Utilization of Carbonaceous Materials To Restore the Coking Properties of Weathered Coals

Coking coals with different rank and maceral compositions have been weathered, and their fluidity has been determined through high-temperature rheometry. The pristine and weathered coals were blended with carbonaceous additives comprised of coal tar, diesel fuel, high-density polyethylene, sugar beet roots, lignin, and bio-oil in order to produce blends with optimum fluid characteristics. The addition of only 3 wt % coal tar to a high-rank coal weathered for 6 months completely restored its fluid properties, and the addition of 3 wt % diesel fuel was able to restore the fluidity of the coal but only after shorter weathering periods (4 months). However, the strength parameter R1 (particles > 0.6 mm) of the semicokes obtained from these blends at 700 °C was lower than that of the pristine coal by 3%. Biomass additives such as sugar beet roots and lignin were found to reduce the fluidity of a weathered coal with medium-volatile-matter content (25 wt % dry ash free (daf)) to levels similar to those encountere...

[1]  M. Hajaligol,et al.  Characterization of chars from pyrolysis of lignin , 2004 .

[2]  M. Diez,et al.  Effects of plastic wastes on coal pyrolysis behaviour and the structure of semicokes , 2005 .

[3]  K. Katoh,et al.  Study on thermoplasticity of coals by dynamic viscoelastic measurement: effect of coal rank and comparison with Gieseler fluidity , 2000 .

[4]  R. Sakurovs Interactions between coking coals and plastics during co-pyrolysis☆ , 2003 .

[5]  M. Diez,et al.  Influence of additives of various origins on thermoplastic properties of coal , 2009 .

[6]  J. White,et al.  Notes: Experimental Studies of Disperse Two‐Phase Flow of Molten Polymers Through Dies , 1975 .

[7]  A. Clemens,et al.  The effect of decacyclene on coal fluidity , 1987 .

[8]  Anthony Dufour,et al.  The Effect of Biomass on Fluidity Development in Coking Blends Using High-Temperature SAOS Rheometry , 2012 .

[9]  J. Patrick,et al.  Determination of the Effect of Different Additives in Coking Blends Using a Combination of in Situ High-Temperature 1H NMR and Rheometry , 2005 .

[10]  Kartic C. Khilar,et al.  Pyrolysis characteristics of biomass and biomass components. , 1996 .

[11]  D. S. Montgomery,et al.  Oxidation studies on coking coal related to weathering. 3. The influence of acidic hydroxyl groups, created during oxidation, on the plasticity and dilatation of the weathered coking coal , 1974 .

[12]  Kenjiro Kato,et al.  The effect of plastic addition on coal caking properties during carbonization , 2003 .

[13]  H. Marsh,et al.  Carbonization and liquid-crystal (mesophase) development. 22. Micro-strength and optical textures of cokes from coal-pitch co-carbonizations , 1981 .

[14]  R. Baker,et al.  The pyrolytic formation of formaldehyde from sugars and tobacco , 2006 .

[15]  Ramon Alvarez,et al.  Plastic wastes, lube oils and carbochemical products as secondary feedstocks for blast-furnace coke , 2011 .

[16]  Ramon Alvarez,et al.  Effect of the addition of waste sawdust on thermoplastic properties of a coal , 2013 .

[17]  H. Marsh,et al.  Carbonization and liquid—crystal (mesophase) development. 19. Co-carbonization of oxidized coals with model organic compounds , 1981 .

[18]  M. Diez,et al.  Gas chromatographic study of the volatile products from co-pyrolysis of coal and polyethylene wastes. , 2001, Journal of chromatography. A.

[19]  J. Patrick,et al.  Use of rheometry and 1H NMR spectroscopy for understanding the mechanisms behind the generation of coking pressure , 2004 .

[20]  M. Diez,et al.  Plastic Wastes as Modifiers of the Thermoplasticity of Coal , 2005 .

[21]  M. Diez,et al.  On the Possibility of Using Coking Plant Waste Materials as Additives for Coke Production , 1998 .

[22]  Ramon Alvarez,et al.  Biomass derived products as modifiers of the rheological properties of coking coals , 2012 .