Catalytic properties of metal-phthalocyanines in reactions involving hydrogen

The catalytic properties and the mechanism of activation of phthalocyanines in reactions with participation of hydrogen are examined. The mechanism of the catalytic action of phthalocyanines is discussed. Two types of active centres ('metallic' and 'organic') are distinguished in the phthalocyanine molecule. Problems associated with the fixation of phthalocyanine catalysts on carriers are considered. The bibliography includes 120 references.

[1]  E. M. Sul'man.  Selective hydrogenation of unsaturated ketones and acetylene alcohols , 1994 .

[2]  Y. Yoshimura,et al.  Preparation of Molybdenum Sulfide Catalysts Promoted by Ni and Co Organometallics , 1993 .

[3]  K. Sakamoto,et al.  Studies on Phthalocyanine Type Compounds (Part V*) Catalytic Behavior of Metal Phthalocyanine in the Hydrogen Atmosphere , 1990 .

[4]  O. S. Popov,et al.  Kinetic model and mechanism for selective hydrogenation of acetylene alcohols , 1988 .

[5]  O. Golubchikov,et al.  Applied Aspects of the Chemistry of the Porphyrins , 1986 .

[6]  I. Mochida,et al.  Enhanced catalytic activity of cobalt tetraphenylporphyrin on titanium dioxide by evacuation at elevated temperatures for intensifying the complex-support interaction , 1983 .

[7]  I. Mochida,et al.  Strong interaction of metallotetraphenylporphyrins with supporting metal oxides observed in the catalytic decomposition of hydrogen peroxide , 1982 .

[8]  T. Beringhelli,et al.  Oxygen chemisorption on γ-Al2O3·phthalocyaninato·-cobalt(II): Coordination of O2 by complexed cobalt centers; Tumbling of molecular oxygen on surface cobalt centers , 1982 .

[9]  I. Mochida,et al.  Modified electronic structure and enhanced catalytic activity of cobalt tetraphenylporphyrin supported by titanium dioxide , 1980 .

[10]  I. Okura,et al.  On the kinetics and the mechanism of hydrogen peroxide decomposition with silica-supported metallo-porphyrins , 1979 .

[11]  В. ю. Захаров,et al.  Определение дисперсности фталоцианинов в цеолитной матрице , 1977 .

[12]  T. Hara,et al.  The Liquid-phase Oxidation of Acetaldehyde with Metal Polyphthalocyanines. Solvent Effect , 1977 .

[13]  N. Kawashima,et al.  The Effect of Metal Oxides on the Transformation of Copper Phthalocyanine Crystals in Organic Solvents , 1976 .

[14]  D. Galizzioli,et al.  NEW ADDUCTS OF PHTHALOCYANINATOCOBALT(II) WITH PYRIDINE AND 4‐METHYLPYRIDINE AND THEIR VIBRATIONAL, MAGNETIC, AND ELECTRONIC PROPERTIES PART 1, REACTIVITY TOWARDS OXYGEN , 1975 .

[15]  T. Hara,et al.  Catalytic Activity of Metal Polyphthalocyanines in Autoxidation Reactions , 1975 .

[16]  J. Manassen,et al.  Heterogeneous and homogeneous catalysis by substituted cobalt tetraphenylporphyrins, and correlations with IR spectra , 1974 .

[17]  E. Davidson,et al.  Porphyrins XXVIII. Extended Hückel calculations on metal phthalocyanines and tetrazaporphins , 1973 .

[18]  Walker Fa.  Reactions of monomeric cobalt-oxygen complexes. I. Thermodynamics of reaction of molecular oxygen with five- and six-coordinate amine complexes of a cobalt porphyrin. , 1973 .

[19]  E. Fleischer,et al.  Reduction of acetylene and nitrogen by a cobalt-porphyrin system. , 1972, Journal of the American Chemical Society.

[20]  H. Kropf,et al.  Gasphasenhydrierung und Dehydrierung von Allylalkohol an Nickelphthalocyanin* , 1971 .

[21]  T. Kwan,et al.  Oxygenation of cobalt tetraphenylporphine as investigated by ESR spectroscopy , 1970 .

[22]  J. Manassen,et al.  Electrochemical and electron paramagnetic resonance studies of metalloporphyrins and their electrochemical oxidation products. , 1970, Journal of the American Chemical Society.

[23]  J. Manassen.  Metal complexes of phthalocyanine and $alpha;,$beta;,$gamma;,$delta;-tetraphenyl porphyrin as heterogeneous catalysts in oxidative dehydrogenation. Correlation between catalytic activity and redox potential , 1970 .

[24]  T. Kwan,et al.  On the Interaction of Oxygen with Cobalt Phthalocyanine in Solution as investigated by ESR , 1969 .

[25]  T. Onishi,et al.  Decomposition of Formic Acid over Metal Phthalocyanines , 1968 .

[26]  J. Sharp,et al.  Spectroscopic characterization of a new polymorph of metal-free phthalocyanine , 1968 .

[27]  S. E. Harrison,et al.  On the Origin of Unpaired Electrons in Metal-Free Phthalocyanine , 1964 .

[28]  H. Kuhn,et al.  Lichtabsorption und Assoziations- und Protonierungsgleichgewichte von Lösungen eines Cu-Phthalocyaninsulfonats , 1963 .

[29]  H. Taube,et al.  One-Electron Oxidation of Copper Phthalocyanine , 1951 .

[30]  H. Taniguchi,et al.  Amphiphilic Compounds Having Heterocycles. Effects of the Structure of Heterocycle on the Behavior of the Monolayer at the Air–Water Interface , 1990 .

[31]  O. Tkachenko,et al.  Xps Study of Transition Metal Complexes in Zeolites , 1984 .

[32]  F. Steinbach,et al.  Metal Phthalocyanines Used as Catalysts in Gas Phase Reactions , 1978 .

[33]  J. Zwart,et al.  Activation of cobalt–phthalocyanine catalyst by polymer attachment , 1976 .

[34]  W. V. Tilborg,et al.  Mechanism of the metal-phthalocyanine-catalysed oxidation of cumene in the liquid phase , 1975 .

[35]  D. Galizzioli,et al.  New adducts of phthalocyaninatocobalt(II) with pyridine and 4-methylpyridine and their vibrational, magnetic, and electronic properties. Part I. Reactivity towards oxygen , 1975 .

[36]  S. Naito,et al.  Oxidative Dehydrogenation of Alcohols over Metal Polyphthalocyanines , 1975 .

[37]  F. Steinbach,et al.  Heterogene Katalyse an komplex gebundenen Metallatomen am Beispiel der Propanol(2)dampfoxydation an Phthalocyaninpulvern , 1973 .

[38]  D. M. Wagnerová,et al.  Autooxidation of hydrazine catalyzed by tetrasulphophthalocyanines , 1973 .

[39]  M. Ichikawa,et al.  Catalytic activity and electron configuration of the EDA complexes of phthalocyanine with alkali metals. Hydrogen adsorption and the H2—D2 exchange reaction , 1972 .

[40]  J. Robertson,et al.  7. An X-ray study of the phthalocyanines. Part IV. Direct quantitative analysis of the platinum compound , 1940 .

[41]  A. H. Cook.  325. Catalytic properties of the phthalocyanines. Part I. Catalase properties , 1938 .

[42]  J. Robertson,et al.  37. An X-ray study of the phthalocyanines. Part III. Quantitative structure determination of nickel phthalocyanine , 1937 .