A review on advances of torrefaction technologies for biomass processing

Torrefaction is a thermochemical pretreatment process at 200–300 °C in an inert condition which transforms biomass into a relatively superior handling, milling, co-firing and clean renewable energy into solid biofuel. This increases the energy density, water resistance and grindability of biomass and makes it safe from biological degradation which ultimately makes easy and economical on transportation and storing of the torrefied products. Torrefied biomass is considered as improved version than the current wood pellet products and an environmentally friendly future alternative for coal. Torrefaction carries devolatilisation, depolymerization and carbonization of lignocellulose components and generates a brown to black solid biomass as a productive output with water, organics, lipids, alkalis, SiO2, CO2, CO and CH4. During this process, 70 % of the mass is retained as a solid product, and retains 90 % of the initial energy content. The torrefied product is then shaped into pellets or briquettes that pack much more energy density than regular wood pellets. These properties minimize on the difference in combustion characteristics between biomass and coal that bring a huge possibility of direct firing of biomass in an existing coal-fired plant. Researchers are trying to find a solution to fire/co-fire torrefied biomass instead of coal in an existing coal-fired based boiler with minimum modifications and expenditures. Currently available torrefied technologies are basically designed and tested for woody biomass so further research is required to address on utilization of the agricultural biomass with technically and economically viable. This review covers the torrefaction technologies, its’ applications, current status and future recommendations for further study.

[1]  Farid Nasir Ani,et al.  Microwave induced pyrolysis of oil palm biomass. , 2011, Bioresource technology.

[2]  F. Rosillo-calle,et al.  The biomass assessment handbook : bioenergy for a sustainable environment , 2008 .

[3]  M. Dietenberger,et al.  Wood Products: Thermal Degradation and Fire , 2001 .

[4]  Jian Deng,et al.  Pretreatment of agricultural residues for co-gasification via torrefaction , 2009 .

[5]  C. Wyman,et al.  Features of promising technologies for pretreatment of lignocellulosic biomass. , 2005, Bioresource technology.

[6]  W. A. Amos,et al.  Report on Biomass Drying Technology , 1999 .

[7]  P. Perré,et al.  Alterations in energy properties of eucalyptus wood and bark subjected to torrefaction: the potential of mass loss as a synthetic indicator. , 2010, Bioresource technology.

[8]  J. Pérez,et al.  Biodegradation and biological treatments of cellulose, hemicellulose and lignin: an overview , 2002, International microbiology : the official journal of the Spanish Society for Microbiology.

[9]  J. J. Chew,et al.  Recent advances in biomass pretreatment – Torrefaction fundamentals and technology , 2011 .

[10]  P. Perré,et al.  Characterisation of the torrefaction of beech wood using NIRS: Combined effects of temperature and duration , 2011 .

[11]  A. Nordin,et al.  Torrefaction and Gasification of Hydrolysis Residue , 2008 .

[12]  R.W.R. Zwart,et al.  The Impact of Biomass Pretreatment on the Feasibility of Overseas Biomass Conversion to Fischer-Tropsch Products , 2006 .

[13]  B. Jenkins,et al.  Combustion properties of biomass , 1998 .

[14]  Jenny M. Jones,et al.  Torrefaction of reed canary grass, wheat straw and willow to enhance solid fuel qualities and combustion properties , 2008 .

[15]  Emmanuel G. Koukios,et al.  Progress in Thermochemical, Solid-State Refining of Biofuels — From Research to Commercialization , 1993 .

[16]  Ky Dangtran,et al.  A Comparison of Fluid Bed and Multiple Hearth Biosolids Incineration , 2000 .

[17]  René Guyonnet,et al.  Energy requirement for fine grinding of torrefied wood , 2010 .

[18]  S. Rao,et al.  Fluidized bed drying of solids , 1990 .

[19]  J. McMullen,et al.  Storage and Handling Characteristics of Pellets from Poultry Litter , 2005 .

[21]  Gui-jun Wang,et al.  Pretreatment of biomass by torrefaction , 2011 .

[22]  Pak Sui Lam,et al.  Colorimetry Applied to Steam-Treated Biomass and Pellets Made from Western Douglas Fir (Pseudotsuga menziesii L.) , 2012 .

[23]  S. Sadaka,et al.  Improvements of biomass physical and thermochemical characteristics via torrefaction process , 2009 .

[24]  Wlodzimierz Blasiak,et al.  Pyrolysis characteristics and global kinetics of coconut and cashew nut shells , 2006 .

[25]  D. Ciolkosz,et al.  A review of torrefaction for bioenergy feedstock production , 2011 .

[26]  A. Mujumdar,et al.  Advanced drying technologies , 2001 .

[27]  R. Guyonnet,et al.  Thermal treatment of wood: analysis of the obtained product , 1989, Wood Science and Technology.

[28]  Toyoji Kakuchi,et al.  Rapid pyrolysis of wood block by microwave heating , 2004 .

[29]  Peter McKendry,et al.  Energy production from biomass (Part 1): Overview of biomass. , 2002, Bioresource technology.

[30]  D. T. Liang,et al.  In-Depth Investigation of Biomass Pyrolysis Based on Three Major Components: Hemicellulose, Cellulose and Lignin , 2006 .

[31]  J. R. Hess,et al.  REVIEW: A review on biomass torrefaction process and product properties for energy applications , 2011 .

[32]  Wei-Hsin Chen,et al.  An evaluation on improvement of pulverized biomass property for solid fuel through torrefaction , 2011 .

