Modeling agricultural air quality: Current status, major challenges, and outlook

Agricultural air quality is an important emerging area of atmospheric sciences that represents significant challenges in many aspects of research including measurements, modeling, regulations, emission control, and operation managements. This work presents a review of current status, major challenges, and future research needs and opportunities of several important aspects of agricultural air quality modeling including chemical species, concentration and deposition measurements for model verification, emission inventories, major physical and chemical processes, model application and evaluation, and policy implications.

[1]  Mark A. Sutton,et al.  Development of resistance models to describe measurements of bi-directional ammonia surface-atmosphere exchange , 1998 .

[2]  K. W. Van der Hoek Estimating ammonia emission factors in Europe: Summary of the work of the UNECE ammonia expert panel , 1998 .

[3]  P. Adams,et al.  A temporally and spatially resolved ammonia emission inventory for dairy cows in the United States , 2004 .

[4]  P. Warneck Chemistry of the natural atmosphere , 1999 .

[5]  W. Asman Parameterization of below-cloud scavenging of highly soluble gases under convective conditions , 1995 .

[6]  Cliff I. Davidson,et al.  An ammonia emission inventory for fertilizer application in the United States , 2003 .

[7]  J. Seinfeld,et al.  Photooxidation of dimethyl sulfide and dimethyl disulfide. I: Mechanism development , 1990 .

[8]  Nicholas J. Hutchings,et al.  A detailed ammonia emission inventory for Denmark , 2001 .

[9]  Mark A. Sutton,et al.  A multi-layer model to describe the atmospheric transport and deposition of ammonia in Great Britain , 1998 .

[10]  W. K. Hicks,et al.  Atmospheric nitrogen deposition in world biodiversity hotspots: the need for a greater global perspective in assessing N deposition impacts , 2006 .

[11]  A. Mosier,et al.  Contributions of agroecosystems to global climate change , 1993 .

[12]  J. Vose,et al.  Nitrogen trace gas emissions from a riparian ecosystem in southern Appalachia. , 2002, Chemosphere.

[13]  François Dulac,et al.  Wet deposition in a global size-dependent aerosol transport model: 1. Comparison of a 1 year 210Pb simulation with ground measurements , 1998 .

[14]  V. Varel,et al.  In vitro study of the biochemical origin and production limits of odorous compounds in cattle feedlots. , 2001, Journal of animal science.

[15]  S. Twomey Nucleation of Ammonium Chloride Particles from Hydrogen Chloride and Ammonia in Air , 1959 .

[16]  M. Fraser Atmospheric Pollution: History, Science and Regulation , 2003 .

[17]  F. Fehsenfeld,et al.  Natural Vegetation as a Source or Sink for Atmospheric Ammonia: A Case Study , 1992, Science.

[18]  J. Seinfeld Atmospheric Chemistry and Physics of Air Pollution , 1986 .

[19]  T. Meyers,et al.  Measurement of bi-directional ammonia fluxes over soybean using the modified Bowen-ratio technique , 2006 .

[20]  T. Graedel,et al.  Atmospheric Emissions Inventories: Status and Prospects , 1995 .

[21]  Tom Misselbrook,et al.  A new inventory of ammonia emissions from Irish agriculture , 2003 .

[22]  J. Duyzer,et al.  Measurement of the dry deposition flux of NH3 on to coniferous forest. , 1992, Environmental pollution.

[23]  Jan Willem Erisman,et al.  Atmospheric deposition of ammonia to semi-natural vegetation in the Netherlands: Methods for mapping and evaluation , 1998 .

[24]  G. Farquhar,et al.  On the Gaseous Exchange of Ammonia between Leaves and the Environment: Determination of the Ammonia Compensation Point. , 1980, Plant physiology.

[25]  M. Schulz,et al.  The global distribution of acidifying wet deposition. , 2002, Environmental Science and Technology.

[26]  G. Hidy,et al.  Effects of Changes in Sulfate, Ammonia, and Nitric Acid on Particulate Nitrate Concentrations in the Southeastern United States , 2003, Journal of the Air & Waste Management Association.

[27]  R. Atkinson Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds , 1989 .

[28]  Agricultural Ecosystem Effects on Trace Gases and Global Climate Change , 1993 .

[29]  J. Cape,et al.  Atmospheric nitrogen compounds-issues related to agricultural systems. , 2003, Environment international.

[30]  Gregory D. Jennings,et al.  Emerging national research needs for agricultural air quality , 2006 .

