The Mechanism of the High Resistance to Hydrogen-Induced Strength Loss in Ultra-High Strength High-Entropy Alloy

The resistance of the Al0.5Cr0.9FeNi2.5V0.2 high-entropy alloy (HEA) to hydrogen embrittlement (HE) was investigated by a slow strain rate test (SSRT), and the fracture surface was examined through a scanning electron microscope. Compared with other high-strength steels, Al0.5Cr0.9FeNi2.5V0.2 showed insignificant strength loss after hydrogen charging. The fracture surface of the hydrogen-charged specimens mainly consisted of dimples, and no intergranular morphology was observed. The coupling effect of the dispersed nano-structured precipitates and high-density dislocations in Al0.5Cr0.9FeNi2.5V0.2 improves the resistance to hydrogen-induced strength loss.

[1]  N. Tsuji,et al.  Hydrogen-Related Fracture Behavior under Constant Loading Tensile Test in As-Quenched Low-Carbon Martensitic Steel , 2022, Metals.

[2]  Jee-Hyun Kang,et al.  Nitrogen effect on hydrogen diffusivity and hydrogen embrittlement behavior in austenitic stainless steels , 2020 .

[3]  Milos B. Djukic,et al.  Hydrogen embrittlement of low carbon structural steel at macro-, micro- and nano-levels , 2020 .

[4]  J. Cairney,et al.  Observation of hydrogen trapping at dislocations, grain boundaries, and precipitates , 2020, Science.

[5]  D. Wan,et al.  In-situ observation of martensitic transformation in an interstitial metastable high-entropy alloy during cathodic hydrogen charging , 2019 .

[6]  U. Ramamurty,et al.  Influences of hydrogen charging method on the hydrogen distribution and nanomechanical properties of face-centered cubic high-entropy alloy: A comparative study , 2019, Scripta Materialia.

[7]  H. Abreu,et al.  The effect of prior austenite grain size on hydrogen embrittlement of Co-containing 18Ni 300 maraging steel , 2019, International Journal of Hydrogen Energy.

[8]  Milos B. Djukic,et al.  The synergistic action and interplay of hydrogen embrittlement mechanisms in steels and iron: Localized plasticity and decohesion , 2019, Engineering Fracture Mechanics.

[9]  Chang-wook Lee,et al.  Baking Effect on Desorption of Diffusible Hydrogen and Hydrogen Embrittlement on Hot-Stamped Boron Martensitic Steel , 2019, Metals.

[10]  T. Iijima,et al.  The finding of hydrogen trapping at phase boundary in austenitic stainless steel by scanning Kelvin probe force microscopy , 2019, Scripta Materialia.

[11]  Qian Xiao,et al.  High-content ductile coherent nanoprecipitates achieve ultrastrong high-entropy alloys , 2018, Nature Communications.

[12]  D. Wan,et al.  Hydrogen embrittlement effect observed by in-situ hydrogen plasma charging on a ferritic alloy , 2018, Scripta Materialia.

[13]  Xiaogang Li,et al.  Effect of Nb on the hydrogen-induced cracking of high-strength low-alloy steel , 2018, Corrosion Science.

[14]  J. Takahashi,et al.  Origin of hydrogen trapping site in vanadium carbide precipitation strengthening steel , 2018, Acta Materialia.

[15]  B. Campillo,et al.  Microalloyed Steels through History until 2018: Review of Chemical Composition, Processing and Hydrogen Service , 2018 .

[16]  C. Fritzen,et al.  Hydrogen Embrittlement Mechanism in Fatigue Behavior of Austenitic and Martensitic Stainless Steels , 2018 .

[17]  J. Kermode,et al.  Understanding and mitigating hydrogen embrittlement of steels: a review of experimental, modelling and design progress from atomistic to continuum , 2018, Journal of Materials Science.

[18]  H. Springer,et al.  Spatially resolved localization and characterization of trapped hydrogen in zero to three dimensional defects inside ferritic steel , 2018 .

[19]  K. Verbeken,et al.  The detrimental effect of hydrogen at dislocations on the hydrogen embrittlement susceptibility of Fe-C-X alloys: An experimental proof of the HELP mechanism , 2018 .

[20]  J. Kelleher,et al.  Effect of hydrogen charging on dislocation multiplication in pre-strained super duplex stainless steel , 2018 .

[21]  D. Eliezer,et al.  Mechanisms of hydrogen trapping in austenitic, duplex, and super martensitic stainless steels , 2017 .

[22]  C. Liu,et al.  Precipitation hardening in CoCrFeNi-based high entropy alloys , 2017 .

[23]  M. Béreš,et al.  Role of lattice strain and texture in hydrogen embrittlement of 18Ni (300) maraging steel , 2017 .

[24]  V. Olden,et al.  A coupled diffusion and cohesive zone modelling approach for numerically assessing hydrogen embrittlement of steel structures , 2017 .

[25]  N. Jones,et al.  High-entropy alloys: a critical assessment of their founding principles and future prospects , 2016 .

[26]  M. Béreš,et al.  Hydrogen embrittlement of ultra high strength 300 grade maraging steel , 2015 .

[27]  E. Sattler,et al.  Microstructural properties controlling hydrogen environment embrittlement of cold worked 316 type austenitic stainless steels , 2015 .

[28]  J. Chen,et al.  Effect of pre-strain on hydrogen embrittlement of high strength steels , 2014 .

[29]  K. Takai,et al.  Dependence of hydrogen-induced lattice defects and hydrogen embrittlement of cold-drawn pearlitic steels on hydrogen trap state, temperature, strain rate and hydrogen content , 2014 .

[30]  I. M. Robertson,et al.  The effect of nanosized (Ti,Mo)C precipitates on hydrogen embrittlement of tempered lath martensitic steel , 2014 .

[31]  C. Tasan,et al.  Hydrogen-assisted decohesion and localized plasticity in dual-phase steel , 2014 .

[32]  K. Dahmen,et al.  Microstructures and properties of high-entropy alloys , 2014 .

[33]  A. Volinsky,et al.  Microstructure effect on hydrogen-induced cracking in TM210 maraging steel , 2013 .

[34]  W. Curtin,et al.  Atomic mechanism and prediction of hydrogen embrittlement in iron. , 2013, Nature materials.

[35]  M. Nagumo,et al.  Lattice defects dominating hydrogen-related failure of metals , 2008 .

[36]  K. Tsuzaki,et al.  Effect of hydrogen on the fracture behavior of high strength steel during slow strain rate test , 2007 .

[37]  D. Olson,et al.  Hydrogen trapping in ferritic steel weld metal , 2002 .

[38]  M. Nagumo Function of Hydrogen in Embrittlement of High-strength Steels , 2001 .

[39]  F. Frasconi,et al.  Experimental study of hydrogen embrittlement in Maraging steels , 2018 .

[40]  Thorsten Michler,et al.  Microstructural aspects upon hydrogen environment embrittlement of various bcc steels , 2010 .

[41]  K. Shimizu,et al.  Effect of Hydrostatic Pressure on Martensitic Transformations in Cu–Al–Ni Shape Memory Alloys , 1988 .