Fabrication and testing of CONTISOL: A new receiver-reactor for day and night solar thermochemistry

Abstract The CONTISOL concept is a new vision of an integrated solar receiver/reactor for a variety of thermochemical processes. The concept includes a single monolithic solar absorber with two inter-mixed, but non-intersecting sets of gas channels. One set of channels is always used for a chemical process. During daytime operation, the other set of channels is used to heat air which is sent to thermal storage. During nighttime operation, the air flow is reversed, transferring heat from thermal storage to the monolith through the same set of channels, thus providing energy to continue chemical processing continuously through day and night. In this paper we introduce the general operation of the system and discuss its benefits applied to solar methane reforming as an example process. Past solar reactors which influenced the development of CONTISOL are discussed. A 5 kW scale demonstration prototype has been constructed at DLR and thermal experiments have been conducted using the DLR high flux solar simulator. A statistical design-of-experiments procedure has been applied to evaluate the influence of absorber temperature, gas flow rates, and gas inlet temperatures on heat transfer rates to gas streams, and to construct a thermal performance map of the device. The target gas outlet temperatures of over 850 °C were reached during these tests. Limitations on the initial design of the monolith are discussed including recommendations for future improvements.

[1]  A. Steinfeld,et al.  Solar-driven gasification of carbonaceous feedstock-a review , 2011 .

[2]  T. Kodama,et al.  Stepwise production of CO-rich syngas and hydrogen via solar methane reforming by using a Ni(II)–ferrite redox system , 2002 .

[3]  Ulrich Langnickel,et al.  Solar steam reforming of methane , 1991 .

[4]  T. Kodama,et al.  Ni/ceramic/molten-salt composite catalyst with high-temperature thermal storage for use in solar reforming processes , 2004 .

[5]  Antje Wörner,et al.  CO2 reforming of methane in a solar driven volumetric receiver–reactor , 1998 .

[6]  Valerio Fernández,et al.  DESIGN AND IMPLEMENTATION PLAN OF A 10 MW SOLAR TOWER POWER PLANT BASED ON VOLUMETRIC-AIR TECHNOLOGY IN SEVILLE (SPAIN) , 2000 .

[7]  Talbot A. Chubb,et al.  Characteristics of CO2CH4 reforming-methanation cycle relevant to the solchem thermochemical power system , 1980 .

[8]  Richard B. Diver,et al.  Solar test of an integrated sodium reflux heat pipe receiver/reactor for thermochemical energy transport , 1992 .

[9]  I. Barin Thermochemical data of pure substances , 1989 .

[10]  M. Piccirilli,et al.  Thermochemical conversion of solar energy by steam reforming of methane , 1986 .

[11]  Reiner Buck,et al.  Carbon Dioxide Reforming of Methane in a Solar Volumetric Receiver-Reactor: The CAESAR Project. , 1991 .

[12]  V. Parmon,et al.  Theoretical and experimental studies of solar catalytic power plants based on reversible reactions with participation of methane and synthesis gas , 1990 .

[13]  A. Steinfeld,et al.  Dry Reforming of Methane Using a Solar-Thermal Aerosol Flow Reactor , 2004 .

[14]  M. Dry High quality diesel via the Fischer–Tropsch process – a review , 2002 .

[15]  Elias K. Stefanakos,et al.  Optimal heliostat aiming strategy for uniform distribution of heat flux on the receiver of a solar power tower plant , 2014 .

[16]  Christian Sattler,et al.  Solar thermal reforming of methane feedstocks for hydrogen and syngas production—A review , 2014 .

[17]  Heath Rushing,et al.  Design and Analysis of Experiments by Douglas Montgomery: A Supplement for Using JMP , 2013 .