces.

[13]  Zhouqing Xu,et al.  The Enhanced Catalytic Activities of Asymmetric Au-Ni Nanoparticle Decorated Halloysite-Based Nanocomposite for the Degradation of Organic Dyes , 2016, Nanoscale Research Letters.

[14]  Jing Ouyang,et al.  Metal oxide nanoparticles deposited onto carbon-coated halloysite nanotubes , 2014 .

[15]  Y. Lvov,et al.  Evaluation of toxicity of nanoclays and graphene oxide in vivo: a Paramecium caudatum study , 2016 .

[16]  Dimitrios Stampoulis,et al.  Assay-dependent phytotoxicity of nanoparticles to plants. , 2009, Environmental science & technology.

[17]  Jin-dun Liu,et al.  The removal of dye from aqueous solution using alginate-halloysite nanotube beads. , 2012 .

[18]  M. Radziemska,et al.  CONTENT OF SELECTED HEAVY METALS IN NI-CONTAMINATED SOIL FOLLOWING THE APPLICATION OF HALLOYSITE AND ZEOLITE , 2016 .

[19]  G. Lazzara,et al.  Synthesis and Characterization of Halloysite–Cyclodextrin Nanosponges for Enhanced Dyes Adsorption , 2017 .

[20]  P. Słomkiewicz,et al.  Possible use of halloysite in phytoremediation of soils contaminated with heavy metals , 2012 .

[21]  P. E. Poh,et al.  Halloysite/alginate nanocomposite beads: Kinetics, equilibrium and mechanism for lead adsorption , 2016 .

[22]  Stephen Mann,et al.  Nanoparticles can cause DNA damage across a cellular barrier. , 2009, Nature nanotechnology.

[23]  Y. Lvov,et al.  Enlargement of halloysite clay nanotube lumen by selective etching of aluminum oxide. , 2012, ACS nano.

[24]  K. Berent,et al.  Hybrid photosensitizer based on halloysite nanotubes for phenol-based pesticide photodegradation , 2015 .

[25]  Y. Lvov,et al.  Biomimetic cell-mediated three-dimensional assembly of halloysite nanotubes. , 2013, Chemical communications.

[26]  Hongda Chen,et al.  Nanoscale Science and Engineering for Agriculture and Food Systems , 2012 .

[27]  Liqun Zhang,et al.  Nanodot-Loaded Clay Nanotubes as Green and Sustained Radical Scavengers for Elastomer , 2017 .

[28]  Junliang Sun,et al.  Zeolite A synthesized from alkaline assisted pre-activated halloysite for efficient heavy metal removal in polluted river water and industrial wastewater. , 2017, Journal of environmental sciences.

[29]  Eric Eslinger,et al.  Clay minerals for petroleum geologists and engineers , 1988 .

[30]  Y. Lvov,et al.  Toxicity of halloysite clay nanotubes in vivo: a Caenorhabditis elegans study , 2015 .

[31]  Faheem Ahmed,et al.  Nanobiotechnology: Scope and Potential for Crop Improvement , 2013 .

[32]  Baoshan Xing,et al.  Phytotoxicity of nanoparticles: inhibition of seed germination and root growth. , 2007, Environmental pollution.

[33]  D. Mills,et al.  Enhanced efficiency of antiseptics with sustained release from clay nanotubes , 2014 .

[34]  J. Matusik,et al.  Enhanced heavy metal adsorption on functionalized nanotubular halloysite interlayer grafted with aminoalcohols , 2014 .

[35]  Giuseppe Lazzara,et al.  Covalently modified halloysite clay nanotubes: synthesis, properties, biological and medical applications. , 2017, Journal of materials chemistry. B.

[36]  Xiazhang Li,et al.  Halloysite–CeO2–AgBr nanocomposite for solar light photodegradation of methyl orange , 2015 .

[37]  Mingliang Du,et al.  Green synthesis of halloysite nanotubes supported Ag nanoparticles for photocatalytic decomposition of methylene blue , 2012 .

[38]  G. Kiani,et al.  Adsorption studies on the removal of Malachite Green from aqueous solutions onto halloysite nanotubes , 2011 .

[39]  H. Murray.  Applied clay mineralogy : occurrences, processing, and application of kaolins, bentonites, palygorskite-sepiolite, and common clays , 2007 .

