New Materials and Performance Limits for Thermoelectric Cooling

34.4 Introduction Systematic Search Historical Review New Materials Phonon "Glasses" Desired Performance PGEC Relaxation of A,,. Assumption Band Gaps of Semiconductors Carrier Mobilities Background Explanation Electronegativities and Good Thermoelectric Semiconductors Dopant and Mixed-Crystal Effects on Mobilities Dopant Effects on the Weighted Mobility Mixed-Crystal Effects on Mobility Weighted Mobility Lattice Thermal Conductivity Phonon Scattering Mechanisms New Amin Crystals and New Thermoelectrics Conclusions From the Analysis Appendix: Calculation of ZT for PGEC References

[1]  A. D. Stuckes Measurement of thermal conductivity of semiconductors at high temperatures , 1961 .

[2]  G. A. Slack,et al.  Thermal conductivity of ice , 1980 .

[3]  A. Ormont,et al.  Galvano- and thermomagnetic properties of platinum antimonide , 1973 .

[4]  Y. P. Handa,et al.  Thermal conductivity of xenon hydrate , 1987 .

[5]  B. A. Efimova,et al.  Scattering of Current Carriers and Transport Phenomena in Lead Chalcogenides II. Experiment , 1971 .

[6]  W. Phillips,et al.  Thermal conductivity of ice and ice clathrate , 1987 .

[7]  Werner Haken Beitrag zur Kenntnis der thermoelektrischen Eigenschaften der Metallegierungen , 1910 .

[8]  L. N. Lukyanova,et al.  The Conduction Band Parameters and Scattering Mechanisms in Solid Solutions Based on Bi2Te3 , 1989 .

[9]  D. A. Wright Materials for direct-conversion thermoelectric generators , 1970 .

[10]  D. Greig Thermoelectricity and Thermal Conductivity in the Lead Sulfide Group of Semiconductors , 1960 .

[11]  E. Burstein,et al.  De Haas-van Alphen and high field galvanomagnetic studies of the Bi2Te3 valence band structure , 1963 .

[12]  R. B. Mallinson,et al.  de Haas-van Alphen Effect in n-Type Bi 2 Te 3 , 1968 .

[13]  F. D. Rosi,et al.  Compound tellurides and their alloys for peltier cooling—A review , 1972 .

[14]  K. Yvon,et al.  Single crystal X-ray study of Mo6Se8-type selenides containing partially substituted (Mo,Me)6 clusters (Me = Ru,Re) , 1983 .

[15]  J. Cowen,et al.  The thermal conductivity of silver iodide , 1982 .

[16]  J. Cook,et al.  An exploratory study of the thermal conductivity of methane hydrate , 1983 .

[17]  R. Wolfe,et al.  Galvanomagnetic Effects in n-Type Bismuth Telluride , 1958 .

[18]  C. Kittel,et al.  Interpretation of the Thermal Conductivity of Glasses , 1949 .

[19]  Pohl,et al.  Thermal properties of a tetrahedrally bonded amorphous solid: CdGeAs2. , 1988, Physical review. B, Condensed matter.

[20]  W. W. Scanlon,et al.  Mobility of Electrons and Holes in PbS, PbSe, and PbTe between Room Temperature and 4.2°K , 1958 .

[21]  Jin-Seung Jung,et al.  Synthesis and crystal structure of a novel Zintl phase: K3SbTe3 , 1991 .

[22]  C. F. Gallo,et al.  Transport Properties of Bismuth Single Crystals , 1963 .

[23]  H J Goldsmid,et al.  The Electrical Conductivity and Thermoelectric Power of Bismuth Telluride , 1958 .

[24]  W. Heiliger,et al.  Seebeck coefficient and electrical conductivity in p‐(Bi1−xSbx)2 Te3 at room temperature , 1983 .

[25]  R. Dalven Electronic Structure of PbS, PbSe, and PbTe , 1974 .

[26]  H. Hong,et al.  Crystal structure of Tl3AsSe3 , 1974 .

[27]  T. Irie Lattice Thermal Conductivity of Disordered Alloys of Ternary Compound Semiconductors Cu2(Sn, Ge)(Se, S)3 (Ag, Pb, Sb)Te2, and (Ag, Sn, Sb)Te2 , 1966 .

