Design and Control of the Styrene Process

A recent paper by Vasudevan et al. (Ind. Eng. Chem. Res. 2009, 48, 10941−10961) presented a flowsheet of the styrene process, which has several interesting design and control features. Their study concentrated on a comparison of three plantwide control methodologies. The economic optimum design of the process was given, but no quantitative details were given of how the optimum was obtained. The chemistry of styrene process involves the dehydrogenation of ethylbenzene. The reaction is endothermic, nonequimolar and reversible, so high temperatures and low pressures are conducive to high conversion in the adiabatic vapor-phase reactors. Steam is mixed with the ethylbenzene (EB) fed to the reactors to lower the partial pressure of ethylbenzene and increase conversion. There are also several other side reactions that produce undesirable byproducts (benzene, toluene, ethylene and carbon dioxide), whose reaction rates increase with temperature and partial pressures. The main design optimization variables in this...