[40]  A. Poma,et al.  Penetration and Toxicity of Nanomaterials in Higher Plants , 2015, Nanomaterials.

[41]  Giuseppe Lazzara,et al.  Halloysite nanotubes as support for metal-based catalysts , 2016 .

[42]  Y. Rui,et al.  Uptake, transport, distribution and Bio-effects of SiO2 nanoparticles in Bt-transgenic cotton , 2014, Journal of Nanobiotechnology.

[43]  M. H. Siddiqui,et al.  Role of nano-SiO2 in germination of tomato (Lycopersicum esculentum seeds Mill.). , 2014, Saudi journal of biological sciences.

[44]  G. Sposito,et al.  Surface geochemistry of the clay minerals. , 1999, Proceedings of the National Academy of Sciences of the United States of America.

[45]  H. Nakata,et al.  Organochlorine Pesticides and Polychlorinated Biphenyl Residues in Foodstuffs and Human Tissues from China: Status of Contamination, Historical Trend, and Human Dietary Exposure , 2002, Archives of environmental contamination and toxicology.

[46]  Yasuhiko Yoshida,et al.  Nanoparticulate material delivery to plants , 2010 .

[47]  Sangeeta Garg,et al.  Synthesis of cross-linked starch based polymers for sorption of organic pollutants from aqueous solutions , 2012 .

[48]  Jin-dun Liu,et al.  Removal of methylene blue from aqueous solutions by adsorption onto chemically activated halloysite nanotubes , 2011 .

[49]  B. Loganathan,et al.  Contamination profiles and mass loadings of macrolide antibiotics and illicit drugs from a small urban wastewater treatment plant. , 2009, Chemosphere.

[50]  C. Delerue-Matos,et al.  Ecotoxicological aspects related to the presence of pharmaceuticals in the aquatic environment. , 2010, Journal of hazardous materials.

[51]  Kang Feiyu,et al.  Microstructure and Photocatalytic Decomposition of Methylene Blue by TiO2‐Mounted Halloysite, a Natural Tubular Mineral , 2006 .

[52]  Peng Liu,et al.  Adsorption behavior of methylene blue on halloysite nanotubes , 2008 .

[53]  Yuan Tian,et al.  Carboxylated multi-walled carbon nanotubes aggravated biochemical and subcellular damages in leaves of broad bean (Vicia faba L.) seedlings under combined stress of lead and cadmium. , 2014, Journal of hazardous materials.

[54]  G. Kiani.  High removal capacity of silver ions from aqueous solution onto Halloysite nanotubes , 2014 .

[55]  Tianxi Liu,et al.  Enhanced visible-light photocatalytic performance of electrospun carbon-doped TiO2/halloysite nanotube hybrid nanofibers. , 2015, Journal of colloid and interface science.

[56]  Yan-Xing Wang,et al.  Preparation of halloysite-derived mesoporous silica nanotube with enlarged specific surface area for enhanced dye adsorption , 2016 .

[57]  G. Cavallaro,et al.  Alginate gel beads filled with halloysite nanotubes , 2013 .

[58]  Jong Bum Lee,et al.  Engineering DNA-based functional materials. , 2011, Chemical Society reviews.

[59]  Yuri Lvov,et al.  Halloysite clay nanotubes for controlled release of protective agents. , 2011, Journal of nanoscience and nanotechnology.

[60]  Ruichao Liu,et al.  HALLOYSITE NANOTUBE-FE3O4 COMPOSITE FOR REMOVAL OF METHYL VIOLET FROM AQUEOUS SOLUTIONS , 2012 .

[61]  Zhiping Zhou,et al.  Ultrahigh adsorption of typical antibiotics onto novel hierarchical porous carbons derived from renewable lignin via halloysite nanotubes-template and in-situ activation , 2016 .

[62]  G. Cavallaro,et al.  Multicavity halloysite-amphiphilic cyclodextrin hybrids for co-delivery of natural drugs into thyroid cancer cells. , 2015, Journal of materials chemistry. B.

[63]  E. Varghese,et al.  Exploitation of Nano-Bentonite, Nano-Halloysite and Organically Modified Nano-Montmorillonite as an Adsorbent and Coagulation Aid for the Removal of Multi-Pesticides from Water: A Sorption Modelling Approach , 2015, Water, Air, & Soil Pollution.

