Carbonation of Serpentinite in Creeping Faults of California

Several large strike slip faults in central and northern California accommodate plate motions through aseismic creep. Although there is no consensus regarding the underlying cause of aseismic creep, aqueous fluids and mechanically weak, velocity‐strengthening minerals appear to play a central role. This study integrates field observations and thermodynamic modeling to examine possible relationships between the occurrence of serpentinite, silica‐carbonate rock, and CO2‐rich aqueous fluids in creeping faults of California. Our models predict that carbonation of serpentinite leads to the formation of talc and magnesite, followed by silica‐carbonate rock. While abundant exposures of silica‐carbonate rock indicate complete carbonation, serpentinite‐hosted CO2‐rich spring fluids are strongly supersaturated with talc at elevated temperatures. Hence, carbonation of serpentinite is likely ongoing in parts of the San Andres Fault system and operates in conjunction with other modes of talc formation that may further enhance the potential for aseismic creep, thereby limiting the potential for large earthquakes.

[1]  D. Moore,et al.  Serpentinite‐Rich Gouge in a Creeping Segment of the Bartlett Springs Fault, Northern California: Comparison With SAFOD and Implications for Seismic Hazard , 2018, Tectonics.

[2]  C. Garrido,et al.  Carbonation of mantle peridotite by CO2-rich fluids: the formation of listvenites in the Advocate ophiolite complex (Newfoundland, Canada) , 2018, Lithos.

[3]  Z. Reches,et al.  The frictional strength of talc gouge in high‐velocity shear experiments , 2017 .

[4]  Piyush Agram,et al.  Aseismic slip and seismogenic coupling along the central San Andreas Fault , 2015 .

[5]  D. Moore Comparative mineral chemistry and textures of SAFOD fault gouge and damage-zone rocks , 2014 .

[6]  R. Simpson,et al.  Subsurface geometry of the San Andreas‐Calaveras fault junction: Influence of serpentinite and the Coast Range Ophiolite , 2014 .

[7]  C. Spiers,et al.  The roles of quartz and water in controlling unstable slip in phyllosilicate-rich megathrust fault gouges , 2014, Earth, Planets and Space.

[8]  B. Reynard Serpentine in active subduction zones , 2013 .

[9]  T. McCollom,et al.  Compositional controls on hydrogen generation during serpentinization of ultramafic rocks , 2013 .

[10]  D. Lockner,et al.  Chemical controls on fault behavior: Weakening of serpentinite sheared against quartz‐bearing rocks and its significance for fault creep in the San Andreas system , 2013 .

[11]  B. Jamtveit,et al.  Massive serpentinite carbonation at Linnajavri, N–Norway , 2012 .

[12]  J. Eiler,et al.  Coexisting serpentine and quartz from carbonate-bearing serpentinized peridotite in the Samail Ophiolite, Oman , 2012, Contributions to Mineralogy and Petrology.

[13]  Jafar Hadizadeh,et al.  Aseismic sliding of active faults by pressure solution creep: Evidence from the San Andreas Fault Observatory at Depth , 2011 .

[14]  Ute Weckmann,et al.  Correlation between deep fluids, tremor and creep along the central San Andreas fault , 2011, Nature.

[15]  C. Garrido,et al.  Thermodynamic constraints on mineral carbonation of serpentinized peridotite , 2011 .

[16]  S. Hickman,et al.  Low strength of deep San Andreas fault gouge from SAFOD core , 2011, Nature.

[17]  Mark D. Zoback,et al.  Scientific Drilling Into the San Andreas Fault Zone —An Overview of SAFOD's First Five Years , 2011 .

[18]  E. Pili Isotopic evidence for the infiltration of mantle and metamorphic CO2-H2O fluids from below in faulted rocks from the San Andreas Fault System , 2011 .

[19]  W. Ellsworth,et al.  Scientific Drilling Into the San Andreas Fault Zone , 2010 .

[20]  T. McCollom,et al.  Iron partitioning and hydrogen generation during serpentinization of abyssal peridotites from 15°N on the Mid-Atlantic Ridge , 2009 .