[31]  Jianlin Hu,et al.  Modeling atmospheric transport and fate of ammonia in North Carolina—Part II: Effect of ammonia emissions on fine particulate matter formation , 2008 .

[32]  R. Cicerone,et al.  The atmospheric chemistry of hydrogen cyanide (HCN) , 1983 .

[33]  Jan Willem Erisman,et al.  Ammonia exchange over coniferous forest , 1998 .

[34]  R. Draxler,et al.  Estimating PM10 air concentrations from dust storms in Iraq, Kuwait and Saudi Arabia , 2001 .

[35]  B. Loubet,et al.  The mass budget of atmospheric ammonia in woodland within 1 km of livestock buildings , 1998 .

[36]  K. Yagi,et al.  Evaluation of emission factors for indirect N2O emission due to nitrogen leaching in agro‐ecosystems , 2005 .

[37]  D. Simpson,et al.  Deposition and emissions of reactive nitrogen over European forests: A modelling study , 2006 .

[38]  V. R. Phillips,et al.  A UK inventory of nitrous oxide emissions from farmed livestock , 1999 .

[39]  B. Finlayson‐Pitts,et al.  Atmospheric chemistry : fundamentals and experimental techniques , 1986 .

[40]  M. T. Emerson,et al.  Proton‐Transfer Studies by Nuclear Magnetic Resonance. I. Diffusion Control in the Reaction of Ammonium Ion in Aqueous Acid , 1960 .

[41]  Y. Balkanski,et al.  Wet deposition in a global size-dependent aerosol transport model. 2. Influence of the scavenging scheme on 210Pb vertical profiles, surface concentrations, and deposition , 1998 .

[42]  W. Carter,et al.  Atmospheric reactions of N-nitrosodimethylamine and dimethylnitramine. , 1984, Environmental science & technology.

[43]  Mark A. Sutton,et al.  A two‐layer canopy compensation point model for describing bi‐directional biosphere‐atmosphere exchange of ammonia , 2001 .

[44]  M. Jacobson Fundamentals of Atmospheric Modeling: Contents , 1998 .

[45]  H. V. Jaarsveld,et al.  A variable-resolution transport model applied for NHχ in Europe , 1992 .

[46]  J. Crowley,et al.  Sequential Two (Blue) Photon Absorption by NO2 in the Presence of H2 as a Source of OH in Pulsed Photolysis Kinetic Studies: Rate Constants for Reaction of OH with CH3NH2, (CH3)2NH, (CH3)3N, and C2H5NH2 at 295 K , 1998 .

[47]  John H. Seinfeld,et al.  Global concentrations of tropospheric sulfate, nitrate, and ammonium aerosol simulated in a general circulation model , 1999 .

[48]  Carsten Ambelas Skjøth,et al.  Implementing a dynamical ammonia emission parameterization in the large‐scale air pollution model ACDEP , 2004 .

[49]  W. Parton,et al.  Characteristics of Ammonia Volatilization from Spring Wheat , 1989 .

[50]  W. Collins,et al.  Present and future acid deposition to ecosystems: The effect of climate change , 2006 .

[51]  P. Mcmurry,et al.  Measurements of new particle formation and ultrafine particle growth rates at a clean continental site , 1997 .

[52]  Srinath Krishnan,et al.  Modeling atmospheric transport and fate of ammonia in North Carolina—Part I: Evaluation of meteorological and chemical predictions , 2008 .

[53]  A. J. Janssen,et al.  A long-range transport model for ammonia and ammonium for Europe , 1987 .

[54]  J. Seinfeld,et al.  A comparative review of inorganic aerosol thermodynamic equilibrium modules: similarities, differences, and their likely causes , 2000 .

[55]  Cliff I. Davidson,et al.  A process-based model of ammonia emissions from dairy cows: improved temporal and spatial resolution , 2004 .

[56]  Dimitrios V. Vayenas,et al.  Simulation of the thermodynamics and removal processes in the sulfate-ammonia-nitric acid system during winter: Implications for PM2.5 control strategies , 2005 .

[57]  H. ApSimon,et al.  Cost-effective strategies for the abatement of ammonia emissions from European agriculture , 1998 .

[58]  Robin L. Dennis,et al.  Seasonal NH3 emission estimates for the eastern United States , 2003 .

[59]  W. Palm,et al.  Rate constants for the gas-phase reaction of OHwith amines:tert-Butyl amine, 2,2,2-Trifluoroethyl amine, and 1,4-Diazabicyclo[2.2.2] octane , 1996 .

