Three‐Dimensional Printing of Multifunctional Nanocomposites: Manufacturing Techniques and Applications

The integration of nanotechnology into three-dimensional printing (3DP) offers huge potential and opportunities for the manufacturing of 3D engineered materials exhibiting optimized properties and multifunctionality. The literature relating to different 3DP techniques used to fabricate 3D structures at the macro- and microscale made of nanocomposite materials is reviewed here. The current state-of-the-art fabrication methods, their main characteristics (e.g., resolutions, advantages, limitations), the process parameters, and materials requirements are discussed. A comprehensive review is carried out on the use of metal- and carbon-based nanomaterials incorporated into polymers or hydrogels for the manufacturing of 3D structures, mostly at the microscale, using different 3D-printing techniques. Several methods, including but not limited to micro-stereolithography, extrusion-based direct-write technologies, inkjet-printing techniques, and popular powder-bed technology, are discussed. Various examples of 3D nanocomposite macro- and microstructures manufactured using different 3D-printing technologies for a wide range of domains such as microelectromechanical systems (MEMS), lab-on-a-chip, microfluidics, engineered materials and composites, microelectronics, tissue engineering, and biosystems are reviewed. Parallel advances on materials and techniques are still required in order to employ the full potential of 3D printing of multifunctional nanocomposites.

[1]  Haiqing Peng,et al.  Sidewall Amino-Functionalization of Single-Walled Carbon Nanotubes through Fluorination and Subsequent Reactions with Terminal Diamines , 2003 .

[2]  Daniel E. Resasco,et al.  Functionalization of Single-Walled Carbon Nanotubes with Polystyrene via Grafting to and Grafting from Methods , 2004 .

[3]  C. P. Purssell,et al.  A miniature flow sensor fabricated by micro-stereolithography employing a magnetite/acrylic nanocomposite resin , 2011 .

[4]  Mehdi Hojjati,et al.  Review article: Polymer-matrix Nanocomposites, Processing, Manufacturing, and Application: An Overview , 2006 .

[5]  B. Aïssa,et al.  Micromechanical characterization of single-walled carbon nanotube reinforced ethylidene norbornene nanocomposites for self-healing applications , 2012 .

[6]  Mohammed H Al-Saleh,et al.  Copper nanowire/polystyrene nanocomposites: Lower percolation threshold and higher EMI shielding , 2011 .

[7]  Michael C. McAlpine,et al.  3D printed quantum dot light-emitting diodes. , 2014, Nano letters.

[8]  E. Toyserkani,et al.  Additive Manufacturing of Graphene–Hydroxyapatite Nanocomposite Structures , 2015 .

[9]  D. Therriault,et al.  Solvent-cast three-dimensional printing of multifunctional microsystems. , 2013, Small.

[10]  Lin Li,et al.  Carbon Nanotube/Polypropylene Composite Particles for Microwave Welding , 2012 .

[11]  Zhanhu Guo,et al.  In situ stabilized carbon nanofiber (CNF) reinforced epoxy nanocomposites , 2010 .

[12]  John A. Rogers,et al.  Omnidirectional Printing of Flexible, Stretchable, and Spanning Silver Microelectrodes , 2009, Science.

[13]  S. Iijima.  Helical microtubules of graphitic carbon , 1991, Nature.

[14]  Kukjoo Kim,et al.  Direct printing of reduced graphene oxide on planar or highly curved surfaces with high resolutions using electrohydrodynamics. , 2015, Small.

[15]  Marco Pirola,et al.  Hybrid Ag-based inks for nanocomposite inkjet printed lines: RF properties , 2014 .

[16]  Karl Schulte,et al.  Synergistic effects in network formation and electrical properties of hybrid epoxy nanocomposites containing multi-wall carbon nanotubes and carbon black , 2009 .

[17]  J. Czyżewski,et al.  Rapid prototyping of electrically conductive components using 3D printing technology , 2009 .

[18]  Erik H. Waller,et al.  Three‐Dimensional μ‐Printing: An Enabling Technology , 2015 .

[19]  G. Botton,et al.  Polymerization from the surface of single-walled carbon nanotubes - preparation and characterization of nanocomposites. , 2003, Journal of the American Chemical Society.

[20]  C. Decker,et al.  Photoinitiated crosslinking polymerisation , 1996 .

[21]  M. Rong,et al.  Surface modification of nanoscale fillers for improving properties of polymer nanocomposites: A review , 2006 .

[22]  M. Moniruzzaman,et al.  Increased flexural modulus and strength in SWNT/epoxy composites by a new fabrication method , 2006 .

