Non-destructive micro-analytical system for the study of the manufacturing processes of a group of gold jewels from "El Carambolo" treasure

Abstract The impressive gold treasure of El Carambolo, representative of the Tartesic culture and dated from the 8th to 6th century BCE, constitutes a typological and stylistic unity unparalleled in the archeological field. Due to the importance of this treasure and the interest in studying it in depth, a new micro X-ray fluorescence (micro-XRF) portable system has been developed at the Centro Nacional de Aceleradores (Sevilla, Spain). Eleven jewels of El Carambolo treasure have been analyzed in order to characterize the composition of the employed alloys, to identify the manufacturing processes and to discuss hypothesis about the production workshop of the treasure. Besides, the application of the new micro-XRF instrumentation allowed the analysis of small details like decoration elements and joining areas. This study permits the characterization of the joining methods and manufacturing procedures, thus, the construction stages of these highly complex jewels can be inferred. Many archeological and historical studies of the treasure have been performed during the last years but very few analytical results have been published. Furthermore, the results demonstrate the capability of the new developed portable micro-XRF setup to substitute satisfactorily other micro-analytical techniques, such as micro-PIXE (Particle Induced X-ray Emission), when the sample cannot be brought to a laboratory.

[1]  B. Gómez-Tubío,et al.  External-beam PIXE spectrometry for the study of Punic jewellery (SW Spain): The geographical provenance of the palladium-bearing gold , 2006 .

[2]  Charles P. Swann,et al.  PIXE spectrometry as an archaeometric tool , 1986 .

[3]  M. A. Respaldiza,et al.  PIXE–PIGE analysis of a Visigothic gold cross , 2004 .

[4]  J. L. Carrasco,et al.  Revestidos como Dios manda. El tesoro del Carambolo como ajuar de consagración , 2011 .

[5]  José M. Torres-Ruiz,et al.  Tertiary and Quaternary alluvial gold deposits of Northwest Spain and Roman mining (NW of Duero and Bierzo Basins) , 2000 .

[6]  A. Oddy The production of gold wire in antiquity , 1977 .

[7]  A. G. Karydas,et al.  A compositional study of a museum jewellery collection (7th–1st BC) by means of a portable XRF spectrometer , 2004 .

[8]  Alfredo Mederos Martín La metamorfosis de Villena. Comercio de oro, estaño y sal durante el Bronce Final I entre el Atlántico y el Mediterráneo (1625-1300 AC) , 1999 .

[9]  S. Scrivano,et al.  Identification of soldering and welding processes in ancient gold jewelry by micro-XRF spectroscopy , 2013 .

[10]  M. A. Respaldiza,et al.  External microbeam set-up at the CNA (Sevilla) and its application to the study of Tartesic jewellery , 2001 .

[11]  G. Demortier,et al.  PIXE in an external microbeam arrangement for the study of finely decorated tartesic gold jewellery items , 1999 .

[12]  Salvatore Siano,et al.  Modern and ancient gold jewellery attributed to the Etruscans: a science-based study , 2009 .

[13]  P. Parrini,et al.  Etruscan Filigree: Welding Techniques of Two Gold Bracelets from Vetulonia , 1983, American Journal of Archaeology.

[14]  G. Raynor,et al.  Phase Diagrams of Ternary Gold Alloys , 1990 .

[15]  A. Hauptmann,et al.  Bronze Age gold in Southern Georgia , 2009 .

[16]  A. G. Karydas,et al.  A portable semi-micro-X-ray fluorescence spectrometer for archaeometrical studies ☆ , 2004 .

[17]  B. Gómez-Tubío,et al.  Gold and electrum jewellery in the strategic area of Gadir in Phoenician period , 2007 .

[18]  R. Hough,et al.  The crystallography, metallography and composition of gold. , 2009 .

[19]  M. Guerra,et al.  In-situ examination and analysis of the gold jewellery from the Phoenician tomb of Kition (Cyprus) , 2009 .

[20]  M. A. Respaldiza,et al.  PIXE and SEM studies of Tartesic gold artefacts , 1998 .

[21]  Barbara Armbruster,et al.  Tecnología de herramientas rotativas durante el bronce final atlántico: el depósito de Villena , 1994 .

[22]  A. Perea Estudio microscópico y microanalítico de las soldaduras y otros procesos técnicos en la orfebrería prehistórica del Sur de la Península Ibérica , 1990 .

[23]  R. F. Tylecote,et al.  A History of Metallurgy , 1976 .

[24]  Alvaro Fernández Flores,et al.  El Carambolo, secuencia cronocultural del yacimiento. Síntesis de las intervenciones 2002-2005 , 2010 .

[25]  J. Ogden Jewellery of The Ancient World , 1983 .