[60]  W. Palm,et al.  FIRST RATE CONSTANTS FOR REACTIONS OF OH RADICALS WITH AMIDES , 1997 .

[61]  S. Pandis,et al.  An Analysis of Four Models Predicting the Partitioning of Semivolatile Inorganic Aerosol Components , 1999 .

[62]  W. Slinn,et al.  Predictions for particle deposition on natural waters , 1980 .

[63]  Mark A. Sutton,et al.  Dry deposition of reduced nitrogen , 1994 .

[64]  J. J. Renard,et al.  Fate of ammonia in the atmosphere--a review for applicability to hazardous releases. , 2004, Journal of hazardous materials.

[65]  A. Nenes,et al.  Continued development and testing of a new thermodynamic aerosol module for urban and regional air quality models , 1999 .

[66]  Christian Seigneur,et al.  A comprehensive performance evaluation of MM5-CMAQ for the Summer 1999 Southern Oxidants Study episode—Part II: Gas and aerosol predictions , 2006 .

[67]  M. Canagaratna,et al.  Structure and Bonding of the Sulfamic Acid Zwitterion: Microwave Spectrum of +H3N−SO3- , 1996 .

[68]  P. Crutzen,et al.  A three-dimensional model of the global ammonia cycle , 1994 .

[69]  Theo Demmers,et al.  Ammonia emission factors for UK agriculture. , 2000 .

[70]  Robin L. Dennis,et al.  NARSTO critical review of photochemical models and modeling , 2000 .

[71]  J. Seinfeld,et al.  Simulation of Aerosol Dynamics: A Comparative Review of Algorithms Used in Air Quality Models , 1999 .

[72]  R. A. Cox,et al.  Evaluated Kinetic, Photochemical and Heterogeneous Data for Atmospheric Chemistry: Supplement V. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry , 1997 .

[73]  J. Jonson,et al.  EMEP Eulerian model for atmospheric transport and deposition of nitrogen species over Europe , 1998 .

[74]  M. Sofiev,et al.  The long-range transport of ammonia and ammonium in the Northern Hemisphere , 1998 .

[75]  R. Harley,et al.  Mathematical modeling and control of the dry deposition flux of nitrogen-containing air pollutants , 1993 .

[76]  A study of atmospheric ammonia by means of modeling analysis in the Kanto region of Japan , 2005 .

[77]  F. Binkowski,et al.  Models-3 community multiscale air quality (cmaq) model aerosol component , 2003 .

[78]  D. Hegg,et al.  A preliminary study of the effect of ammonia on particle nucleation in the marine boundary layer , 1995 .

[79]  Robert G. Flocchini,et al.  Characterization and quantification of odorous and non-odorous volatile organic compounds near a commercial dairy in California , 2003 .

[80]  David Fowler,et al.  Atmospheric nitrogen compounds II: emissions, transport, transformation, deposition and assessment , 2001 .

[81]  W. Robarge,et al.  Inorganic PM2.5 at a U.S. agricultural site. , 2006, Environmental pollution.

[82]  C. Pilinis,et al.  An estimation of the spatial distribution of agricultural ammonia emissions in the Greater Athens Area. , 2004, The Science of the total environment.

[83]  J. Houghton,et al.  Climate change 2001 : the scientific basis , 2001 .

[84]  Viney P. Aneja,et al.  Ammonia flux and dry deposition velocity from near-surface concentration gradient measurements over a grass surface in North Carolina , 2004 .

[85]  Wayne P. Robarge,et al.  Ambient ammonia and ammonium aerosol across a region of variable ammonia emission density , 2004 .

[86]  L. Lekkerkerk Implications of Dutch ammonia policy on the livestock sector , 1998 .

[87]  J. D. Whyatt,et al.  Multi-pollutant modelling and the critical loads approach for nitrogen , 1998 .

[88]  Wayne P. Robarge,et al.  Atmospheric concentrations of ammonia and ammonium aerosols in eastern north Carolina. , 2000 .

[89]  J. Seinfeld,et al.  Development and application of the Model of Aerosol Dynamics, Reaction, Ionization, and Dissolution (MADRID) , 2004 .

[90]  Mark Z. Jacobson,et al.  Fundamentals of atmospheric modeling , 1998 .

[91]  Jonathan O. Allen,et al.  Evolution of nitrogen species air pollutants along trajectories crossing the Los Angeles area. , 2002, Environmental science & technology.

[92]  Roger Atkinson,et al.  Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III - gas phase reactions of inorganic halogens , 2006 .

