论文信息 - Bis(3,5-dimethylpyridine-κN)bis(tri-tert-butoxysilanethiolato-κS)chromium(II) toluene solvate

Bis(3,5-dimethylpyridine-κN)bis(tri-tert-butoxysilanethiolato-κS)chromium(II) toluene solvate

In the title chromium silanethiolate, [Cr(C12H27O3SSi)2(C7H9N)2]·C7H8, the CrII atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement. The mononuclear molecule lies on a twofold axis that passes through the pyridine N atoms. The toluene solvent molecule is equally disordered about a twofold axis.

Anna Ciborska | Katarzyna Baranowska | Wiesław Wojnowski

[1] W. Wojnowski,et al. Untersuchungen über die Alkoholyse des SiS2. II. Darstellung von Trialkoxysilanthiolen und Tetraalkoxycyclodisilthianen aus den tertiären Alkoholen , 1962 .

[2] Anna Ciborska,et al. (1,2-Dimethoxyethane-κ O )bis(tri- tert -butoxysilanethiolato-κ 2 O , S )chromium(II) , 2007 .

[3] M. Wieczerzak,et al. Self-assembly of zinc and cobalt complexes mimicking active site of alcohol dehydrogenase , 2008 .

[4] G. Sheldrick. A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[5] Louis J. Farrugia,et al. WinGX suite for small-molecule single-crystal crystallography , 1999 .

[6] C. Rao,et al. Structural diversity of homoleptic ethane-1,2-dithiolato complexes of the first transition series , 1985 .

[7] W. Wojnowski,et al. Beiträge zur Chemie der Silicium-Schwefel-Verbindungen. XVI.Trialkoxythiosilanolate von Metallen der I. und II. Hauptgruppe der Elemente und Darstellung von reinen Trialkoxysilanthiolen† , 1974 .

[8] A. Konitz,et al. Cobalt(II) tri-tert-butoxysilanethiolates: in search of models for catalytic metal site of liver alcohol dehydrogenase , 2002 .

[9] Louis J. Farrugia,et al. ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[10] Anna Ciborska,et al. Bis(di-n-propylamine-κN)bis(tri-tert-butoxysilanethiolato-κS)chromium(II) , 2007, Acta crystallographica. Section E, Structure reports online.