[23]  K. Leong,et al.  Solid freeform fabrication of three-dimensional scaffolds for engineering replacement tissues and organs. , 2003, Biomaterials.

[24]  A. Rinzler,et al.  Fluorination of single-wall carbon nanotubes , 1998 .

[25]  Mohsen A. Jafari,et al.  Processing of advanced electroceramic components by fused deposition technique , 2001 .

[26]  James M Tour,et al.  Overcoming the insolubility of carbon nanotubes through high degrees of sidewall functionalization. , 2004, Chemistry.

[27]  UV‐assisted three‐dimensional printing of polymer nanocomposites based on inorganic fillers , 2017 .

[28]  D. Therriault,et al.  Reinforcing epoxy nanocomposites with functionalized carbon nanotubes via biotin–streptavidin interactions , 2012 .

[29]  Jieqiong Lin,et al.  A review on the processing accuracy of two-photon polymerization , 2015 .

[30]  Jun Yeob Song,et al.  High‐Resolution Printing of 3D Structures Using an Electrohydrodynamic Inkjet with Multiple Functional Inks , 2015, Advanced materials.

[31]  Daniel Therriault,et al.  Ultraviolet‐Assisted Direct‐Write Fabrication of Carbon Nanotube/Polymer Nanocomposite Microcoils , 2010, Advanced materials.

[32]  G. Engelmann,et al.  Complete 3D UV microfabrication technology on strongly sloping topography substrates using epoxy photoresist SU-8 , 2004 .

[33]  Jonathan N. Coleman,et al.  Mechanical Reinforcement of Polymers Using Carbon Nanotubes , 2006 .

[34]  Caroline Sunyong Lee,et al.  Measurement of anisotropic compressive strength of rapid prototyping parts , 2007 .

[35]  Daniel Therriault,et al.  Processing parameters investigation for the fabrication of self-supported and freeform polymeric microstructures using ultraviolet-assisted three-dimensional printing , 2014 .

[36]  D. Therriault,et al.  Helical Dielectrophoretic Particle Separator Fabricated by Conformal Spindle Printing , 2014 .

[37]  T. Chou,et al.  Processing-structure-multi-functional property relationship in carbon nanotube/epoxy composites , 2006 .

[38]  B. Nalini,et al.  Cellulose derivatives as excellent dispersants for single-wall carbon nanotubes as demonstrated by absorption and photoluminescence spectroscopy , 2006 .

[39]  J. Lewis,et al.  Direct writing in three dimensions , 2004 .

[40]  Mark A. Ganter,et al.  A review of process development steps for new material systems in three dimensional printing (3DP) , 2008 .

[41]  Daniel M. Vogt,et al.  Capacitive Soft Strain Sensors via Multicore–Shell Fiber Printing , 2015, Advanced materials.

[42]  Jiahua Zhu,et al.  An overview of the engineered graphene nanostructures and nanocomposites , 2013 .

[43]  M. Khakani,et al.  Manufacturing composite beams reinforced with three-dimensionally patterned-oriented carbon nanotubes through microfluidic infiltration , 2012 .

[44]  Nanocomposites of graphene/polymers: a review , 2015 .

[45]  M. Khakani,et al.  Micro-infiltration of three-dimensional porous networks with carbon nanotube-based nanocomposite for material design , 2011 .

[46]  K. Kern,et al.  Microcontact Printing of CdS/Dendrimer Nanocomposite Patterns on Silicon Wafers , 2004 .

[47]  W. E. Billups,et al.  Fluorination of single-wall carbon nanotubes and subsequent derivatization reactions. , 2002, Accounts of chemical research.

[48]  Paul J. Campagnola,et al.  Submicron Multiphoton Free-Form Fabrication of Proteins and Polymers: Studies of Reaction Efficiencies and Applications in Sustained Release , 2000 .

[49]  Yunqi Liu,et al.  Freestanding graphene paper supported three-dimensional porous graphene-polyaniline nanocomposite synthesized by inkjet printing and in flexible all-solid-state supercapacitor. , 2014, ACS applied materials & interfaces.

[50]  Jennifer Fielding,et al.  Carbon nanofiber paper for lightning strike protection of composite materials , 2010 .

[51]  J. Muth,et al.  3D Printing of Free Standing Liquid Metal Microstructures , 2013, Advanced materials.

[52]  Pierre J. Carreau,et al.  Flow induced orientation of multiwalled carbon nanotubes in polycarbonate nanocomposites: Rheology, conductivity and mechanical properties , 2010 .

