PRODUCTS OF CHLOROPHYLL PHOTODEGRADATION–2. STRUCTURAL IDENTIFICATION

Abstract— Hydrophilic products of chlorophyll a photodegradation are structurally identified using UV/visible and fourier transform infrared spectrophotometry and gas chromatography‐mass spectrometry. The major peak detected during reverse‐phase high performance liquid chromatography of the colourless photodegradation products is identified as glycerol. Lactic, citric, succinic and malonic acids, as well as alanine, are also identified.

[1]  R. Brereton,et al.  PRODUCTS OF CHLOROPHYLL PHOTODEGRADATION–1. DETECTION and SEPARATION , 1990 .

[2]  Stanley B. Brown,et al.  THE DEGRADATION OF CHLOROPHYLL - A BIOLOGICAL ENIGMA. , 1987, The New phytologist.

[3]  E. W. Baker,et al.  The biogeochemistry of chlorophyll , 1986 .

[4]  R. Chalmers,et al.  Organic Acids in Man , 1983, Archives of disease in childhood.

[5]  Stanley B. Brown,et al.  The appearance of chlorophyll derivatives in senescing tissue , 1983 .

[6]  R. Troxler,et al.  Mechanism of photooxidation of bacteriochlorophyll c derivatives. A possible model for natural chlorophyll breakdown. , 1980, The Journal of biological chemistry.

[7]  J. Bolton,et al.  THE INVOLVEMENT OF THE HYDROXYL RADICAL IN THE DESTRUCTIVE PHOTOOXIDATION OF CHLOROPHYLLS IN VIVO AND IN VITRO * , 1978 .

[8]  N. Winograd,et al.  The role of water on the photoactivity of chlorophyll a. In vitro experimental characterization of the PSI Light Reaction in photosynthesis. , 1977, Journal of the American Chemical Society.

[9]  T. M. Korn,et al.  LOW‐TEMPERATURE PHOTCOXIDATION OF CHLOROPHYLL‐A * , 1972 .

[10]  D. Mauzerall,et al.  THE PHOTOOXYGENATION OF MAGNESIUM‐OCTAETHYLPORPHIN * , 1971 .

[11]  J. Jen,et al.  ON THE PHOTODECOMPOSITION OF CHLOROPHYLL IN VITRO‐II. INTERMEDIATES AND BREAKDOWN PRODUCTS * , 1970, Photochemistry and photobiology.

[12]  S. Aronoff,et al.  Investigations on the biogenesis of chlorophyll a. I. Purification and mass spectra of maleimides from the oxidation of chlorophyll and related compounds. , 1968, Archives of biochemistry and biophysics.

[13]  J. Barrett Photo-oxidation of Magnesium Porphyrins and Formation of Protobiliviolin , 1967, Nature.

[14]  C. Warner Formaldehyde as an Oxidation Product of Chlorophyll Extracts , 1914 .

[15]  H. Wager The Action of Light on Chlorophyll , 1914 .

[16]  S. H. Vines The Function of Chlorophyll , 1879, Nature.