Key developments in CIGS thin film solar cells on ceramic substrates

Nowadays the improvement of the photovoltaic building-integration (BIPV) has become very important. In fact, more emphasis has been put on the possibility of producing photovoltaic modules able to be integrated, or even to be directly assembled to form the so-called ventilated walls for buildings. This integration can be improved by using, alternatively to glass, other materials for the substrate or for the final “box”, in which the solar cells are encapsulated. A good candidate as a substrate material that substitutes the glass is ceramic. This kind of non-transparent substrates is useful in the substrate configuration solar cell technology. An example of this technology is represented by the Cu(In,Ga)Se2-based solar cells. The challenge in this field corresponds to directly use, as a substrate large dimension ceramic tiles, which are commercially available on the market. For this reason, the process technology developed at ThiFiLab for glass substrates has been transferred on this kind of new substrates and some solar cells have been produced showing efficiencies in the range of 12–14%.

[1]  P. Fons,et al.  Buried p-n junction formation in CuGaSe2 thin-film solar cells , 2014 .

[2]  Sputtered In2O3 and ITO thin films containing zirconium , 2009 .

[3]  S. Nishiwaki,et al.  Review of progress toward 20% efficiency flexible CIGS solar cells and manufacturing issues of solar modules , 2012, 2012 IEEE 38th Photovoltaic Specialists Conference (PVSC) PART 2.

[4]  S. Popović,et al.  Crystal data for AgGaxIn1−xSe2 and CuGaxIn1−xSe2 , 1980 .

[5]  S. Nishiwaki,et al.  Characterization of the Cu(In,Ga)Se2/Mo interface in CIGS solar cells , 2001 .

[6]  M. Konagai,et al.  Electrical and Structural Characterizations of Cu(InGa)Se2 Thin Films Using Electrochemical Capacitance–Voltage Method and Focused-Ion Beam Process , 2000 .

[7]  Yun Sun,et al.  Effects of substrate temperature on the structural and electrical properties of Cu(In,Ga)Se2 thin films , 2009 .

[8]  T. Nakada,et al.  Direct evidence of Cd diffusion into Cu(In, Ga)Se2 thin films during chemical-bath deposition process of CdS films , 1999 .

[9]  G. Gordillo,et al.  Study of electrical properties of CIGS thin films prepared by multistage processes , 2010 .

[10]  M. Powalla,et al.  Approaches to flexible CIGS thin-film solar cells , 2005 .

[11]  Joshua M. Pearce,et al.  A Review of Solar Photovoltaic Levelized Cost of Electricity , 2011 .

[12]  A. Rockett,et al.  Near-surface defect distributions in Cu(In,Ga)Se2 , 2003 .

[13]  H. Schock,et al.  The role of structural properties and defects for the performance of Cu-chalcopyrite-based thin-film solar cells , 2001 .

[14]  S. Asher,et al.  High efficiency graded bandgap thin-film polycrystalline Cu(In,Ga) Se2-based solar cells , 1996 .