[28]  W. M. Yim,et al.  BiSb alloys for magneto-thermoelectric and thermomagnetic cooling , 1972 .

[29]  F. Klaiber,et al.  The structure type of Re2Te5, a new [M6X14] cluster compound , 1983 .

[30]  G. White,et al.  The thermal and electrical resistivity of bismuth and antimony at low temperatures , 1958 .

[31]  G. E. Smith,et al.  Thermoelectric Properties of Bismuth‐Antimony Alloys , 1962 .

[32]  T. Seidel,et al.  High‐Temperature Thermal and Electrical Properties of GaSb‐InSb Alloys , 1967 .

[33]  M. D. Hurley,et al.  Growth and electrical properties of epitaxial PbSexTe1−x layers , 1976 .

[34]  Watson,et al.  Lower limit to the thermal conductivity of disordered crystals. , 1992, Physical review. B, Condensed matter.

[35]  R. G. Ross,et al.  Clathrate and other solid phases in the tetrahydrofuran–water system: thermal conductivity and heat capacity under pressure , 1982 .

[36]  G. A. Slack,et al.  The Thermal Conductivity of Nonmetallic Crystals , 1979 .

[37]  R. G. Ross,et al.  Thermal conductivity and heat capacity of solid phases of NH4Cl under pressure , 1979 .

[38]  I. Kudman Thermoelectric properties of p-type PbTe-PbSe alloys , 1972 .

[39]  F. D. Rosi,et al.  Thermoelectric properties of Bi2Te3-Sb2Te3-Sb2Se3 pseudo-ternary alloys in the temperature range 77 to 300° K , 1966 .

[40]  H. Ehrenreich Electron mobility of indium arsenide phosphide [In(AsyP1−y)] , 1959 .

[41]  B. Nag,et al.  Free-carrier absorption and electron mobility in n-type PbTe , 1978 .

[42]  H. Scherrer,et al.  Thermal properties of high quality single crystals of bismuth telluride—Part II: Mixed-scattering model , 1988 .

[43]  G. A. Slack,et al.  THERMAL CONDUCTIVITY OF BORON AND SOME BORON COMPOUNDS. , 1971 .

[44]  G. A. Slack,et al.  Some properties of semiconducting IrSb3 , 1994 .

[45]  Gerald D. Mahan,et al.  Figure of merit for thermoelectrics , 1989 .

[46]  Moayyed A. Hussain,et al.  The maximum possible conversion efficiency of silicon‐germanium thermoelectric generators , 1991 .

[47]  W. Zawadzki,et al.  Electron transport phenomena in small-gap semiconductors , 1974 .

[48]  G. Vineyard,et al.  Semiconductor Thermoelements and Thermoelectric Cooling , 1957 .

[49]  A. Allred,et al.  Electronegativity values from thermochemical data , 1961 .

[50]  C. Greaves,et al.  Structural properties of the molybdenum-ruthenium telluride of composition Mo4.5Ru1.5Te8 , 1991 .

[51]  J. M. Parker,et al.  A new compound in the Ge-Te system , 1978 .

[52]  Watson,et al.  Thermal properties of boron and borides. , 1989, Physical review. B, Condensed matter.

[53]  J. Woolley,et al.  Conduction bands of GaxIn1–x Sb alloys , 1969 .

[54]  T. Klitsner,et al.  Thermal conductivity of thin films: Measurements and understanding , 1989 .

[55]  T. K. Dey,et al.  Lattice thermal conductivity of bismuth-antimony alloy single crystals at low temperatures , 1976 .

[56]  G. Guseinov,et al.  Heat conductivity of TlxGa1−xX (0⩽x⩽1; X = S, Se, Te) monocrystals , 1976 .

[57]  M. Ewbank,et al.  Thermal conductivity and specific heat of the chalcogenide salt: Tl3 AsSe3 , 1982 .

[58]  R. Uno On the Electrical Properties of Polycrystalline Boron. , 1958 .

[59]  L. Testardi,et al.  Transport properties of p-type Bi2Te3Sb2Te3 alloys in the temperature range 80–370°K , 1962 .