Brackish groundwater treatment by nanofiltration, reverse osmosis and electrodialysis in Tunisia: performance and cost comparison

The possibility of producing drinking water from brackish groundwater using nanofiltration (NF), reverse osmosis (RO) and electrodialysis (ED) processes was studied. Brackish groundwater samples were taken from the south of Tunisia (Gabes and Zarzis cities), and characterized in terms of pH, conductivity, hardness and inorganic matters. The results obtained in this work show that nanofiltration permits to reduce the concentrations of Ca2+, Mg2+ and SO42−, which are responsible for elevated sulfate hardness. The total dissolved salts of the produced water is equal to 1890 mg.l−1. This is higher than the maximum value for drinking water fixed by the WHO at 500 mg.l−1. Desalination of brackish groundwater by RO or ED might be technically and economically viable to cope with water scarcity and overcome the water deficit in Tunisia. The results showed that RO and ED were actually efficient since they highly reduced the content of inorganic matters present in raw waters. The treatment by RO or ED shows that the concentrations of ions in the obtained permeate (or the diluate) did not exceed the permissible WHO standards. ED seems to be the economical desalination process for Gabes water due to its low energy consumption whereas Zarzis water should be treated with the RO process.

[1]  Frederick George Donnan,et al.  Theory of membrane equilibria and membrane potentials in the presence of non-dialysing electrolytes. A contribution to physical-chemical physiology , 1995 .

[2]  Nafiz Kahraman,et al.  Exergy analysis of a combined RO, NF, and EDR desalination plant , 2005 .

[3]  E. Wa̧sik,et al.  Ion balance in NF-treated well water for drinking water production , 2005 .

[4]  Imed Houcine,et al.  Desalination in Tunisia: Past experience and future prospects , 1998 .

[5]  Jamal O. Jaber,et al.  Brackish groundwater treatment by reverse osmosis in Jordan , 2004 .

[6]  L. Firdaous,et al.  Modification of the ionic composition of salt solutions by electrodialysis , 2004 .

[7]  Mahmoud Dhahbi,et al.  The role of membrane technologies in supplying drinking and industrial water in Tunisia: Conventional process and new trends , 2003 .

[8]  Yoshinobu Tanaka,et al.  Ion-exchange membrane electrodialytic salt production using brine discharged from a reverse osmosis seawater desalination plant , 2003 .

[9]  M. Ghoul,et al.  Mechanisms for the selective rejection of solutes in nanofiltration membranes , 1997 .

[10]  T. Sata,et al.  Interaction between anionic polyelectrolytes and anion exchange membranes and change in membrane properties , 1995 .

[11]  N. Walton Electrical Conductivity and Total Dissolved Solids—What is Their Precise Relationship? , 1989 .

[12]  Kamel Fethi,et al.  Performances de la Station de Dessalement de Gabès (22,500 m3/j) apres cinq ans de fonctionnement☆ , 2001 .

[13]  Kamel Fethi Optimization of energy consumption in the 3300 m3/d RO Kerkennah plant* , 2003 .