[93]  B. Finlayson‐Pitts,et al.  Atmospheric Chemistry , 2010, Proceedings of the National Academy of Sciences.

[94]  Carolien Kroeze,et al.  Ammonia abatement and its impact on emissions of nitrous oxide and methane - Part 2: application for Europe , 2001 .

[95]  B. Mulliken,et al.  THE REACTIONS OF SULFUR DIOXIDE WITH EXCESS AMMONIA , 1980 .

[96]  Mark A. Sutton,et al.  The exchange of atmospheric ammonia with vegetated surfaces. II: Fertilized vegetation , 1993 .

[97]  Donald R. McCubbin,et al.  Livestock ammonia management and particulate-related health benefits. , 2002, Environmental science & technology.

[98]  Prakash Karamchandani,et al.  Plume-in-grid modeling for particulate matter , 2006 .

[99]  Jan K. Schjoerring,et al.  Physiological parameters controlling plant-atmosphere ammonia exchange , 1998 .

[100]  Hal Westberg,et al.  Identification and quantification of volatile organic compounds from a dairy , 2003 .

[101]  David T. Allen,et al.  Ammonia emissions, concentrations and implications for particulate matter formation in Houston, TX , 2006 .

[102]  M. Wesely Parameterization of surface resistances to gaseous dry deposition in regional-scale numerical models , 1989 .

[103]  R. Harrison,et al.  Ammonia surface-exchange above an agricultural field in Southeast England , 1996 .

[104]  Richard D. Alexander,et al.  A Comparative Review , 1968 .

[105]  R. Zellner,et al.  B. Finlayson‐Pitts, J. N. Pitts, Jr.: Atmospheric Chemistry: Fundamentals and Experimental Techniques, J. Wiley and Sons, New York, Chichester, Brisbane, Toronto and Singapore 1986. 1098 Seiten, Preis: £ 57.45. , 1986 .

[106]  Viney P. Aneja,et al.  Evaluation and improvement of ammonia emissions inventories , 2003 .

[107]  Daniel Grosjean,et al.  Photooxidation of dimethyl sulfide and dimethyl disulfide. II: Mechanism evaluation , 1990 .

[108]  Nelson L. Seaman,et al.  Meteorological modeling for air-quality assessments , 2000 .

[109]  B. F. Pain,et al.  An inventory of nitrous oxide emissions from agriculture in the UK using the IPCC methodology: emission estimate, uncertainty and sensitivity analysis , 2001 .

[110]  R. B. Jackson,et al.  Global biodiversity scenarios for the year 2100. , 2000, Science.

[111]  Julian Heicklen,et al.  Kinetics of particle growth. II. Kinetics of the reaction of ammonia with hydrogen chloride and the growth of pariculate ammonium chloride , 1973 .

[112]  K. Bower,et al.  A modelling study of the interaction of ammonia with cloud , 1998 .

[113]  D. Bouldin,et al.  Fluxes of Ammonia Over an Alfalfa Field1 , 1985 .

[114]  W. Robarge,et al.  Atmospheric concentrations of ammonia and ammonium at an agricultural site in the southeast United States , 2002 .

[115]  J. Heicklen,et al.  Thermodynamics of the reactions (NH3)n.SO2(s) .far. nNH3(g) + SO2(g) , 1974 .

[116]  J. Steinbacher,et al.  Ammonia exchange between the atmosphere and the surface waters at two locations in the Chesapeake Bay. , 2001, Environmental science & technology.

[117]  Mark Z. Jacobson,et al.  Fundamentals of Atmospheric Modeling: Cloud thermodynamics and dynamics , 2005 .

[118]  Gregory J. McRae,et al.  Mathematical modeling of the formation and transport of ammonium nitrate aerosol , 1983 .

[119]  P. Brimblecombe,et al.  Solubility of ammonia in pure aqueous and multicomponent solutions , 1989 .

[120]  Christian Seigneur,et al.  A comprehensive performance evaluation of MM5-CMAQ for the summer 1999 southern oxidants study episode, Part III: Diagnostic and mechanistic evaluations , 2006 .

[121]  J. Gullberg,et al.  Airborne chemical compounds on dairy farms. , 2001, Journal of environmental monitoring : JEM.

[122]  R. Mathur,et al.  Seasonal and annual modeling of reduced nitrogen compounds over the eastern United States: Emissions, ambient levels, and deposition amounts , 2003 .

[123]  B. F. Pain,et al.  A new inventory for ammonia emissions from U.K. agriculture , 1998 .