Sustainable and recyclable palladium nanoparticles–catalyzed reduction of nitroaromatics in water/glycerol at room temperature

Palladium nanoparticles with unique catalytic activity and high stability are synthesized. These nanoparticles exhibit excellent catalytic reduction activity for nitroaromatics in green solvents in the presence of H2 at ambient pressure and temperature. The prominent advantages of this nanotechnology include low consumption of catalyst, excellent chemoselectivity, high reusability of the catalyst, and environmentally green solvents.

[1]  Chao Ma,et al.  Phosphorus-rich network polymer supported ruthenium nanoparticles for nitroarene reduction , 2019, Materials Letters.

[2]  Xiaotong Liu,et al.  Ultrafine Pd Nanoparticles Anchored on Nitrogen-Doping Carbon for Boosting Catalytic Transfer Hydrogenation of Nitroarenes , 2018, ACS omega.

[3]  Bin Sun,et al.  Selective hydrogenation of aromatic compounds using modified iridium nanoparticles , 2018 .

[4]  R. Kempe,et al.  Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes , 2018, Scientific Reports.

[5]  R. Bal,et al.  Surfactant‐Induced Preparation of Highly Dispersed Ni‐Nanoparticles Supported on Nanocrystalline ZrO2 for Chemoselective Reduction of Nitroarenes , 2018 .

[6]  Lei Wu,et al.  Enantioselective hydrogenation of N-heteroaromatics catalyzed by chiral diphosphine modified binaphthyl palladium nanoparticles , 2017 .

[7]  Kondo‐François Aguey‐Zinsou,et al.  Synthesis of LiAlH4 Nanoparticles Leading to a Single Hydrogen Release Step upon Ti Coating , 2017 .

[8]  F. Gallou,et al.  Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature. , 2016, Angewandte Chemie.

[9]  G. Sekar,et al.  Stable and reusable platinum nanocatalyst: an efficient chemoselective reduction of nitroarenes in water , 2016 .

[10]  Wen‐Chang Chen,et al.  Syntheses of 4-Indolylquinoline Derivatives via Reductive Cyclization of Indolylnitrochalcone Derivatives by Fe/HCl , 2015, Molecules.

[11]  Andrew G. Leach,et al.  Rationally designing safer anilines: the challenging case of 4-aminobiphenyls. , 2012, Journal of medicinal chemistry.

[12]  A. Wolfson,et al.  Transfer Hydrogenations of Nitrobenzene Using Glycerol as Solvent and Hydrogen Donor , 2011 .

[13]  Jun Jin,et al.  Pd immobilized on amine-functionalized magnetite nanoparticles: a novel and highly active catalyst for hydrogenation and Heck reactions , 2011 .

[14]  Kangnian Fan,et al.  Highly Chemo‐ and Regioselective Transfer Reduction of Aromatic Nitro Compounds using Ammonium Formate Catalyzed by Supported Gold Nanoparticles , 2011 .

[15]  R. Boukherroub,et al.  Palladium‐catalyzed reduction of nitroaromatic compounds to the corresponding anilines , 2010 .

[16]  H. Blaser,et al.  Selective Catalytic Hydrogenation of Functionalized Nitroarenes: An Update , 2009 .

[17]  Yanqing Peng,et al.  Efficient and mild room temperature reduction of benzophenones under ultrasound irradiation. , 2005, Ultrasonics sonochemistry.

[18]  R. Jayaram,et al.  Liquid phase catalytic transfer hydrogenation of aromatic nitro compounds on perovskites prepared by microwave irradiation , 2003 .

[19]  N. Ono.  The nitro group in organic synthesis , 2001 .

[20]  R. Wolski,et al.  Catalytic hydrogen transfer over magnesia. XIV. Cyclohexene as hydrogen donor , 2000 .

[21]  M. Poupart,et al.  Solid-Phase Synthesis of Peptidyl Trifluoromethyl Ketones , 1999 .

[22]  H. V. Bekkum,et al.  Catalytic Syntheses of Aromatic Amines , 1997 .

[23]  R. Johnstone,et al.  Heterogeneous catalytic transfer hydrogenation and its relation to other methods for reduction of organic compounds , 1985 .

[24]  D. Seebach,et al.  Improved Nitroaldol Reactions and Reductive Routes to Vicinal Aminoalcohols , 1981 .