Sensitively Humidity‐Driven Actuator Based on Photopolymerizable PEG‐DA Films

Hydrogels such as poly(ethylene glycol) diacrylate are a class of cross-linked polymers that have the ability to absorb water and change volume. Here, a humidity responsiveness of hydrogel film fabricated by the photopolymerization of poly(ethylene glycol) diacrylate (PEG-DA) monomer is reported. This kind of film could be driven by a small humidity gradient, thus spontaneous deformation and motion can be achieved by placing the film onto a moist filter paper. The influence factors of humidity response sensitivity such as the exposure time and number-average molecular weight of PEG-DA monomer used during the fabrication are investigated. Under different relative humidity, the film displays different degrees of pink color and the intensities of fluorescence under 365 nm illumination are also different, which renders the film to be used as a “humidity test strip.” A humidity-driven walking device is fabricated and the walking velocity is about 3 mm min−1 under the actuating water vapor. Vapor of volatile polar solvents could also drive the actuator to achieve fast deformation and shows the variety of the film responsivity.

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