Domain-enhanced interlayer coupling in ferroelectric/paraelectric superlattices.

We investigate the ferroelectric phase transition and domain formation in a periodic superlattice consisting of alternate ferroelectric (FE) and paraelectric (PE) layers of nanometric thickness. We find that the polarization domains formed in the different FE layers can interact with each other via the PE layers. By coupling the electrostatic equations with those obtained by minimizing the Ginzburg-Landau functional, we calculate the critical temperature of transition Tc as a function of the FE/PE superlattice wavelength Lambda and quantitatively explain the recent experimental observation of a thickness dependence of the ferroelectric transition temperature in KTaO3/KNbO3 strained-layer superlattices.

[1]  Seungbum Hong Nanoscale phenomena in ferroelectric thin films , 2004 .

[2]  M. Okuyama,et al.  Ferroelectric random access memories : fundamentals and applications , 2004 .

[3]  S. Phillpot,et al.  Ferroelectric phase transitions and dynamical behavior in KNbO3/KTaO3 superlattices by molecular-dynamics simulation , 2002 .

[4]  A. Bratkovsky,et al.  Abrupt appearance of the domain pattern and fatigue of thin ferroelectric films , 1999, Physical review letters.

[5]  D. Norton,et al.  X-Ray Diffraction Measurement of the Effect of Layer Thickness on the Ferroelectric Transition in Epitaxial KTaO 3 / KNbO 3 Multilayers , 1998 .

[6]  A. Tagantsev,et al.  Effect of mechanical boundary conditions on phase diagrams of epitaxial ferroelectric thin films , 1998 .

[7]  Boris A. Strukov,et al.  Ferroelectric Phenomena in Crystals , 1998 .

[8]  Zhong,et al.  Surface and size effects on ferroelectric films with domain structures. , 1995, Physical review. B, Condensed matter.

[9]  Budai,et al.  Strain relaxation by domain formation in epitaxial ferroelectric thin films. , 1992, Physical review letters.

[10]  Kurt Binder,et al.  Surface effects on phase transitions in ferroelectrics and dipolar magnets , 1979 .

[11]  A. L. Roitburd,et al.  Equilibrium structure of epitaxial layers , 1976 .

[12]  I. P. Batra,et al.  Thermodynamic stability of thin ferroelectric films , 1972 .

[13]  E. M. Lifshitz,et al.  Electrodynamics of continuous media , 1961 .

[14]  Charles Kittel,et al.  Theory of the structure of ferromagnetic domains in films and small particles , 1946 .