[53]  Ahmad Safari,et al.  Processing of advanced electroceramic components by fused deposition technique , 2001 .

[54]  J. Tour,et al.  Water-soluble, exfoliated, nonroping single-wall carbon nanotubes. , 2004, Journal of the American Chemical Society.

[55]  G. Hwang,et al.  Efficient Load Transfer to Polymer‐Grafted Multiwalled Carbon Nanotubes in Polymer Composites , 2004 .

[56]  Satoshi Kawata,et al.  Finer features for functional microdevices , 2001, Nature.

[57]  David A. Hutchins,et al.  A Simple, Low-Cost Conductive Composite Material for 3D Printing of Electronic Sensors , 2012, PloS one.

[58]  J. Lewis,et al.  Microperiodic structures: Direct writing of three-dimensional webs , 2004, Nature.

[59]  Marinella Levi,et al.  Conductive 3D microstructures by direct 3D printing of polymer/carbon nanotube nanocomposites via liquid deposition modeling , 2015 .

[60]  R. Smalley,et al.  Oxygen-containing functional groups on single-wall carbon nanotubes: NEXAFS and vibrational spectroscopic studies. , 2001, Journal of the American Chemical Society.

[61]  Daniel Therriault,et al.  Properties of polylactide inks for solvent-cast printing of three-dimensional freeform microstructures. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[62]  A. I. Alateyah,et al.  Processing, Properties, and Applications of Polymer Nanocomposites Based on Layer Silicates: A Review , 2013 .

[63]  Tang Yiping,et al.  Nano‐TiO2‐modified photosensitive resin for RP , 2011 .

[64]  G. Lubineau,et al.  Thermal conductivity and stability of a three‐phase blend of carbon nanotubes, conductive polymer, and silver nanoparticles incorporated into polycarbonate nanocomposites , 2015 .

[65]  Wei Zhu,et al.  Bio-inspired detoxification using 3D-printed hydrogel nanocomposites , 2014, Nature Communications.

[66]  M. Khakani,et al.  Electrical transport properties of single wall carbon nanotube/polyurethane composite based field effect transistors fabricated by UV-assisted direct-writing technology , 2012, Nanotechnology.

[67]  Koji Ikuta,et al.  A three-dimensional microfabrication system for biodegradable polymers with high resolution and biocompatibility , 2008 .

[68]  J. Lewis,et al.  Conformal Printing of Electrically Small Antennas on Three‐Dimensional Surfaces , 2011, Advanced materials.

[69]  Jae-Won Choi,et al.  Conformal direct-print of piezoresistive polymer/nanocomposites for compliant multi-layer tactile sensors , 2015 .

[70]  M. Khakani,et al.  Preparation and mechanical characterization of laser ablated single-walled carbon-nanotubes/polyurethane nanocomposite microbeams , 2010 .

[71]  Jin-Woo Choi,et al.  Patterning conductive PDMS nanocomposite in an elastomer using microcontact printing , 2009 .

[72]  J. Lewis,et al.  Phase behavior and rheological properties of polyelectrolyte inks for direct-write assembly. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[73]  Robert H. Hauge,et al.  Purification and Characterization of Single-Wall Carbon Nanotubes (SWNTs) Obtained from the Gas-Phase Decomposition of CO (HiPco Process) , 2001 .

[74]  Dimitris C. Lagoudas,et al.  Mechanical properties of surface-functionalized SWCNT/epoxy composites , 2008 .

[75]  J. Cesarano,et al.  Directed colloidal assembly of 3D periodic structures , 2002 .

[76]  Sheng Liu,et al.  Single-walled carbon nanotube network/poly composite thin film for flow sensor , 2010 .

[77]  J. Rogers,et al.  Mechanisms, Capabilities, and Applications of High-Resolution Electrohydrodynamic Jet Printing. , 2015, Small.

[78]  Qinglin Sheng,et al.  A sandwich-type phenolic biosensor based on tyrosinase embedding into single-wall carbon nanotubes and polyaniline nanocomposites , 2013 .

[79]  Wei Wang,et al.  Conductivity improvement of silver flakes filled electrical conductive adhesives via introducing silver–graphene nanocomposites , 2014, Journal of Materials Science: Materials in Electronics.

[80]  R. Smalley,et al.  Infrared Spectral Evidence for the Etching of Carbon Nanotubes: Ozone Oxidation at 298 K , 2000 .

[81]  Richard E. Smalley,et al.  Enhancement of adsorption inside of single-walled nanotubes: opening the entry ports , 2000 .

