A simple approach in fabricating chemical sensor using laterally grown multi-walled carbon nanotubes

Abstract In this work, we proposed a new process for fabricating chemical sensors employing multi-walled carbon nanotubes (MWNTs) as the active sensing element. The MWNTs were selectively grown between lateral sides of the catalytic metals on pre-defined Nb electrodes. Upon exposure to air or NH 3 , the electrical resistance of the MWNTs is found to decrease or increase, respectively. The response time decreases and the sensitivity increases while measurement temperature and gas concentration increase. Though there are a few technical problems to be solved, our results show a promising technique for chemical gas sensor.

[1]  Kong,et al.  Nanotube molecular wires as chemical sensors , 2000, Science.

[2]  S. Tans,et al.  Molecular transistors: Potential modulations along carbon nanotubes , 2000, Nature.

[3]  W. D. de Heer,et al.  Carbon Nanotubes--the Route Toward Applications , 2002, Science.

[4]  Zettl,et al.  Extreme oxygen sensitivity of electronic properties of carbon nanotubes , 2000, Science.

[5]  Herbert Shea,et al.  Single- and multi-wall carbon nanotube field-effect transistors , 1998 .

[6]  Yoshinori Ando,et al.  Electrical conductivities of multi-wall carbon nano tubes , 1999 .

[7]  Charles M. Lieber,et al.  Carbon nanotube-based nonvolatile random access memory for molecular computing , 2000, Science.

[8]  B. Ju,et al.  Lateral growth of aligned mutilwalled carbon nanotubes under electric field , 2003 .

[9]  Hongjie Dai,et al.  Electrical measurements of individual semiconducting single-walled carbon nanotubes of various diameters , 2000 .

[10]  Gerhard Wiegleb,et al.  Semiconductor gas sensor for detecting NO and CO traces in ambient air of road traffic , 1994 .

[11]  Jijun Zhao,et al.  Gas molecule adsorption in carbon nanotubes and nanotube bundles , 2002 .

[12]  David E. Williams Semiconducting oxides as gas-sensitive resistors , 1999 .

[13]  S. Tans,et al.  Room-temperature transistor based on a single carbon nanotube , 1998, Nature.

[14]  Eklund,et al.  Effects of gas adsorption and collisions on electrical transport in single-walled carbon nanotubes , 2000, Physical review letters.

[15]  Craig A. Grimes,et al.  A wireless, passive carbon nanotube-based gas sensor , 2002 .

[16]  Jose Maria Kenny,et al.  Sensors for sub-ppm NO2 gas detection based on carbon nanotube thin films , 2003 .