[64]  Filippo Parisi,et al.  Pharmaceutical properties of supramolecular assembly of co-loaded cardanol/triazole-halloysite systems. , 2015, International journal of pharmaceutics.

[65]  Y. Lvov,et al.  The application of halloysite tubule nanoclay in drug delivery , 2016, Expert opinion on drug delivery.

[66]  G. Lazzara,et al.  Ecotoxicity of halloysite nanotube–supported palladium nanoparticles in Raphanus sativus L , 2016, Environmental toxicology and chemistry.

[67]  Pengwei Huo,et al.  Preparation high photocatalytic activity of CdS/halloysite nanotubes (HNTs) nanocomposites with hydrothermal method , 2012 .

[68]  Pengwu Zheng,et al.  Adsorption and photodegradation of methylene blue on TiO2-halloysite adsorbents , 2014, Korean Journal of Chemical Engineering.

[69]  Yatao Zhang,et al.  Potent antibacterial activity of a novel silver nanoparticle-halloysite nanotube nanocomposite powder. , 2013, Journal of inorganic biochemistry.

[70]  Zhang Xiang,et al.  Rapid adsorption of Cr (VI) on modified halloysite nanotubes , 2010 .

[71]  S. Milioto,et al.  Development and characterization of co-loaded curcumin/triazole-halloysite systems and evaluation of their potential anticancer activity. , 2014, International journal of pharmaceutics.

[72]  A. Pace,et al.  The effect of montmorillonite clay in alginate gel beads for polychlorinated biphenyl adsorption: Isothermal and kinetic studies , 2014 .

[73]  R. Fakhrullin,et al.  Clay-based drug-delivery systems: what does the future hold? , 2017, Therapeutic delivery.

[74]  F. Parisi,et al.  A synergic nanoantioxidant based on covalently modified halloysite-trolox nanotubes with intra-lumen loaded quercetin. , 2016, Journal of materials chemistry. B.

[75]  Ahmad Fauzi Ismail,et al.  Fabrication of polydopamine functionalized halloysite nanotube/polyetherimide membranes for heavy metal removal , 2016 .

[76]  Hong Wang,et al.  Supramolecular gel composites reinforced by using halloysite nanotubes loading with in-situ formed Fe3O4 nanoparticles and used for dye adsorption , 2016 .

[77]  D. Lee,et al.  Phytotoxicity of Carbon Nanotubes Assessed by Brassica Juncea and Phaseolus Mungo , 2010 .

[78]  G. Cavallaro,et al.  Exploiting the Colloidal Stability and Solubilization Ability of Clay Nanotubes/Ionic Surfactant Hybrid Nanomaterials , 2012 .

[79]  Y. Lvov,et al.  Enzyme-activated intracellular drug delivery with tubule clay nanoformulation , 2015, Scientific Reports.

[80]  Ling Yang,et al.  Particle surface characteristics may play an important role in phytotoxicity of alumina nanoparticles. , 2005, Toxicology letters.

[81]  Y. Lvov,et al.  Clay nanotube encapsulation for functional biocomposites. , 2014, Advances in colloid and interface science.

[82]  Jin-dun Liu,et al.  Chitosan–halloysite hybrid-nanotubes: Horseradish peroxidase immobilization and applications in phenol removal , 2013 .

[83]  Y. Lvov,et al.  Halloysite Clay Nanotubes for Enzyme Immobilization. , 2016, Biomacromolecules.

[84]  Á. Jos,et al.  Toxicological evaluation of clay minerals and derived nanocomposites: a review. , 2015, Environmental research.

[85]  A. Takahara,et al.  Selective modification of halloysite lumen with octadecylphosphonic acid: new inorganic tubular micelle. , 2012, Journal of the American Chemical Society.

[86]  Nalinkanth G. Veerabadran,et al.  CLAY NANOTUBES FOR ENCAPSULATION AND SUSTAINED RELEASE OF DRUGS , 2007 .

[87]  Liqun Zhang,et al.  Highly aging-resistant elastomers doped with antioxidant-loaded clay nanotubes. , 2015, ACS applied materials & interfaces.

[88]  Xiaofei Ma,et al.  Synthesis, adsorption and photocatalytic property of halloysite-TiO2-Fe3O4 composites , 2016 .

