Pinch and exergy analysis of lignocellulosic ethanol, biomethane, heat and power production from straw

Abstract In this work a complex process for production of bioethanol, biomethane, heat and power from the wheat straw is introduced and analyzed with regard to pinch and exergy analysis. The pinch analysis is focused on the bioethanol production where a well-designed heat exchanger network increases heat integration up to 45 MW. To obtain optimal total site external hot and cold utilities demands at different temperature levels as well as maximum power generated by steam turbine, an integrated steam cycle composite curve has been added to the grand composite curve of the “background process”. The exergy analysis takes into account three production sections separately and exergy efficiencies are calculated to find the quantity of irreversibilities the bioethanol processes. The results from exergy analysis show that the bioethanol process has the highest exergy efficiency because of usage of stillage for other processes in which a considerable part of exergy entering is converted into irreversibility because of heat losses and non reacting unknown material produced as material losses.

[1]  Stanislav Boldyryev,et al.  Process integration of sodium hypophosphite production , 2010 .

[2]  A. Buswell,et al.  The mechanism of the methane fermentation. , 1952, Journal of the American Chemical Society.

[3]  H. Kooi,et al.  Exergy analysis with a flowsheeting simulator—I. Theory; calculating exergies of material streams , 1996 .

[4]  François Maréchal,et al.  Targeting the optimal integration of steam networks: Mathematical tools and methodology , 1999 .

[5]  Anton Friedl,et al.  Modeling and simulation of coupled ethanol and biogas production , 2010 .

[6]  Ignacio E. Grossmann,et al.  Optimal synthesis of heat exchanger networks involving isothermal process streams , 2008, Comput. Chem. Eng..

[7]  Jan Szargut,et al.  Exergy Analysis of Thermal, Chemical, and Metallurgical Processes , 1988 .

[8]  J. Seabra,et al.  Green house gases emissions in the production and use of ethanol from sugarcane in Brazil: the 2005/2006 averages and a prediction for 2020. , 2008 .

[9]  Anselm Eisentraut,et al.  Sustainable Production of Second-Generation Biofuels: Potential and Perspectives in Major Economies and Developing Countries , 2010 .

[10]  A. Friedl,et al.  Prozesssimulation der Produktion von Ethanol und Methan aus lignocellulosehaltigen Rohstoffen , 2011 .

[11]  Mahmoud M. El-Halwagi,et al.  Exergy analysis and process integration of bioethanol production from acid pre-treated biomass: Comparison of SHF, SSF and SSCF pathways , 2011 .

[12]  Masaru Nakaiwa,et al.  Pinch analysis for bioethanol production process from lignocellulosic biomass , 2011 .

[13]  Anton Friedl,et al.  Analysis and decrease of the energy demand of bioethanol-production by process integration , 2007 .

[14]  David M. Mousdale,et al.  Introduction to Biofuels , 2010 .

[15]  Kj Krzysztof Ptasinski,et al.  Exergetic evaluation of biomass gasification , 2007 .

[16]  Norbert Asprion,et al.  Work Flow in Process Development for Energy Efficient Processes , 2010 .

[17]  Robin Smith,et al.  Chemical Process: Design and Integration , 2005 .

[18]  Ian C. Kemp,et al.  Pinch Analysis and Process Integration: A User Guide on Process Integration for the Efficient Use of Energy , 2007 .

[19]  Anton Friedl,et al.  Effect of process integration on the exergy balance of a two-stage process for fermentative hydrogen production , 2010 .

[20]  Anton Friedl,et al.  Perspectives for the production of bioethanol from wood and straw in Austria: technical, economic, and ecological aspects , 2012, Clean Technologies and Environmental Policy.

[21]  Reinerus Louwrentius Cornelissen,et al.  Thermodynamics and sustainable development; the use of exergy analysis and the reduction of irreversibility , 1997 .

[22]  Andrea Toffolo,et al.  Synthesis and parameter optimization of a combined sugar and ethanol production process integrated w , 2011 .

[23]  Bodo Linnhoff,et al.  A User guide on process integration for the efficient use of energy , 1994 .

[24]  Per Sassner Lignocellulosic Ethanol Production Based on Steam Pretreatment and SSF: Process Development through Experiments and Simulations , 2007 .

[25]  Anton Friedl,et al.  Application of exergy balances for evaluation of process configurations for biological hydrogen production , 2010 .