Electrical conduction mechanisms in thermally evaporated lead phthalocyanine thin films

The AC electrical behaviour of sandwich devices fabricated entirely in vacuum using thermally evaporated thin films of lead phthalocyanine and gold electrodes is observed over the frequency range to Hz and the temperature range 160 to 440 K. In the high-frequency region the AC conductivity is proportional to . Capacitance and dissipation factors decrease with increasing frequency and increase with increasing temperature. The results obtained show the relative importance of the hopping model and band theory in describing the film conduction with regard to the operating conditions. The former is dominant at low temperatures and high frequencies, whereas the latter is dominant at high temperatures and low frequencies.

[1]  R. D. Gould,et al.  Dependence of AC electrical parameters on frequency and temperature in zinc phthalocyanine thin films , 1993 .

[2]  R. D. Gould,et al.  A.c. electrical properties of thermally evaporated thin films of copper phthalocyanine , 1993 .

[3]  J. Silver,et al.  Dielectric and Optical Studies of Sublimed MoOPc Films , 1992 .

[4]  R. A. Collins,et al.  Ohmic and Space-Charge-Limited Conduction in Lead Phthalocyanine Thin Films , 1991 .

[5]  C. Hogarth,et al.  The effect of annealing on the AC electrical properties of SiO/SnO2 amorphous thin films , 1987 .

[6]  R. D. Gould,et al.  Dependence of the mobility and trap concentration in evaporated copper phthalocyanine thin films on background pressure and evaporation rate , 1986 .

[7]  R. Even,et al.  Spectroscopic properties and conductivity of thin films of partially reduced metallo‐phthalocyanines , 1985 .

[8]  V. S. Dharmadhikari Dielectric and transport properties of thin polycrystalline CdTe films , 1983 .

[9]  L. Schein Temperature independent drift mobility along the molecular direction of As 2 S 3 , 1977 .

[10]  A. Jonscher Alternating current diagnostics of poorly conducting thin films , 1976 .

[11]  M. Abkowitz,et al.  Dark and photogenerated ac conductivity inAs2S3single crystals , 1975 .

[12]  G. G. Roberts,et al.  Study of Localized Levels in Semi-Insulators by Combined Measurements of Thermally Activated Ohmic and Space-Charge-Limited Conduction , 1969 .

[13]  Alan Sussman,et al.  Space‐Charge‐Limited Currents in Copper Phthalocyanine Thin Films , 1967 .

[14]  C. M. Huggins,et al.  Dielectric Properties of Some Powdered Organic Semiconductors , 1963 .

[15]  H. Nalwa,et al.  Dielectric properties of cobalt phthalocyanine , 1983 .

[16]  H. Metiu,et al.  The temperature dependence of the electron mobility in molecular crystals , 1979 .

[17]  D. D. Eley,et al.  The semiconductivity of organic substances. Part 2 , 1955 .