[89]  K. Kümmerer.  Pharmaceuticals in the Environment , 2001 .

[90]  B. Gaber,et al.  Thin film nanofabrication via layer-by-layer adsorption of tubule halloysite, spherical silica, proteins and polycations , 2002 .

[91]  Bing Zhang,et al.  Continuous fixed bed adsorption of Cu(II) by halloysite nanotube-alginate hybrid beads: an experimental and modelling study. , 2014, Water science and technology : a journal of the International Association on Water Pollution Research.

[92]  M. Tagliabue,et al.  Zeolites and related mesoporous materials for multi-talented environmental solutions , 2013 .

[93]  G. Lazzara,et al.  Thermodynamics of Proton Binding of Halloysite Nanotubes , 2016 .

[94]  J. Matusik,et al.  The effect of acid activation and calcination of halloysite on the efficiency and selectivity of Pb(II), Cd(II), Zn(II) and As(V) uptake , 2016, Clay Minerals.

[95]  Xiaoyan Liu,et al.  Fabrication of highly hydrophobic organic-inorganic hybrid magnetic polysulfone microcapsules: A lab-scale feasibility study for removal of oil and organic dyes from environmental aqueous samples. , 2016, Journal of hazardous materials.

[96]  Yuri Lvov,et al.  Halloysite clay nanotubes as a ceramic "skeleton" for functional biopolymer composites with sustained drug release. , 2013, Journal of materials chemistry. B.

[97]  Liqun Zhang,et al.  Halloysite Clay Nanotubes for Loading and Sustained Release of Functional Compounds , 2016, Advanced materials.

[98]  Pengwei Huo,et al.  Synthesis of thermal-responsive photocatalysts by surface molecular imprinting for selective degradation of tetracycline , 2013 .

[99]  Katsuhiko Ariga,et al.  Activated interiors of clay nanotubes for agglomeration-tolerant automotive exhaust remediation , 2015 .

[100]  Talgar Shaymurat,et al.  Phytotoxic and genotoxic effects of ZnO nanoparticles on garlic (Allium sativum L.): A morphological study , 2012, Nanotoxicology.

[101]  Deyi Wu,et al.  Chitosan modified zeolite as a versatile adsorbent for the removal of different pollutants from water , 2013 .

[102]  Jin-dun Liu,et al.  Study on the adsorption of Neutral Red from aqueous solution onto halloysite nanotubes. , 2010, Water research.

[103]  Yuri Lvov,et al.  Halloysite nanotubule clay for efficient water purification. , 2013, Journal of colloid and interface science.

[104]  V. Vergaro,et al.  Cytocompatibility and uptake of halloysite clay nanotubes. , 2010, Biomacromolecules.

[105]  V. Zharov,et al.  Complex genetic, photothermal, and photoacoustic analysis of nanoparticle-plant interactions , 2010, Proceedings of the National Academy of Sciences.

[106]  E. Tekay,et al.  Biosorbent immobilized nanotube reinforced hydrogel carriers for heavy metal removal processes , 2015 .

[107]  Ruichao Liu,et al.  Adsorption of methyl violet from aqueous solution by halloysite nanotubes , 2011 .

[108]  Yuri Lvov,et al.  Halloysite tubes as nanocontainers for anticorrosion coating with benzotriazole. , 2009, ACS applied materials & interfaces.

[109]  Chengyu Ma,et al.  Silane-modified halloysite/Fe3O4 nanocomposites: Simultaneous removal of Cr(VI) and Sb(V) and positive effects of Cr(VI) on Sb(V) adsorption , 2017 .

[110]  Yongsheng Yan,et al.  Hollow imprinted polymer nanorods with a tunable shell using halloysite nanotubes as a sacrificial template for selective recognition and separation of chloramphenicol , 2016 .

[111]  Abdul Shukor Juraimi,et al.  Effects of Engineered Nanomaterials on Plants Growth: An Overview , 2014, TheScientificWorldJournal.

[112]  S. Milioto,et al.  Dual drug-loaded halloysite hybrid-based glycocluster for sustained release of hydrophobic molecules , 2016 .

[113]  Cuiping Li,et al.  Enhanced visible light photocatalytic activity of polyaniline–crystalline TiO2–halloysite composite nanotubes by tuning the acid dopant in the preparation , 2015 .