Thionitrosyl Complexes of Ruthenium and Osmium

The ruthenium trichloride hydrate and osmium tricholide react with (NSCl)3 in presence of triphenylphosphine and triphenylarsine to give thionitrosyl complexes M(NS)Cl3L2 (M) Rn, or Os; L PPh3 or AsPh3. Thionitrosyl-Komplexe des Rutheniums und Osmiums Rutheniumtrichloridhydrat und Osmiumtrichlorid reagieren mit(NSCl)3 in Gegenwart von Triphenylphosphin und Triphenylarsin zu den Thionitrosylkomplexen M(Ns)Cl3L2 (M Rn, or Os; L PPh3 or AsPh3).