Facile fabrication of an electrolyte-gated In2O3 nanoparticle-based thin-film transistor uniting laser ablation and inkjet printing

We propose the inkjet printing of new thin-film transistors (TFTs) based upon a sodium alginate (NaAlg) electrolyte–gate and a new In2O3 nanoparticle ink in which the electrodes and channels were formed by laser ablation. Laser ablation improved the conductive ink channel resolution leading to a smaller channel length through low-temperature processing steps. The NaAlg based electrolyte and a thickness independent gate dielectric allow for an in-plane design resulting in relaxed manufacturing tolerance requirements and reduced processing steps/time. The fabricated TFT operates at a very low voltage (<1.5 V) with a measured field-effect mobility of 0.77 cm2 V−1 s−1 and an ON/OFF current ratio exceeding 105. The electrolyte-gated TFTs exhibit excellent durability over 1500 switching cycles and 10 days. The TFTs demonstrate no cytotoxicity in vitro, indicating that they have the potential to be suitable for low-cost environmentally friendly electronics and biosensor applications.

[1]  T. Guo,et al.  Solution-processed metal oxide arrays using femtosecond laser ablation and annealing for thin-film transistors , 2017 .

[2]  M. Aegerter,et al.  Direct gravure printing of indium tin oxide nanoparticle patterns on polymer foils , 2008 .

[3]  Ulrich S. Schubert,et al.  Novel approaches for low temperature sintering of inkjet-printed inorganic nanoparticles for roll-to-roll (R2R) applications , 2013 .

[4]  Kazuhito Tsukagoshi,et al.  High-density electrostatic carrier doping in organic single-crystal transistors with polymer gel electrolyte , 2006 .

[5]  Costas P. Grigoropoulos,et al.  Fabrication of multilayer passive and active electric components on polymer using inkjet printing and low temperature laser processing , 2007 .

[6]  C. Frisbie,et al.  High Carrier Density and Metallic Conductivity in Poly(3‐hexylthiophene) Achieved by Electrostatic Charge Injection , 2006 .

[7]  H. Hahn,et al.  Temperature tolerance study of high performance electrochemically gated SnO2 nanowire field-effect transistors , 2013 .

[8]  E. Fortunato,et al.  Fully solution-induced high performance indium oxide thin film transistors with ZrOx high-k gate dielectrics , 2018, RSC advances.

[9]  Hyun-Joong Chung,et al.  Electronic transport properties of amorphous indium-gallium-zinc oxide semiconductor upon exposure to water , 2008 .

[10]  Alejandro de la Fuente Vornbrock,et al.  Printing Techniques for Thin‐Film Electronics , 2012 .

[11]  S. Seki,et al.  Electronic functionalization of solid-to-liquid interfaces between organic semiconductors and ionic liquids: Realization of very high performance organic single-crystal transistors , 2008 .

[12]  Kentaro Ito,et al.  High efficiency indium oxide/cadmium telluride solar cells , 1987 .

[13]  Xuan Cao,et al.  Highly Sensitive and Wearable In2O3 Nanoribbon Transistor Biosensors with Integrated On-Chip Gate for Glucose Monitoring in Body Fluids. , 2018, ACS nano.

[14]  D. Schroder.  Semiconductor Material and Device Characterization , 1990 .

[15]  Eugenio Cantatore,et al.  Applications of Organic and Printed Electronics , 2013 .

[16]  Ghassan E. Jabbour,et al.  Inkjet Printing: Inkjet Printing—Process and Its Applications (Adv. Mater. 6/2010) , 2010 .

[17]  C. Frisbie,et al.  Polymer electrolyte-gated organic field-effect transistors: low-voltage, high-current switches for organic electronics and testbeds for probing electrical transport at high charge carrier density. , 2007, Journal of the American Chemical Society.

[18]  Young-Jin Kwack,et al.  Electrohydrodynamic Jet Printed Indium–Zinc–Oxide Thin-Film Transistors , 2016, Journal of Display Technology.

