Io's surface and the histories of the Galilean satellites

Similarities and differences among the Galilean satellites are discussed. A hypothesis is offered that the surface of Io is largely covered by 'evaporite' salts produced by defluidization of Io's interior, migration of salt-saturated solutions to Io's surface, and subsequent H2O loss to space. Laboratory reflectance studies show that evaporites constitute a good match to Io's spectrum in the infrared, in contrast to ices or frosts, the presence of which is not considered likely in view of the absence of near IR ice bands in Io's surface spectrum. Likely coloring agents in the blue include elemental sulfur, which may be produced from sulfates by proton irradiation or other processes, and F-centers produced by irradiation with magnetospheric protons. Preferential irradiation of material in the polar regions may account for Io's peculiar dark polar caps.