Development of an automatic system for the on-site pH measurement of soil samples

Abstract An automatic pH-measurement directly on-site on the farmland requires robust and reliable sensor systems. The massive antimony oxide electrode offers the possibility to determine the acidity in freshly sampled soils within the required range of pH 4 to pH 7 in a short time and without elaborate preparation steps. Some essential steps of the development of an antimony oxide sensor system applicable for the on-site measuring are presented in detail. The introduced set-up is a promising fundament for the establishment of a rapid pH-determination direct on the field.

[1]  Agner Fog,et al.  Electronic semiconducting oxides as pH sensors , 1984 .

[2]  S. Motellier,et al.  pH determination of clay interstitial water using a fiber-optic sensor , 1995 .

[3]  A. Uhl,et al.  Die elektrometrische Titration von Säuren und Basen mit der Antimon-Indikatorelektrode , 1923 .

[4]  C. Boyd,et al.  Poind Soil pH Measurement , 2001 .

[5]  H. Kahlert,et al.  A New Calibration Free pH‐Probe for In Situ Measurements of Soil pH , 2004 .

[6]  D. R. Ess,et al.  AN AUTOMATED SAMPLING SYSTEM FOR MEASURING SOIL pH , 1999 .

[7]  Dirk Gansert,et al.  A novel non-invasive optical method for quantitative visualization of pH dynamics in the rhizosphere of plants. , 2007, Plant, cell & environment.

[8]  Henning Matthiesen,et al.  In situ measurement of soil pH , 2004 .

[9]  J. Willaman,et al.  Measurement of Hydrogen–Ion Concentration in the Control of Pulp and Paper Manufacture1 , 1928 .

[10]  G. Perley Antimony electrode for industrial hydrogen-ion measurements , 1939 .

[11]  Christian Walter,et al.  Rapid, quantitative and spatial field measurements of soil pH using an Ion Sensitive Field Effect Transistor , 2004 .

[12]  E. J. Roberts,et al.  THE ANTIMONY-ANTIMONY TRIOXIDE ELECTRODE AND ITS USE AS A MEASURE OF ACIDITY1 , 1928 .

[13]  M. N. Quigley,et al.  Comparison of a combination pH electrode and field effect transistor electrode for the determination of soil pH and lime requirement , 1995 .

[14]  E. Snyder THE APPLICATION OF THE ANTIMONY ELECTORDE TO THE DETERMINATION OF THE pH VALUES OF SOILS , 1928 .

[15]  Marc-Oliver Aust,et al.  Time‐resolved in‐situ pH measurement in differently treated, saturated and unsaturated soils , 2015 .

[16]  U. Rascher,et al.  Monitoring rhizospheric pH, oxygen, and organic acid dynamics in two short-time flooded plant species , 2012 .

[17]  W. C. Purdy,et al.  The Antimony-Antimony Oxide Electrode , 1958 .

[18]  W. Fischer,et al.  Die Verwendung von Antimon-Elektroden zur pH-Messung in Böden , 1981 .

[19]  David C. Jones,et al.  Agitated soil measurement method for integrated on-the-go mapping of soil pH, potassium and nitrate contents , 2008 .

[20]  Min Wang,et al.  An electrochemical approach to monitor pH change in agar media during plant tissue culture. , 2007, Biosensors & bioelectronics.