[19]  Eugenio Cantatore,et al.  Applications of organic and printed electronics : a technology-enabled revolution , 2013 .

[20]  Hailong Hu,et al.  Inkjet-Printed In-Ga-Zn Oxide Thin-Film Transistors with Laser Spike Annealing , 2017, Journal of Electronic Materials.

[21]  Kevin J Edgar,et al.  Alginate derivatization: a review of chemistry, properties and applications. , 2012, Biomaterials.

[22]  H. Tønnesen,et al.  Alginate in Drug Delivery Systems , 2002, Drug development and industrial pharmacy.

[23]  Allison A. Cargill,et al.  3D nanostructured inkjet printed graphene via UV-pulsed laser irradiation enables paper-based electronics and electrochemical devices. , 2016, Nanoscale.

[24]  Horst Hahn,et al.  A general route toward complete room temperature processing of printed and high performance oxide electronics. , 2015, ACS nano.

[25]  Daihua Zhang,et al.  Electronic transport studies of single-crystalline In2O3 nanowires , 2003 .

[26]  S. K. Garlapati,et al.  Electrolyte-gated, high mobility inorganic oxide transistors from printed metal halides. , 2013, ACS applied materials & interfaces.

[27]  Yeon-Gon Mo,et al.  Origin of threshold voltage instability in indium-gallium-zinc oxide thin film transistors , 2008 .

[28]  H. Hahn,et al.  High‐Speed, Low‐Voltage, and Environmentally Stable Operation of Electrochemically Gated Zinc Oxide Nanowire Field‐Effect Transistors , 2013 .

[29]  É. Cavalheiro,et al.  Thermal behavior of alginic acid and its sodium salt , 2004, Ecletica Quimica.

[30]  Chih-hung Chang,et al.  Low-temperature, high-performance, solution-processed indium oxide thin-film transistors. , 2011, Journal of the American Chemical Society.

[31]  W. Cho,et al.  High-performance a-IGZO thin-film transistor with conductive indium-tin-oxide buried layer , 2017 .

[32]  Sheikh A. Akbar,et al.  Gas Sensors Based on One Dimensional Nanostructured Metal-Oxides: A Review , 2012, Sensors.

[33]  Pedro Barquinha,et al.  Solvothermal synthesis of gallium-indium-zinc-oxide nanoparticles for electrolyte-gated transistors. , 2015, ACS applied materials & interfaces.

[34]  Horst Hahn,et al.  Inkjet printed, high mobility inorganic-oxide field effect transistors processed at room temperature. , 2011, ACS nano.

[35]  G. Jabbour,et al.  Inkjet Printing—Process and Its Applications , 2010, Advanced materials.

[36]  T. Guo,et al.  Solution-Processed Organic Thin-Film Transistor Arrays with the Assistance of Laser Ablation. , 2017, ACS applied materials & interfaces.

[37]  Shimpei Ono,et al.  A comparative study of organic single-crystal transistors gated with various ionic-liquid electrolytes , 2009 .

[38]  M. Hersam,et al.  Inkjet printed circuits based on ambipolar and p-type carbon nanotube thin-film transistors , 2017, Scientific Reports.

[39]  Wei Zhang,et al.  Printed Sub‐2 V Gel‐Electrolyte‐Gated Polymer Transistors and Circuits , 2010 .

[40]  Mario Caironi,et al.  High-resolution direct-writing of metallic electrodes on flexible substrates for high performance organic field effect transistors , 2013 .

[41]  J. Rhim,et al.  Kinetics of Water Vapor Absorption by Sodium Alginate-based Films , 2008 .

[42]  H. Wiggers,et al.  Stable colloidal dispersions of silicon nanoparticles for the fabrication of films using inkjet printing technology , 2010, 2010 3rd International Nanoelectronics Conference (INEC).