Crystal structure, phase transitions, anomalous thermal and elastic properties of bis (butylammonium) zirconium bis(nitrilotriacetate) dihydrate and bis(butylammonium) hafnium bis(nitrilotriacetate) dihydrate, [NH3(CH2)3CH3]2X[N(CH2COO)3]2 . 2 H2O, (X=Zr, Hf)