[33]  Kj Krzysztof Ptasinski,et al.  Thermodynamics of gas-char reactions: first and second law analysis , 2003 .

[34]  A. Loupy Microwaves in organic synthesis , 2002 .

[35]  Changkook Ryu,et al.  Effect of process parameters on pelletisation of herbaceous crops , 2009 .

[36]  A. S. Mujumdar,et al.  Study of Residence Time Distribution in a Pilot-Scale Screw Conveyor Dryer , 2007 .

[37]  P.C.A. Bergman,et al.  Torrefaction for biomass co-firing in existing coal-fired power stations BIOCOAL , 2005 .

[38]  Kj Krzysztof Ptasinski,et al.  Torrefaction for entrained-flow gasification of biomass , 2004 .

[39]  C. Leonelli,et al.  Microwave and ultrasonic processing: Now a realistic option for industry , 2010 .

[40]  I. Obernberger,et al.  Physical characterisation and chemical composition of densified biomass fuels with regard to their combustion behaviour , 2004 .

[41]  P. Flynn,et al.  Biomass power cost and optimum plant size in western Canada , 2003 .

[42]  F. Shafizadeh,et al.  Thermal deterioration of wood. , 1977 .

[43]  Multiple steady states of a crossflow moving bed reactor: theory and experiment , 1988 .

[44]  R. .. Morey,et al.  Factors affecting strength and durability of densified biomass products. , 2009 .

[45]  Wen-Jhy Lee,et al.  Thermal pretreatment of wood (Lauan) block by torrefaction and its influence on the properties of the biomass , 2011 .

[46]  I. Turner,et al.  The Choice of a Low Temperature Pyrolysis Model at the Microscopic Level for use in a Macroscopic Formulation , 2005 .

[47]  K.H.J. Buschow,et al.  Encyclopedia of Materials: Science and Technology , 2004 .

[48]  Kj Krzysztof Ptasinski,et al.  More efficient biomass gasification via torrefaction , 2006 .

[49]  T. Jeffries Biodegradation of lignin and hemicelluloses , 1994 .

[50]  S. Sokhansanj,et al.  Biomass Torrefaction Process Review and Moving Bed Torrefaction System Model Development , 2010 .

[51]  X. Bi,et al.  Rate and peak concentrations of off-gas emissions in stored wood pellets--sensitivities to temperature, relative humidity, and headspace volume. , 2009, The Annals of occupational hygiene.

[52]  P. Perré,et al.  Choix d'un modèle de pyrolyse ménagée du bois à l'échelle de la microparticule en vue de la modélisation macroscopique , 2006 .

[53]  Arun S. Mujumdar,et al.  An Experimental Study of the Thermal Performance of a Screw Conveyor Dryer , 2006 .

[54]  Jiří Martinec,et al.  Pretreatment and feeding of biomass for pressurized entrained flow gasification , 2009 .

[55]  Zulfan Adi Putra,et al.  Techno‐economic assessment of biomass pre‐conversion processes as a part of biomass‐to‐liquids line‐up , 2009 .

[56]  Barry Turner,et al.  United Nations (UN) , 2009 .

[57]  Kj Krzysztof Ptasinski,et al.  Torrefaction of wood: Part 1. Weight loss kinetics , 2006 .

[58]  S. Pipatmanomai,et al.  Overview and Experiences of Biomass Fluidized Bed Gasification in Thailand , 2011 .

[59]  Zhang Dong-li,et al.  The Study on Performance of Twin Screw Conveyer , 1996 .

[60]  J. J. Pis,et al.  Influence of torrefaction on the grindability and reactivity of woody biomass , 2008 .

[61]  Angel Díaz-Ortiz,et al.  Microwaves in organic synthesis. Thermal and non-thermal microwave effects. , 2005, Chemical Society reviews.

[62]  I. S. Goldstein Wood Technology: Chemical Aspects , 1977 .

[63]  Linghong Zhang,et al.  Overview of recent advances in thermo-chemical conversion of biomass. , 2010 .

[64]  T. G. Bridgeman,et al.  An investigation of the grindability of two torrefied energy crops , 2010 .

[65]  S. Mani,et al.  Impact of torrefaction on the grindability and fuel characteristics of forest biomass. , 2011, Bioresource technology.

[66]  Carlos Alberto Luengo,et al.  Wood briquette torrefaction , 2005 .

[67]  André Faaij,et al.  Pre-treatment technologies, and their effect on international bioenergy supply chain logistics. Techno-economic evaluation of torrefaction, fast pyrolysis and pelletisation , 2008 .

[68]  Victor R. Vasquez,et al.  Thermal pretreatment of lignocellulosic biomass , 2009 .

[69]  Victor R Vasquez,et al.  Effect of thermal pretreatment on equilibrium moisture content of lignocellulosic biomass. , 2011, Bioresource technology.

[70]  H. Gerhauser,et al.  BO2-technology for biomass upgrading into solid fuel - pilot-scale testing and market implementation , 2008 .

[71]  Animesh Dutta,et al.  Torrefaction of Agriculture Residue To Enhance Combustible Properties , 2010 .

[72]  Kj Krzysztof Ptasinski,et al.  Biomass upgrading by torrefaction for the production of biofuels: A review , 2011 .

[73]  S. Salvador,et al.  Impact of torrefaction on syngas production from wood , 2009 .

[74]  Po Chih Kuo,et al.  Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as , 2011 .