Synthesis, properties and application of electronically-tuned tetraarylarsonium salts as phase transfer catalysts (PTC) for the synthesis of gem -difluorocyclopropanes

[1]  A. Charette,et al.  Difluorocarbene Addition to Alkenes and Alkynes in Continuous Flow. , 2016, Organic letters.

[2]  K. Krishnan,et al.  Recent advances in the syntheses, transformations and applications of 1,1-dihalocyclopropanes. , 2015, Organic & biomolecular chemistry.

[3]  V. V. Levin,et al.  Nucleophilic bromo- and iododifluoromethylation of aldehydes. , 2014, Organic letters.

[4]  Fei Wang,et al.  Synthesis of gem-difluorocyclopropa(e)nes and O-, S-, N-, and P-difluoromethylated compounds with TMSCF(2)Br. , 2013, Angewandte Chemie.

[5]  Jin‐Hong Lin,et al.  Conversion between difluorocarbene and difluoromethylene ylide. , 2013, Chemistry.

[6]  W. R. Dolbier,et al.  Use of fluoroform as a source of difluorocarbene in the synthesis of difluoromethoxy- and difluorothiomethoxyarenes. , 2013, The Journal of organic chemistry.

[7]  M. Fedoryński,et al.  Phase transfer catalysis in dichlorocarbene chemistry: basic principles and specific features , 2011 .

[8]  G. Olah,et al.  Synthesis of gem-difluorinated cyclopropanes and cyclopropenes: trifluoromethyltrimethylsilane as a difluorocarbene source. , 2011, Angewandte Chemie.

[9]  Wei Zhang,et al.  Chloride ion-catalyzed generation of difluorocarbene for efficient preparation of gem-difluorinated cyclopropenes and cyclopropanes. , 2011, Chemical communications.

[10]  H. Amii,et al.  Sodium Bromodifluoroacetate:A Difluorocarbene Source for the Synthesis of gem-Difluorocyclopropanes , 2010 .

[11]  M. Barbasiewicz,et al.  Phase transfer alkylation of arylacetonitriles revisited , 2006 .

[12]  P. Knochel,et al.  Highly efficient reagents for Br/Mg exchange. , 2006, Angewandte Chemie.

[13]  C. Cai,et al.  Sodium Trifluoroacetate: an Efficient Difluorocarbene Precursor for Alkenes , 2005 .

[14]  M. Mąkosza,et al.  Cocatalysis in phase-transfer catalyzed fluorination of alkyl halides and sulfonates , 2005 .

[15]  R. Shriner,et al.  Tetraphenylarsonium Chloride Hydrochloride , 2003 .

[16]  M. Fedoryński.  Syntheses of gem-dihalocyclopropanes and their use in organic synthesis. , 2003, Chemical reviews.

[17]  W. R. Dolbier,et al.  Structure, synthesis, and chemical reactions of fluorinated cyclopropanes and cyclopropenes. , 2003, Chemical reviews.

[18]  Tian,et al.  A novel and highly efficient synthesis of gem-difluorocyclopropanes , 2000, Organic letters.

[19]  M. Fedoryński,et al.  Synthesis of gem-difluorocyclopropanes in a phase-transfer catalysed system , 1991 .

[20]  E. V. Dehmlow,et al.  Reaktionssteuerung durch die Struktur eines Phasentransfer‐Katalysators bei Tribrommethyl‐Anion‐/Dibromcarben‐Umsetzungen , 1990 .

[21]  M. Fedoryński,et al.  Catalysis in Two-Phase Systems: Phase Transfer and Related Phenomena , 1987 .

[22]  U. Müller,et al.  Eine neue Synthese, das Schwingungsspektrum und die Kristallstruktur von Tetraphenylarsonium-hydrogendichlorid As(C6H5)4[Cl2H] / A New Synthesis, the Vibrational Spectrum and the Crystal Structure of Tetraphenylarsonium Hydrogendichloride As(C6H5)4Cl2H] , 1982 .

[23]  J. Buddrus,et al.  Basisches Verhalten von Epoxiden in Gegenwart von Halogenid-Ionen, IV: gem-Difluorcyclopropane aus Chlordifluormethan und Alkanolat-Ionen in geringer Konzentration , 1976 .

[24]  M. Makosza.  Two-phase reactions in the chemistry of carbanions and halocarbenes. A useful tool in organic synthesis , 1975 .

[25]  C. Müller,et al.  Zur darstellung von 1-fluor-1-brom- und 1-fluor-1-chlor-cyclopropanen , 1971 .

[26]  W. Doering,et al.  The Addition of Dichlorocarbene to Olefins , 1954 .

[27]  G. Wittig,et al.  Pentaphenyl-arsen und Pentaphenyl-antimon , 1952 .