论文信息 - Regioselective synthesis of linalyl compounds via addition reaction of geranyl bromide and tin with carbonyl compounds - 字舞流文

Regioselective synthesis of linalyl compounds via addition reaction of geranyl bromide and tin with carbonyl compounds

Linalyl alkyl or aryl carbinols were regioselectively synthesized by the reaction of geranyl bromide and powdered tin with aldehydes and ketones.

Jingyao Zhou | Shi-hui Wu | Zhao-Gen Chen | G. Lu

[1] Zhengming Li,et al. The Wittig sigmatropic rearrangement in a conjugated diene system I , 1990 .

[2] Xiang Gao,et al. Reaction of Propargyl Bromide with Aldehydes in the Presence of Metallic Tin. Synthesis of Homopropargylalcohols and Homoallenylalcohols , 1990 .

[3] Y. Masuyama,et al. Charge reversal of electrophilic .pi.-allylpalladium intermediates: carbonyl allylation by allylic acetates with tetrakis(triphenylphosphine)palladium-zinc , 1987 .

[4] Y. Naruta,et al. Erythro-selective addition of crotyltrialkyltins to aldehydes regardless of the geometry of the crotyl unit. Stereoselection independent of the stereochemistry of precursors , 1980 .

[5] M. Bennett,et al. Allylation of Quinones with Allyltin Reagents , 1980 .

[6] R. Cookson,et al. Reactions of a ‘myrcene–magnesium’ complex with aldehydes, ketones, epoxides, carbon dioxide, and acetonitrile , 1976 .

[7] K. Mori. Simple synthesis of sex pheromones of codling moth and red bollworm moth by the coupling of Grignard reagents with allylic halides , 1974 .

[8] W. G. Brown,et al. Reduction of Organic Compounds by Lithium Aluminum Hydride. II. Carboxylic Acids , 1947 .