Artificially produced rare-earth free cosmic magnet

Chemically ordered hard magnetic L10-FeNi phase of higher grade than cosmic meteorites is produced artificially. Present alloy design shortens the formation time from hundreds of millions of years for natural meteorites to less than 300 hours. Electron diffraction detects four-fold 110 superlattice reflections and a high chemical order parameter (S  0.8) for the developed L10-FeNi phase. The magnetic field of more than 3.5 kOe is required for the switching of magnetization. Experimental results along with computer simulation suggest that the ordered phase is formed due to three factors related to the amorphous state: high diffusion rates of the constituent elements at lower temperatures when crystallizing, a large driving force for precipitation of the L10 phase, and the possible presence of L10 clusters. Present results can resolve mineral exhaustion issues in the development of next-generation hard magnetic materials because the alloys are free from rare-earth elements, and the technique is well suited for mass production.

[1]  David B. Williams,et al.  Low-temperature phase decomposition in metal from iron, stony-iron, and stony meteorites , 1997 .

[2]  A. Makino,et al.  New Excellent Soft Magnetic FeSiBPCu Nanocrystallized Alloys With High $B_{s}$ of 1.9 T From Nanohetero-Amorphous Phase , 2009, IEEE Transactions on Magnetics.

[3]  E. Kita,et al.  Crystallization process and magnetic properties of Fe100−x,Bx (10 ≦ × ≦ 35) amorphous alloys and supersaturated state of boron inα-Fe , 1988 .

[4]  Akihiro Makino,et al.  Nanocrystalline Soft Magnetic Fe-Si-B-P-Cu Alloys With High $B$ of 1.8–1.9T Contributable to Energy Saving , 2012, IEEE Transactions on Magnetics.

[5]  J. Goldstein,et al.  Inspired by nature: investigating tetrataenite for permanent magnet applications , 2014, Journal of physics. Condensed matter : an Institute of Physics journal.

[6]  C. Larica,et al.  Thermal studies and magnetic properties of mechanical alloyed Fe2B , 2002 .

[7]  A. Bourret,et al.  Magnetization Curves of Fe–Ni (50–50) Single Crystals Ordered by Neutron Irradiation with an Applied Magnetic Field , 1968 .

[8]  Xiaobo Yin,et al.  Magnetic properties and magnetic domain structure of Nd6Dy2Fe82Co4B6 nanocomposite magnets , 2001 .

[9]  J. M. Short,et al.  Cooling rates of 27 iron and stony-iron meteorites , 1967 .

[10]  Michael J. Mehl,et al.  Phase stability in the Fe–Ni system: Investigation by first-principles calculations and atomistic simulations , 2005 .

[11]  A. Pasturel,et al.  The Fe–Ni system: Thermodynamic modelling assisted by atomistic calculations , 2010 .

[12]  L. Néel,et al.  Magnetic Properties of an Iron—Nickel Single Crystal Ordered by Neutron Bombardment , 1964 .

[13]  A. Makino,et al.  Magnetization reversal in a preferred oriented (111) L10 FePt grown on a soft magnetic metallic glass for tilted magnetic recording , 2012, Journal of physics. Condensed matter : an Institute of Physics journal.

[14]  Nan Yao,et al.  Natural Quasicrystals , 2009, Science.

[15]  M. Mizumaki,et al.  Structural, magnetic and electronic state characterization of L1 0-type ordered FeNi alloy extracted from a natural meteorite , 2014, Journal of physics. Condensed matter : an Institute of Physics journal.

[16]  T. Koganezawa,et al.  Addition of Co to L10-ordered FeNi films: influences on magnetic properties and ordered structures , 2014 .

[17]  A. Inoue,et al.  Iron-based bulk metallic glasses , 2013 .

[18]  A. Dinsdale SGTE data for pure elements , 1991 .

[19]  K. Lynn,et al.  Defect generation and analysis in mechanically alloyed stoichiometric Fe-Ni alloys , 2015 .

[20]  J. Goldstein,et al.  De Magnete et Meteorite: Cosmically Motivated Materials , 2014, IEEE Magnetics Letters.

[21]  S. Mitani,et al.  Structure and magnetic properties for L10-ordered FeNi films prepared by alternate monatomic layer deposition , 2007 .

[22]  K. Edalati,et al.  Formation of FeNi with L10-ordered structure using high-pressure torsion , 2014 .

[23]  X. M. Zhang,et al.  Competition driven nanocrystallization in high Bs and low coreloss Fe–Si–B–P–Cu soft magnetic alloys , 2015 .

[24]  Parmanand Sharma,et al.  High coercivity characteristics of FePtB exchange-coupled nanocomposite thick film spring magnets produced by sputtering , 2007 .

[25]  J. M. Knudsen,et al.  Meteorites and thermodynamic equilibrium in f.c.c. iron-nickel alloys (25 - 50%Ni). , 1980 .