Demonstration of forming complex patterns on a Ti-film using a nanosecond pulsed laser

It has always been difficult to process a metal film with high reflectivity in the field of manufacture, industry, medicine, and military, etc. Since much of the laser energy can be reflected especially when the reflectance of the target film surface is high, it is hard to process such a metallic film by laser radiation as the energy absorbed by the film material is very little. In this paper, we used a nanosecond pulsed laser to scribe some patterns on a smooth titanium (Ti) film, and investigated the surface morphology of a Ti film ablated by different laser spot sizes and laser energy. In our experiments, it has been found that the Ti film can be efficiently processed although the surface reflectance of the Ti film is about 57% at the wavelength of 532 nm. We also see that the processing range of the Ti film will decrease when the diameter of a laser beam increases. The experimental results show that the ablated status of the surface of a Ti film for a just-focus beam is much better than that for a defocus beam under the same laser power. Furthermore, the higher the laser power, the larger the processed area. By using the optimal parameters we obtained, we also produced some hole matrices and line patterns on a glass-based Ti film by employing a short pulsed laser. The processed samples were observed with a reflecting microscope and a transmitting microscope, respectively. Our research results can play an important role in the selection of laser parameters for laser processing of some materials with a high reflectivity.

[1]  J. Squier,et al.  Optimization study of the femtosecond laser-induced forward-transfer process with thin aluminum films. , 2007, Applied optics.

[2]  T. Kawai,et al.  Proliferation of mouse fibroblast‐like and osteoblast‐like cells on pure titanium films manufactured by electron beam melting , 2016, Cell biology international.

[3]  B. Jaleh,et al.  Formation of titanium carbide on the titanium surface using laser ablation in n-heptane and investigating its corrosion resistance , 2019, Applied Surface Science.

[4]  Matthew S. Dargusch,et al.  Nanoindentation and wear properties of Ti and Ti-TiB composite materials produced by selective laser melting , 2017 .

[5]  T. Höche,et al.  Laser welding of glasses using a nanosecond pulsed Nd:YAG laser , 2017 .

[6]  J. K. Chen,et al.  Ultrafast solid-liquid-vapor phase change of a thin gold film irradiated by femtosecond laser pulses and pulse trains , 2012 .

[7]  Jean-François Guillemoles,et al.  Comparative investigation of solar cell thin film processing using nanosecond and femtosecond lasers , 2006 .

[8]  A. Dostovalov,et al.  Study of the formation of thermochemical laser-induced periodic surface structures on Cr, Ti, Ni and NiCr films under femtosecond irradiation , 2017 .

[9]  A. Tünnermann,et al.  Femtosecond, picosecond and nanosecond laser ablation of solids , 1996 .

[10]  Nadezhda M. Bulgakova,et al.  Thermoelastic modeling of microbump and nanojet formation on nanosize gold films under femtosecond laser irradiation , 2006 .

[11]  A. Antończak,et al.  Characterisation of coloured TiOx/Ti/glass systems , 2014 .

[12]  A. Ionin,et al.  Single-shot selective femtosecond laser ablation of multi-layered Ti/Al and Ni/Ti films: “Cascaded” heat conduction and interfacial thermal effects , 2018 .

[13]  J. Kruth,et al.  A study of the microstructural evolution during selective laser melting of Ti–6Al–4V , 2010 .

[14]  M. Gedvilas,et al.  Thermochemical writing with high spatial resolution on Ti films utilising picosecond laser , 2019, Optical Materials Express.

[15]  Jae Hyuck Jang,et al.  Atomic structure of conducting nanofilaments in TiO2 resistive switching memory. , 2010, Nature nanotechnology.

[16]  O. Lehmann,et al.  High-rate laser-direct-write dry etching of titanium , 1996 .

[17]  D. Kent,et al.  Recent developments and opportunities in additive manufacturing of titanium-based matrix composites: A review , 2018, International Journal of Machine Tools and Manufacture.

[18]  Sergey A. Babin,et al.  Formation of thermochemical laser-induced periodic surface structures on Ti films by a femtosecond IR Gaussian beam: regimes, limiting factors, and optical properties , 2016 .

[19]  K. A. Yaacob,et al.  Effect of indirect irradiation on surface morphology of Au film by nanosecond laser , 2017 .

[20]  Z. Cai,et al.  Selective patterning and scribing of Ti thin film on glass substrate by 532 nm picosecond laser , 2012 .