[21]  P. Fulton,et al.  Potential role of mantle‐derived fluids in weakening the San Andreas Fault , 2009 .

[22]  B. Evans,et al.  Relationships between the microstructural evolution and the rheology of talc at elevated pressures and temperatures , 2008 .

[23]  D. Lockner,et al.  Talc friction in the temperature range 25°–400 °C: relevance for fault-zone weakening , 2008 .

[24]  Michael J. Rymer,et al.  Talc-bearing serpentinite and the creeping section of the San Andreas fault , 2007, Nature.

[25]  Colin F. Williams,et al.  Frictional strength heterogeneity and surface heat flow: Implications for the strength of the creeping San Andreas fault , 2006 .

[26]  E. Christiansen,et al.  Contributions to mineralogy and petrology , 2006 .

[27]  G. Dipple,et al.  CARBONATED SERPENTINITE (LISTWANITE) AT ATLIN, BRITISH COLUMBIA: A GEOLOGICAL ANALOGUE TO CARBON DIOXIDE SEQUESTRATION , 2005 .

[28]  T. J. Wolery,et al.  Qualification of Thermodynamic Data for Geochemical Modeling of Mineral-Water Interactions in Dilute Systems , 2004 .

[29]  Colin F. Williams,et al.  Heat flow in the SAFOD pilot hole and implications for the strength of the San Andreas Fault , 2004 .

[30]  Darcy K. McPhee,et al.  Crustal structure across the San Andreas Fault at the SAFOD site from potential field and geologic studies , 2004 .

[31]  Tousson Toppozada,et al.  San Andreas Fault Zone, California: M ≥5.5 Earthquake History , 2002 .

[32]  Everett L. Shock,et al.  Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures : Standard partial molal properties of organic species , 2002 .

[33]  T. McCollom Geochemical constraints on primary productivity in submarine hydrothermal vent plumes , 2000 .

[34]  A. Lachenbruch,et al.  Thermal regime of the San Andreas fault near Parkfield, California , 1997 .

[35]  J. Weeks,et al.  The frictional behavior of lizardite and antigorite serpentinites: Experiments, constitutive models, and implications for natural faults , 1994 .

[36]  T. J. Wolery,et al.  EQ3/6, a software package for geochemical modeling of aqueous systems: Package overview and installation guide (Version 7.0) , 1992 .

[37]  E. Oelkers,et al.  SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000 ° C , 1992 .

[38]  Everett L. Shock,et al.  Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Standard partial molal properties of organic species , 1990 .

[39]  J. Bohlke Comparison of metasomatic reactions between a common CO 2 -rich vein fluid and diverse wall rocks; intensive variables, mass transfers, and Au mineralization at Alleghany, California , 1989 .

[40]  Everett L. Shock,et al.  Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Correlation algorithms for ionic species and equation of state predictions to 5 kb and 1000°C , 1988 .

[41]  H. Helgeson,et al.  Summary and critique of the thermodynamic properties of rock forming minerals , 1978 .

[42]  Donald E. White,et al.  Global distribution of carbon dioxide discharges, and major zones of seismicity , 1978 .

[43]  R. G. Coleman,et al.  Ophiolites: Ancient Oceanic Lithosphere? , 1977 .

[44]  I. Barnes,et al.  Effect of geologic structure and metamorphic fluids on seismic behavior of the San Andreas fault system in central and northern California , 1975 .

[45]  J. B. Rapp,et al.  Silica-Carbonate Alteration of Serpentine; Wall Rock Alteration in Mercury Deposits of the California Coast Ranges , 1973 .

[46]  R. Griffis Genesis of a magnesite deposit, Deloro Twp., Ontario , 1972 .

[47]  F. Henderson Hydrothermal alteration and ore deposition in serpentinite-type mercury deposits , 1969 .

[48]  C. R. Allen The tectonic environments of seismically active and inactive areas along the San Andreas fault system , 1968 .

[49]  C. Whitten,et al.  Creep on the San Andreas fault , 1960 .