[82]  Hiroto Murakami,et al.  Noncovalent porphyrin-functionalized single-walled carbon nanotubes in solution and the formation of porphyrin-nanotube nanocomposites , 2003 .

[83]  Thomas A. Campbell,et al.  Inkjet Printing of Quantum Dots in Photopolymer for Use in Additive Manufacturing of Nanocomposites , 2013 .

[84]  Joong Tark Han,et al.  3D Printing of Reduced Graphene Oxide Nanowires , 2015, Advanced materials.

[85]  J. Lewis,et al.  Chaotic mixing in three-dimensional microvascular networks fabricated by direct-write assembly , 2003, Nature materials.

[86]  J. Fischer,et al.  Three‐dimensional optical laser lithography beyond the diffraction limit , 2013 .

[87]  Chuck Zhang,et al.  Effective amino-functionalization of carbon nanotubes for reinforcing epoxy polymer composites , 2006, Nanotechnology.

[88]  M. Padgett,et al.  Development of a 3D printer using scanning projection stereolithography , 2015, Scientific Reports.

[89]  D. Poulikakos,et al.  Direct printing of nanostructures by electrostatic autofocussing of ink nanodroplets , 2012, Nature Communications.

[90]  Ruth D. Goodridge,et al.  Processing of a Polyamide-12/carbon nanofibre composite by laser sintering , 2011 .

[91]  A. Chiolerio,et al.  Radical diffusion engineering: tailored nanocomposite materials for piezoresistive inkjet printed strain measurement , 2013 .

[92]  Chuck Zhang,et al.  Reinforcing polymer composites with epoxide-grafted carbon nanotubes , 2008, Nanotechnology.

[93]  Nancy R. Sottos,et al.  Accelerated Self‐Healing Via Ternary Interpenetrating Microvascular Networks , 2011 .

[94]  J. Lian,et al.  Annealed graphene sheets decorated with silver nanoparticles for inkjet printing , 2015 .

[95]  S. Goh,et al.  Enhancement of the mechanical properties of poly(styrene-co-acrylonitrile) with poly(methyl methacrylate)-grafted multiwalled carbon nanotubes , 2005 .

[96]  Martin Lévesque,et al.  Direct-write fabrication of freestanding nanocomposite strain sensors , 2012, Nanotechnology.

[97]  Jim Euchner.  Design , 2014, Catalysis from A to Z.

[98]  J. Lewis,et al.  Fugitive Inks for Direct‐Write Assembly of Three‐Dimensional Microvascular Networks , 2005 .

[99]  Jean-Pierre Kruth,et al.  Composites by rapid prototyping technology , 2010 .

[100]  N. Hu,et al.  Tunneling effect in a polymer/carbon nanotube nanocompositestrain sensor , 2008 .

[101]  Sailing He,et al.  Rapid Fabrication of Complex 3D Extracellular Microenvironments by Dynamic Optical Projection Stereolithography , 2012, Advanced materials.

[102]  D. Therriault,et al.  Enhanced conductivity of nanocomposite films through heterogeneous distribution of nanofillers during processing , 2015 .

[103]  J. Lewis,et al.  3D‐Printing of Lightweight Cellular Composites , 2014, Advanced materials.

[104]  J. Tour,et al.  Covalent Functionalization of Single-Walled Carbon Nanotubes for Materials Applications , 2004 .

[105]  I. Ghasemi,et al.  Acoustic Performance of 3D Printed Nanocomposite Earmuff , 2015, Global journal of health science.

[106]  D. Therriault,et al.  Three-dimensional printing of freeform helical microstructures: a review. , 2014, Nanoscale.

[107]  Hermann Seitz,et al.  A review on 3D micro-additive manufacturing technologies , 2012, The International Journal of Advanced Manufacturing Technology.

[108]  D. Therriault,et al.  3D printing of a multifunctional nanocomposite helical liquid sensor. , 2015, Nanoscale.

[109]  Thuc P. Vo,et al.  Epoxy/graphene nanocomposites – processing and properties: a review , 2015 .

[110]  A. Chiolerio,et al.  Inkjet printed acrylic formulations based on UV-reduced graphene oxide nanocomposites , 2013, Journal of Materials Science.

[111]  Katsumi Tanigaki,et al.  Opening and purification of carbon nanotubes in high yields , 1995 .

[112]  Nathan J. Castro,et al.  Design of a Novel 3D Printed Bioactive Nanocomposite Scaffold for Improved Osteochondral Regeneration , 2015, Cellular and molecular bioengineering.