Mechanism of efficient and stable surface-emitting cold cathode based on porous polycrystalline silicon films

It is demonstrated that a porous polysilicon (PPS) diode with a structure of Au/PPS/n-type Si operates as an efficient stable surface-emitting cold cathode. 1.5 μm of an nondoped polysilicon layer is formed on an n-type (100) silicon wafer and anodized in a solution of HF (50%): ethanol=1:1 at a current density of 10 mA/cm2 for 30 s under illumination by a 500 W tungsten lamp from a distance of 20 cm. Subsequently, a PPS layer is oxidized in a rapid thermal oxidation furnace for 1 h at a temperature of 700 °C. A semitransparent thin Au film (about 10 nm thick) is deposited onto the PPS layer as a positive electrode and an ohmic contact is formed at the back side of the silicon wafer as a negative electrode. When a positive bias is applied to the Au electrode in vacuum, the diode uniformly emits electrons. No electron emission is observed in the negatively biased region. Emission current is about 10−4 A/cm2 at a 20 V bias. It is further demonstrated that electrons are quasiballistically emitted from a PPS ...