Filler size and content effects on the composite properties of anisotropic conductive films (ACFs) and reliability of flip chip assembly using ACFs

Abstract Flip chip assembly on organic board using anisotropic conductive films (ACFs) is gained more attention because of its many advantages. But to obtain more reliable flip chip assembly, it is necessary to have low coefficient of thermal expansion (CTE) value of ACFs. To control the CTE of ACF materials, non-conductive silica fillers were incorporated into ACFs. The effect of non-conductive silica filler content and size on cure kinetics and thermo-mechanical properties of ACFs was studied. Furthermore, filler content and size effects on reliability of flip chip assembly using ACFs were also investigated. In accordance with increasing filler content, curing peak temperature and storage modulus ( E ′) increased. But CTE decreased as the filler content increased. The effect of filler size on composite properties and assembly reliability showed similar tendency with the filler content effect. The smaller filler size was applied, the better composite properties and reliability were obtained. Conclusively, incorporation of non-conductive fillers, particularly in case of smaller size and higher content, in ACFs improves the material properties significantly, and as a result, flip chip assembly using ACFs is resulted in better reliability.

[1]  G. Hill,et al.  Flip-chip encapsulation on ceramic substrates , 1993, Proceedings of IEEE 43rd Electronic Components and Technology Conference (ECTC '93).

[2]  John J. Shea,et al.  Modeling contact erosion in three phase vacuum contactors , 1997, Electrical Contacts - 1997 Proceedings of the Forty-Third IEEE Holm Conference on Electrical Contacts.

[3]  Sergey V Shkarayev,et al.  Potential Failure Sites in a Flip-Chip Package With and Without Underfill , 1997, Application of Fracture Mechanics in Electronic Packaging.

[4]  Johan Liu,et al.  A reliable and environmentally friendly packaging technology-flip-chip joining using anisotropically conductive adhesive , 1999 .

[5]  Kyung-Wook Paik,et al.  Effects of epoxy functionality on the properties and reliability of the anisotropic conductive films for flip chips on organic substrates , 2006 .

[6]  A. Bar-Cohen,et al.  Coffin-Manson fatigue model of underfilled flip-chips , 1997 .

[7]  Vadim Gektin,et al.  Coffin-Manson based fatigue analysis of underfilled DCAs , 1998, IEEE Transactions on Components, Packaging, and Manufacturing Technology: Part A.

[8]  J. H. Constable,et al.  Continuous electrical resistance monitoring, pull strength, and fatigue life of isotropically conductive adhesive joints , 1999 .

[9]  N. Cheremisinoff,et al.  Elastomer Technology Handbook , 1993 .

[10]  J. Fernández-García,et al.  Thermoplastic polyurethane-fumed silica composites: influence of the specific surface area of fumed silica on the viscoelastic and adhesion properties , 1999 .

[11]  David J. Williams,et al.  Anisotropic Conducting Adhesives for Electronic Interconnection , 1993 .

[12]  Jacqueline I. Kroschwitz,et al.  Encyclopedia of Polymer Science and Technology , 1970 .

[13]  K. Paik,et al.  Flip chip assembly on organic boards using anisotropic conductive adhesives (ACAs) and nickel/gold bumps , 1999, Proceedings of 3rd Electronics Packaging Technology Conference (EPTC 2000) (Cat. No.00EX456).

[14]  J. Galy,et al.  Effect of sub-micron silica fillers on the mechanical performances of epoxy-based composites , 2007 .

[15]  D. V. Krevelen Properties of Polymers , 1990 .

[16]  Henry Lee,et al.  Handbook of Epoxy Resins , 1967 .